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HBF4-Catalysed Nucleophilic Substitutions of Propargylic Alcohols.
European Journal of Organic Chemistry 2015 December
The activity of HBF4 (aqueous solution) as a catalyst in propargylation reactions is presented. Diverse types of nucleophiles were employed in order to form new C-O, C-N and C-C bonds in technical acetone and in air. Good to excellent yields and good chemoselectivities were obtained using low acid loading (typically 1 mol-%) under simple reaction conditions.
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