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Electrochemically active porous organic polymers based on corannulene.

Arosha A K Karunathilake, Christina M Thompson, Sahila Perananthan, John P Ferraris, Ronald A Smaldone
Chemical Communications : Chem Comm 2016 October 26
For the first time, porous organic polymers (POPs) based on the smallest buckybowl, corannulene (BB-POPs) have been synthesized. Three POPs were synthesised via Sonogashira co-polymerization of 1,2,5,6-tetrabromocorannulene and alkyne linkers. BB-POP-3 exhibits the highest surface area (SABET = 560 m2 g-1 ) and CO2 adsorption of 11.7 wt%, while they retain the redox properties of corannulene.

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