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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Double Ring Expansion from an Aromatic [18]Porphyrin(1.1.1.1) to an Antiaromatic [20]Porphyrin(2.1.2.1).
Angewandte Chemie 2016 July 5
Double ring expansion from a 5,15-diarylporphyrin to a 5,16-diaryl-10,11,21,22-tetradehydro[20]porphyrin(2.1.2.1) occurred through a reaction sequence consisting of oxidation with PbO2 to 5,15-dioxoporphodimethene, a Corey-Fuchs reaction with tetrabromomethane in the presence of triphenylphosphine, and Fritsch-Buttenberg-Wiechell rearrangement triggered by tert-butyllithium. The obtained tetradehydro[20]porphyrin(2.1.2.1) and its mono- and dihydrogenated congeners exhibited 20 π antiaromatic character, whereas overhydrogenated congeners bearing a saturated bridge were nonaromatic owing to disrupted π conjugation.
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