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Stability of metal-organic frameworks under gamma irradiation.

C Volkringer, C Falaise, P Devaux, R Giovine, V Stevenson, F Pourpoint, O Lafon, M Osmond, C Jeanjacques, B Marcillaud, J C Sabroux, T Loiseau
Chemical Communications : Chem Comm 2016 October 14
We report the study of the resistance of archetypal MOFs (MILs, HKUST-1, UiO-66, and ZIF-8) under gamma irradiation. The different porous solids were irradiated with doses up to 1.75 MGy. All the MOFs constructed with transition metals (Cu2+ , Zn2+ , Zr4+ ) exhibit an evident destruction of the framework, whereas the compounds constructed with aluminium remain intact.

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