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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Bioinspired Collective Syntheses of Iboga-Type Indole Alkaloids.
Organic Letters 2016 May 21
We present the application of a bioinspired collective synthesis strategy in the total syntheses of seven iboga-type indole alkaloids: (±)-tabertinggine, (±)-ibogamine, (±)-ibogaine, (±)-ibogaine hydroxyindolenine, (±)-3-oxoibogaine hydroxyindolenine, (±)-iboluteine, and (±)-ervaoffines D. In particular, tabertinggine and its congeners serve as iboga precursors for the subsequent biomimetic transformations into other iboga-type alkaloids.
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