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A Mechanofluorochromic Push-Pull Small Molecule with Aggregation-Controlled Linear and Nonlinear Optical Properties.
Advanced Materials 2015 August 6
A small push-pull molecule involving a diphenylamine substituted by an oligo-oxyethylene chain is described. The compound exhibits aggregation-induced emission with solvent-dependent emission wavelength. Spin-cast deep-red amorphous films rapidly self-reorganize into colorless crystalline films which exhibit mechanofluorochromism and aggregation-induced second-harmonic generation.
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