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https://www.readbyqxmd.com/read/29786662/study-on-the-discrimination-between-citri-reticulatae-pericarpium-varieties-based-on-hs-spme-gc-ms-combined-with-multivariate-statistical-analyses
#1
Yuying Zheng, Xuan Zeng, Wei Peng, Zhong Wu, Weiwei Su
Citri reticulatae pericarpium (CRP), the dried pericarps of Citrus reticulata Blanco and its cultivars, has been widely used in drugs and foods in China for centuries. In this study, an accurate and feasible analytical method based on HS-SPME-GC-MS coupled with multivariate statistical analyses was developed to comprehensively compare volatile compounds of pericarps derived from Citrus reticulata "Chachi" ("Guangchenpi" in Chinese, GCP) and other cultivars of Citrus reticulata Blanco ("Chenpi" in Chinese, CP)...
May 22, 2018: Molecules: a Journal of Synthetic Chemistry and Natural Product Chemistry
https://www.readbyqxmd.com/read/29786171/root-bacterial-endophytes-confer-drought-resistance-and-enhance-expression-and-activity-of-a-vacuolar-h-pumping-pyrophosphatase-in-pepper-plants
#2
Gianpiero Vigani, Eleonora Rolli, Ramona Marasco, Marta Dell'Orto, Grégoire Michoud, Asma Soussi, Noura Raddadi, Sara Borin, Claudia Sorlini, Graziano Zocchi, Daniele Daffonchio
It has been previously shown that the transgenic overexpression of the plant root vacuolar proton pumps H+ -ATPase (V-ATPase) and H+ -PPase (V-PPase) confer tolerance to drought. Since plant-root endophytic bacteria can also promote drought tolerance, we hypothesize that such promotion can be associated to the enhancement of the host vacuolar proton pumps expression and activity. To test this hypothesis, we selected two endophytic bacteria endowed with an array of in vitro plant growth promoting traits. Their genome sequences confirmed the presence of traits previously shown to confer drought resistance to plants, such as the synthesis of nitric oxide and of organic volatile organic compounds...
May 22, 2018: Environmental Microbiology
https://www.readbyqxmd.com/read/29784959/commercially-available-natural-benzyl-esters-and-their-synthetic-analogs-exhibit-different-toxicities-against-insect-pests
#3
Yan Feng, Jian Chen, Aijun Zhang
Benzyl methyl ester, also known as methyl benzoate (MB), is a volatile organic compound that exists naturally as a floral fragrance in many plants. Our behavioral bioassays show that MB and some of its naturally occurring and synthetic analogs kill insects at different life stages. Compared to commercial pesticides containing pyriproxyfen and acetamiprid, MB and some analogs are 1.3 to 3.4 times more toxic to gypsy moth larvae and brown marmorated stinkbug nymphs. The arthropod repellent DEET is also a benzyl ester, and shares the same chemical skeleton with MB...
May 21, 2018: Scientific Reports
https://www.readbyqxmd.com/read/29784334/toasted-vine-shoot-chips-as-enological-additive
#4
Cristina Cebrián-Tarancón, Rosario Sánchez-Gómez, M Rosario Salinas, Gonzalo L Alonso, José Oliva, Amaya Zalacain
Different ways of vine-shoots revalorization have been proposed, but not in wine yet, as for example in the same way as oak chips are being used. In this work, vine-shoot samples were submitted to a thermogravimetric analysis to establish the temperature range for its lignin structure decomposition, resulting between 160 and 180 °C. Then, vine-shoot chips from Airén and Cencibel cultivars, with a particle size around 2.5-3.5 cm, were submitted to six toasting conditions: 160 °C and 180 °C for 45, 60 and 75 min...
October 15, 2018: Food Chemistry
https://www.readbyqxmd.com/read/29784332/whey-acerola-flavoured-drink-submitted-ohmic-heating-bioactive-compounds-antioxidant-capacity-thermal-behavior-water-mobility-fatty-acid-profile-and-volatile-compounds
#5
Leandro P Cappato, Marcus Vinicius S Ferreira, Jeremias Moraes, Roberto P S Pires, Ramon S Rocha, Ramon Silva, Roberto P C Neto, Maria Inês B Tavares, Mônica Q Freitas, Flavio N Rodrigues, Veronica M A Calado, Renata S L Raices, Marcia C Silva, Adriano G Cruz
Whey acerola-flavoured drink was subjected to Ohmic Heating (OH) under different operational conditions (45, 60, 80 V at 60 Hz and 10, 100, 1000 Hz with 25 V, 65 °C/30 min) and conventional pasteurization (65 °C/30 min). Bioactive compounds (total phenolics, DPPH, FRAP, ACE levels), fatty acid profile, volatile compounds (CG-MS), thermal behaviors (DSC) and water mobility (TD-NMR) were performed. Reduction of frequency (1000-10 Hz) resulted in a lower bioactive compounds and antioxidant capacity of the samples, except for the DPPH values...
