Kristopher A Hunt, Alex V Carr, Anne E Otwell, Jacob J Valenzuela, Kathleen S Walker, Emma R Dixon, Lauren M Lui, Torben N Nielsen, Samuel Bowman, Frederick von Netzer, Ji-Won Moon, Christopher W Schadt, Miguel Rodriguez, Kenneth Lowe, Dominique Joyner, Katherine J Davis, Xiaoqin Wu, Romy Chakraborty, Matthew W Fields, Jizhong Zhou, Terry C Hazen, Adam P Arkin, Scott D Wankel, Nitin S Baliga, David A Stahl
The sources and sinks of nitrous oxide, as control emissions to the atmosphere, are generally poorly constrained for most environmental systems. Initial depth-resolved analysis of nitrous oxide flux from observation wells and the proximal surface within a nitrate contaminated aquifer system revealed high subsurface production but little escape from the surface. To better understand the environmental controls of production and emission at this site, we used a combination of isotopic, geochemical, and molecular analyses to show that chemodenitrification and bacterial denitrification are major sources of nitrous oxide in this subsurface, where low DO, low pH, and high nitrate are correlated with significant nitrous oxide production...
April 12, 2024: Environmental Science & Technology