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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Relative Reactivity of Stable Ligated Boranes and a Borohydride Salt in Rhodium(II)-Catalyzed Boron-Hydrogen Insertion Reactions.
Journal of Organic Chemistry 2016 March 5
Relative reactivities of a series of neutral ligated boranes L-BH3 (where L is NHC, amine, pyridine, or phosphine) and the cyanoborohydride anion have been assessed in Rh(II)-catalyzed B-H insertion reactions with methyl 2-phenyl-2-diazoacetate. Stable α-boryl ester products were isolated by flash chromatography in all cases except for the salt product from cyanoborohydride. All of the substrates were either comparable to or more reactive than 1,4-cyclohexadiene, which is one of the most reactive substrates in C-H insertion reactions. The range of reactivity between the most reactive pyridine-borane and the least reactive phosphine-borane is a factor of approximately 40.
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