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Ion-Size-Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters.

Christine Artner, Stefan Kronister, Matthias Czakler, Ulrich Schubert
European Journal of Inorganic Chemistry 2014 November
The mixed-metal oxo clusters LnTi4O3(OiPr)2(OMc)11 (Ln = La, Ce; OMc = methacrylate), Ln2Ti6O6(OMc)18(HOiPr) (Ln = La, Ce, Nd, Sm) and Ln2Ti4O4(OMc)14(HOMc)2 (Ln = Sm, Eu, Gd, Ho) have been synthesized from titanium isopropoxide, the corresponding lanthanide acetate and methacrylic acid. The type of cluster obtained strongly depends on the size of the lanthanide ion.

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