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Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't
Light-triggered chemical amplification to accelerate degradation and release from polymeric particles.
Chemical Communications : Chem Comm 2015 December 12
We describe a means of chemical amplification to accelerate triggered degradation of a polymer and particles composed thereof. We designed a light-degradable copolymer containing carboxylic acids masked by photolabile groups and ketals. Photolysis allows the unmasked acidic groups in the polymer backbone to accelerate ketal hydrolysis even at neutral pH.
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