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Topology-dependent emissive properties of zirconium-based porphyrin MOFs.
Chemical Communications : Chem Comm 2016 October 28
Highly ordered chromophoric linkers positioned within the metal-organic frameworks (MOFs) have the potential to mimic natural light-harvesting complexes. Herein we report topological control over the photophysical properties of MOFs via modular interchromophoric electronic coupling to manifest different steady-state singlet emission spectra and their corresponding fluorescence lifetimes.
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