We have located links that may give you full text access.
Synthesis and photophysics of extended π-conjugated systems of substituted 10-aryl-pyrenoimidazoles.
Organic & Biomolecular Chemistry 2016 November 3
The synthesis of π-extended 10-aryl-pyrenoimidazoles having different substituents was realised via Ru(ii)-catalyzed oxidative annulation of 10-aryl-pyrenoimidazole with diphenylacetylene. The single crystal X-ray structure of trifluoromethyl and carboxylate substituted annulated-10-aryl-pyrenoimidazoles confirms the near coplanarity of the pyrene and imidazole moieties and the presence of twisted conformation resulting in intermolecular C-Hπ interactions. The lowest energy absorption maximum becomes red-shifted characteristic to the nature of the substituent owing to the extended π-conjugation, and specifically the nitro substituent shows intense absorption in the visible region with the maximum at 440 nm. All the molecules were found to show intense fluorescence both in solution and solid states. Strikingly, 170 nm red-shifted fluorescence with a large Stokes shift ca. 7000 cm-1 for the nitro derivative, a value nearly two-fold higher than the parent compound despite its rigid polyaromatic skeleton was observed. The combination of electron rich π-conjugated aromatic systems with electron deficient substituents induces the intramolecular charge transfer interactions, which has been corroborated with the theoretical calculations.
Full text links
Related Resources
Trending Papers
Heart failure with preserved ejection fraction: diagnosis, risk assessment, and treatment.Clinical Research in Cardiology : Official Journal of the German Cardiac Society 2024 April 12
Proximal versus distal diuretics in congestive heart failure.Nephrology, Dialysis, Transplantation 2024 Februrary 30
Efficacy and safety of pharmacotherapy in chronic insomnia: A review of clinical guidelines and case reports.Mental Health Clinician 2023 October
World Health Organization and International Consensus Classification of eosinophilic disorders: 2024 update on diagnosis, risk stratification, and management.American Journal of Hematology 2024 March 30
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app