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Solution Conformations of Curcumin in DMSO.

Cathryn A Slabber, Craig D Grimmer, Ross S Robinson
Journal of Natural Products 2016 October 29
NAMFIS (NMR Analysis of Molecular Flexibility In Solution) has been applied to curcumin dissolved in DMSO. Quantitative 1 H-1 H distance constraints reduce a pool of candidate conformations to a solution collection of four enol conformations-two of these match curcumin crystallized with human transthyretin, and one is closely related to a single-crystal structure of curcumin.

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