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Journal Article
Research Support, Non-U.S. Gov't
Engineered P450pyr monooxygenase for asymmetric epoxidation of alkenes with unique and high enantioselectivity.
Chemical Communications : Chem Comm 2013 December 22
A triple mutant of P450pyr monooxygenase (P450pyrTM) catalysed the epoxidation of several para-substituted styrenes as the first enzyme showing high (R)-enantioselectivity and high conversion, demonstrated a broad substrate range, and showed high enantioselectivity for the epoxidation of an unconjugated 1,1-disubstituted alkene, 2-methyl-3-phenyl-1-propene, and a cyclic alkene, N-phenoxycarbonyl-1,2,5,6-tetrahydropyridine, respectively.
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