Vı Ctor Augusto Moreno-Martínez, Diego Martı Nez-Otero, Brandon Meza-González, Fernando Cortéz-Guzmán, Vojtech Jancik
The molecular alumosilicates Al L {OSi(O t Bu)2 O}[OSi{(μ3 -O)(MR2 )2 (μ-O t Bu)}(O t Bu)] ( L = HC[CMeNAr]2 - , where M = Al, R = Me ( 2 ), Et ( 3 ), and i Bu ( 4 ) and M = Ga, R = Me ( 5 )) were obtained from the reaction of Al L {OSi(O t Bu)2 (OH)}2 ( 1 ) with 1 or 2 equiv of the respective organometallic precursor. These compounds have a central bicyclic inorganic core formed by a six-membered AlSi2 O3 alumosilicate ring with a Si-O-Si unit connected via a Si-O bond to a four-membered Al2 O2 alumoxane ring...
May 18, 2020: Inorganic Chemistry