October 15, 2018: Food Chemistry
https://www.readbyqxmd.com/read/29784326/changes-in-chemical-and-sensory-properties-of-amarone-wine-produced-by-penicillium-infected-grapes
#6
Giacomo Zapparoli, Marilinda Lorenzini, Emanuele Tosi, Michela Azzolini, Davide Slaghenaufi, Maurizio Ugliano, Barbara Simonato
There is very little information on effects of Penicillium on aroma of passito wine. This study analyzed chemical composition and sensory properties of Amarone wines produced from withered grapes artificially contaminated by P. expansum or P. crustosum. Changes in properties of the two wines were evident by comparing wines obtained from healthy and Botrytis cinerea infected grapes used as controls. Penicillium infection affected primary and volatile composition of Amarone wine. Sensory profiles of these wines, obtained by descriptive analysis, resulted in clear differences in the wines between themselves and the control wines...
October 15, 2018: Food Chemistry
https://www.readbyqxmd.com/read/29784307/effects-of-postharvest-methyl-jasmonate-treatment-on-main-health-promoting-components-and-volatile-organic-compounds-in-cherry-tomato-fruits
#7
Haoran Liu, Fanliang Meng, Huiying Miao, Shanshan Chen, Tingting Yin, Songshen Hu, Zhiyong Shao, Yuanyuan Liu, Liuxiao Gao, Changqing Zhu, Bo Zhang, Qiaomei Wang
Effects of postharvest methyl jasmonate (MeJA) treatment on the contents of ascorbic acid and carotenoids, as well as the compositions and contents of volatile organic compounds (VOCs) in cherry tomato fruits were investigated during 11 days of storage at room temperature (25 °C). The results showed that MeJA treatment significantly increased the contents of ascorbic acid and carotenoids, especially lycopene in postharvest cherry tomato fruits. Moreover, MeJA treatment improved the contents of carotenoids derived VOCs such as 6-methyl-5-hepten-2-one (MHO), while had no effect on firmness, sugars and titratable acidity...
October 15, 2018: Food Chemistry
https://www.readbyqxmd.com/read/29784304/contribution-of-l-theanine-to-the-formation-of-2-5-dimethylpyrazine-a-key-roasted-peanutty-flavor-in-oolong-tea-during-manufacturing-processes
#8
Xiangyang Guo, Chuankui Song, Chi-Tang Ho, Xiaochun Wan
l-Theanine, the most abundant amino acid in tea, is widely believed to be associated with the tea taste, however, its contribution to the formation of tea aroma is still unknown. Volatiles were determined and nitrogen-containing compounds formed during manufacturing processes were quantified. Lower levels of total sugar and l-theanine were detected in the Oolong tea product undergoing full fire processing (FFOT) suggesting that l-theanine probably involved in the volatile formation during manufacturing processes...
October 15, 2018: Food Chemistry
https://www.readbyqxmd.com/read/29784296/the-effect-of-rosemary-rosmarinus-officinalis-l-extract-on-the-oxidative-stability-of-lipids-in-cow-and-soy-milk-enriched-with-fish-oil
#9
Xujian Qiu, Charlotte Jacobsen, Ann-Dorit Moltke Sørensen
Lipid oxidation of fish oil enriched cow milk and soy milk supplemented with rosemary extract stored at 2 °C was studied. Both peroxide value and volatile secondary lipid oxidation products were determined to monitor the progress of lipid oxidation. Rosemary extract inhibited lipid oxidation in fish oil enriched cow milk. In contrast, soy milk samples having much higher unsaturated fatty acid content showed higher lipid oxidation stability compared to cow milk. Reduction in the content of chlorogenic acid during storage suggested that this compound may contribute to the lipid oxidation stability of fish oil enriched soy milk product...
October 15, 2018: Food Chemistry
https://www.readbyqxmd.com/read/29783892/applying-the-hydrodistillation-process-to-pentadiplandra-brazzeana-baill-root-a-chemical-assessment
#10
Maximilienne Ascension Nyegue, Sabine Montaut, Gina Rosalinda De Nicola, Patrick Rollin, Chantal Menut
A chemical study of the volatile components obtained by applying the hydrodistillation and reflux processes to Pentadiplandra brazzeana roots was performed by GC-FID and GC-MS. The hydrodistillation process showed a total yield of 0.97% with 0.11% of essential oil and 0.86% of volatile compounds from the aqueous reaction medium; in the reflux process, the volatile extract yield was 1.03%. Benzylic-type isothiocyanates were the major degradation products of glucosinolates in the essential oil (95.0%); the CH2 Cl2 extracts obtained from the aqueous solutions were characterised by alcohols and amines in both processes...
