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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Manipulating the diastereoselectivity of ortholithiation in planar chiral ferrocenes.
Organic Letters 2013 July 6
The sense of asymmetric ortholithiation directed by a chiral oxazoline may be inverted simply by the choice of achiral ligand. Comparison of results with a number of ferrocenyl oxazoline derivatives suggests that lithiation takes place by coordination to the oxazoline nitrogen irrespective of the ligand used.
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