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Thermodynamic studies on PNA and PNA/DNA dendrimer formation.

Maria Moccia, Domenica Musumeci, Margherita Valente, Giovanni N Roviello, Roberto Sapio, Carlo Pedone, Enrico M Bucci
Nucleosides, Nucleotides & Nucleic Acids 2007
In this work we report a kinetic and thermodynamic study relative to the formation of gel systems based on PNA and PNA/DNA dendrimers, useful for drug delivery or diagnostic applications. We realized two kinds of systems: a PNA-based monomolecular system formed by an autoassembling PNA tridendron (A) and a PNA/DNA bimolecular system based on a PNA tridendron with a mixed sequence and a DNA crosslinker (B). Both systems have the ability to form a three-dimensional network by means of specific W-C base pairing.

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