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KNH 2 -KH: a metal amide-hydride solid solution.

Antonio Santoru, Claudio Pistidda, Magnus H Sørby, Michele R Chierotti, Sebastiano Garroni, Eugenio Pinatel, Fahim Karimi, Hujun Cao, Nils Bergemann, Thi T Le, Julián Puszkiel, Roberto Gobetto, Marcello Baricco, Bjørn C Hauback, Thomas Klassen, Martin Dornheim
Chemical Communications : Chem Comm 2016 September 28
We report for the first time the formation of a metal amide-hydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2 - ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.

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