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Alkaline-earth phosphonate MOFs with reversible hydration-dependent fluorescence.

Z H Fard, Y Kalinovskyy, D M Spasyuk, B A Blight, G K H Shimizu
Chemical Communications : Chem Comm 2016 October 26
A new rigid tritopic phosphonic ligand, 2,4,6-tris(4-phosphonophenyl)pyridine (H6L), was synthesized and used to assemble isostructural barium (1) and strontium (2) phosphonate metal organic frameworks that exhibit fully reversible and selective water-dependent fluorescence red-shift at room temperature.

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