María Benítez, María L Buil, Miguel A Esteruelas, Ana M López, Cristina Martín-Escura, Enrique Oñate
Complex IrH5 (Pi Pr3 )2 ( 1 ) activates two different σ-bonds of 3-phenoxy-1-phenylisoquinoline, 2-(1 H -benzimidazol-2-yl)-6-phenylpyridine, 2-(1 H -indol-2-yl)-6-phenylpyridine, 2-(2-hydroxyphenyl)-6-phenylpyridine, N -(2-hydroxyphenyl)- N '-phenylimidazolylidene, and 1,3-di(2-pyridyl)-4,6-dimethylbenzene to give IrH{κ3 - C,N,C -[C6 H4 -isoqui-O-C6 H4 ]}(Pi Pr3 )2 ( 2 ), IrH{κ3 - N,N,C -[NBzim-py-C6 H4 ]}(Pi Pr3 )2 ( 3 ), IrH{κ3 - N,N,C -[Ind-py-C6 H4 ]}(Pi Pr3 )2 ( 4 ), IrH{κ3 - C,N,O -[C6 H4 -py-C6 H4 O]}(Pi Pr3 )2 ( 5 ), IrH{κ3 - C,C,O -[C6 H4 -Im-C6 H4 O]}(Pi Pr3 )2 ( 6 ), and IrH{κ3 - N,C,C -[py-C6 HMe2 -C5 H3 N]}(Pi Pr3 )2 ( 7 ), respectively...
March 28, 2024: Inorganic Chemistry