May 21, 2018: Natural Product Research
https://www.readbyqxmd.com/read/29783625/a-simple-alternative-method-for-preservation-of-2-methylisoborneol-in-water-samples
#11
Chun-Cheng Fan, Yi-Ting Chiu, Tsair-Fuh Lin
2-Methylisoborneol (2-MIB) is one of the most commonly observed taste and odor (T&O) compounds present in drinking water sources. As it is biodegradable, a preservation agent, typically mercury chloride, is needed if the water is not analyzed right after sampling. Since mercury is a toxic metal, an alternative chemical that is cheaper and less toxic is desirable. In this study, two chemicals commonly used in water treatment processes, chlorine (as sodium hypochlorite) and KMnO₄ (potassium permanganate), are studied to determine their feasibility as preservation agents for 2-MIB in water...
May 18, 2018: International Journal of Environmental Research and Public Health
https://www.readbyqxmd.com/read/29783172/headspace-sorptive-extraction-gas-chromatography-mass-spectrometry-method-to-measure-volatile-emissions-from-human-airway-cell-cultures
#12
Mei S Yamaguchi, Mitchell M McCartney, Angela L Linderholm, Susan E Ebeler, Michael Schivo, Cristina E Davis
The human respiratory tract releases volatile metabolites into exhaled breath that can be utilized for noninvasive health diagnostics. To understand the origin of this metabolic process, our group has previously analyzed the headspace above human epithelial cell cultures using solid phase microextraction-gas chromatography-mass spectrometry (SPME-GC-MS). In the present work, we improve our model by employing sorbent-covered magnetic stir bars for headspace sorptive extraction (HSSE). Sorbent-coated stir bar analyte recovery increased by 52 times and captured 97 more compounds than SPME...
May 12, 2018: Journal of Chromatography. B, Analytical Technologies in the Biomedical and Life Sciences
https://www.readbyqxmd.com/read/29783096/all-roads-lead-to-rome-towards-understanding-different-avenues-of-tolerance-to-huanglongbing-in-citrus-cultivars
#13
Nabil Killiny, Shelley E Jones, Yasser Nehela, Faraj Hijaz, Manjul Dutt, Frederick G Gmitter, Jude W Grosser
Citrus tolerance to huanglongbing could result from tolerance to the pathogen Candidatus Liberibacter asiaticus (CLas) and/or to its vector Diaphorina citri. Field observations and greenhouse-controlled studies showed that some citrus cultivars were more tolerant than others. However, the mechanism(s) behind the tolerance has not been determined yet. Using GC-MS, we investigated the volatile organic compounds (VOCs) and the non-volatile metabolite profiles of two tolerant citrus cultivars- Australian finger lime, 'LB8-9' Sugar Belle® mandarin hybrid, and a recently released mandarin hybrid 'Bingo'...
May 18, 2018: Plant Physiology and Biochemistry: PPB
https://www.readbyqxmd.com/read/29783051/occurrence-and-potential-human-health-risks-of-semi-volatile-organic-compounds-in-drinking-water-from-cities-along-the-chinese-coastland-of-the-yellow-sea
#14
Zekai Li, Fangyu Chang, Peng Shi, Xun Chen, Feng Yang, Qing Zhou, Yang Pan, Aimin Li
Semi-volatile organic compounds (SVOCs) in drinking water have been considered a severe threat to public health worldwide. However, SVOC contamination and the associated human health risks of the drinking water from cities along tributaries of the Yangtze River and Huaihe River in China have been seldom reported. Here, we focused on the occurrence and distribution of a series of SVOCs, mainly including polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs) and phthalate esters (PAEs), in drinking water of this region...
May 12, 2018: Chemosphere
https://www.readbyqxmd.com/read/29783046/bacterial-community-of-industrial-raw-sausage-packaged-in-modified-atmosphere-throughout-the-shelf-life
#15
Stefano Raimondi, Maria Rosaria Nappi, Tiziana Maria Sirangelo, Alan Leonardi, Alberto Amaretti, Alessandro Ulrici, Rudy Magnani, Chiara Montanari, Giulia Tabanelli, Fausto Gardini, Maddalena Rossi
Ten lots of industrial raw sausages in modified atmosphere (CO2 30%, O2 70%), produced in the same plant over 7 months, were analyzed at the day after production (S samples) and at the end of shelf life (E samples), after 12 days storage at 7 °C to simulate thermal abuse. Quality of the products was generally compromised by storage at 7 °C, with only 3 E samples without alterations. During the shelf life, the pH decreased for the accumulation of acetic and lactic acids. A few biogenic amines accumulated, remaining below acceptable limits...
