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A Late Stage Strategy for the Functionalization of Triazolium-based NHC catalysts.

Kerem E Ozboya, Tomislav Rovis
Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry 2014
A strategy for the diversification of triazolium-based catalysts is presented. This method is based on the reduction to the triazoline, which serves as a suitable and stable substrate for Pd-mediated cross-coupling, followed by trityl cation mediated reoxidation to the triazolium.

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