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Journal Article
Research Support, Non-U.S. Gov't
Synthesis of ferrocenestrone: the first metallocene based steroid analogue.
Chemistry : a European Journal 2012 April 28
Ferrocenestrone, the first steroid derivative containing a metallocene moiety, was stereoselectively prepared. The key steps included the enantioselective functionalization of ferrocene, elongation of the side chain, intramolecular enyne metathesis, Diels-Alder reaction, heterogeneous hydrogenation of the sterically hindered double bond, and finally inversion of the configuration at C13.
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