April 28, 2018: International Journal of Food Microbiology
https://www.readbyqxmd.com/read/29780668/impact-of-front-range-sources-on-reactive-nitrogen-concentrations-and-deposition-in-rocky-mountain-national-park
#16
Katherine B Benedict, Anthony J Prenni, Amy P Sullivan, Ashley R Evanoski-Cole, Emily V Fischer, Sara Callahan, Barkley C Sive, Yong Zhou, Bret A Schichtel, Jeffrey L Collett
Human influenced atmospheric reactive nitrogen (RN) is impacting ecosystems in Rocky Mountain National Park (ROMO). Due to ROMO's protected status as a Class 1 area, these changes are concerning, and improving our understanding of the contributions of different types of RN and their sources is important for reducing impacts in ROMO. In July-August 2014 the most comprehensive measurements (to date) of RN were made in ROMO during the Front Range Air Pollution and Photochemistry Éxperiment (FRAPPÉ). Measurements included peroxyacetyl nitrate (PAN), C1 -C5 alkyl nitrates, and high-time resolution NOx , NOy , and ammonia...
2018: PeerJ
https://www.readbyqxmd.com/read/29779386/gas-analysis-by-electron-ionization-combined-with-chemical-ionization-in-a-compact-ft-icr-mass-spectrometer
#17
Michel Heninger, Hélène Mestdagh, Essyllt Louarn, Gérard Mauclaire, Pierre Boissel, Julien Leprovost, Elsa Bauchard, Sebastien Thomas, Joel Lemaire
In this paper, a compact Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer based on a permanent magnet is presented. This instrument has been developed for real-time analysis of gas emissions. The instrument is well suited to industrial applications or analysis of toxic and complex samples where the concentrations can vary rapidly on a wide range. The novelty of this instrument is the ability to use either electron ionization (EI) or chemical ionization (CI) individually or both of them alternatively...
May 20, 2018: Analytical Chemistry
https://www.readbyqxmd.com/read/29778813/ozone-disrupts-adsorption-of-rhododendron-tomentosum-volatiles-to-neighbouring-plant-surfaces-but-does-not-disturb-herbivore-repellency
#18
Adedayo O Mofikoya, Minna Kivimäenpää, James D Blande, Jarmo K Holopainen
The perennial evergreen woody shrub, Rhododendron tomentosum, confers associational resistance against herbivory and oviposition on neighbouring plants through passive adsorption of some of its constitutively emitted volatile organic compounds (VOCs). The adsorption process is dependent on transport of VOCs in the air. In polluted atmospheres, the VOCs may be degraded and adsorption impeded. We studied the effect of elevated ozone regimes on the adsorption of R. tomentosum volatiles to white cabbage, Brassica oleracea, and the oviposition of the specialist herbivore Plutella xylostella on the exposed plants...
May 17, 2018: Environmental Pollution
https://www.readbyqxmd.com/read/29778176/a-comprehensive-classification-method-for-voc-emission-sources-to-tackle-air-pollution-based-on-voc-species-reactivity-and-emission-amounts
#19
Guohao Li, Wei Wei, Xia Shao, Lei Nie, Hailin Wang, Xiao Yan, Rui Zhang
In China, volatile organic compound (VOC) control directives have been continuously released and implemented for important sources and regions to tackle air pollution. The corresponding control requirements were based on VOC emission amounts (EA), but never considered the significant differentiation of VOC species in terms of atmospheric chemical reactivity. This will adversely influence the effect of VOC reduction on air quality improvement. Therefore, this study attempted to develop a comprehensive classification method for typical VOC sources in the Beijing-Tianjin-Hebei region (BTH), by combining the VOC emission amounts with the chemical reactivities of VOC species...
May 2018: Journal of Environmental Sciences (China)
https://www.readbyqxmd.com/read/29778167/effects-of-adding-bulking-agents-on-the-biodrying-of-kitchen-waste-and-the-odor-emissions-produced
#20
Jing Yuan, Yun Li, Hongyu Zhang, Difang Zhang, David Chadwick, Guoxue Li, Guoying Wang, Menghao Chi, Fan Yang
The effects of adding a bulking agent on the performance and odor emissions (ammonia and eight sulfur-containing odorous compounds) when biodrying kitchen waste were investigated. Three treatments were considered: the addition of either cornstalks (CS) or wood peat (WP) to kitchen waste as a bulking agent before biodrying, and a control treatment (CK). The water-removal rates for CK, CS, and WP treatments were 0.35, 0.56, and 0.43kg/kg, respectively. Addition of bulking agents to kitchen waste produced less leachate, higher moisture-removal rates, and lower consumption of volatile solids...
May 2018: Journal of Environmental Sciences (China)
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