keyword
https://read.qxmd.com/read/38655684/advancing-lithium-sulfur-battery-efficiency-utilizing-a-2d-2d-g-c-3-n-4-mxene-heterostructure-to-enhance-sulfur-evolution-reactions-and-regulate-polysulfides-under-lean-electrolyte-conditions
#1
JOURNAL ARTICLE
Vijay K Tomer, Otavio Augusto Titton Dias, Abdelaziz M Gouda, Ritu Malik, Mohini Sain
Lithium-sulfur batteries (LSBs) show promise for achieving a high energy density of 500 W h kg-1 , despite challenges such as poor cycle life and low energy efficiency due to sluggish redox kinetics of lithium polysulfides (LiPSs) and sulfur's electronic insulating nature. We present a novel 2D Ti3 C2 Mxene on a 2D graphitic carbon nitride (g-C3 N4 ) heterostructure designed to enhance LiPS conversion kinetics and adsorption capacity. In a pouch cell configuration with lean electrolyte conditions (∼5 μL mg-1 ), the g-C3 N4 -Mx/S cathode exhibited excellent rate performance, delivering ∼1061 mA h g-1 at C/8 and retaining ∼773 mA h g-1 after 190 cycles with a Coulombic efficiency (CE) of 92...
April 24, 2024: Materials Horizons
https://read.qxmd.com/read/38649746/nanoscale-doping-of-polymeric-semiconductors-with-confined-electrochemical-ion-implantation
#2
JOURNAL ARTICLE
Lanyi Xiang, Zihan He, Chaoyi Yan, Yao Zhao, Zhiyi Li, Lingxuan Jia, Ziling Jiang, Xiaojuan Dai, Vincent Lemaur, Yingqiao Ma, Liyao Liu, Qing Meng, Ye Zou, David Beljonne, Fengjiao Zhang, Deqing Zhang, Chong-An Di, Daoben Zhu
Nanoresolved doping of polymeric semiconductors can overcome scaling limitations to create highly integrated flexible electronics, but remains a fundamental challenge due to isotropic diffusion of the dopants. Here we report a general methodology for achieving nanoscale ion-implantation-like electrochemical doping of polymeric semiconductors. This approach involves confining counterion electromigration within a glassy electrolyte composed of room-temperature ionic liquids and high-glass-transition-temperature insulating polymers...
April 22, 2024: Nature Nanotechnology
https://read.qxmd.com/read/38645374/structure-and-properties-of-epoxy-resin-graphene-oxide-composites-prepared-from-silicon-dioxide-modified-graphene-oxide
#3
JOURNAL ARTICLE
Jin An, Yue Zhang, Xiaojun Zhang, Mingpeng He, Jiang Zhou, Jin Zhou, Yan Liu, Xuebing Chen, Yiwen Hu, Xiuduo Song, Jinyao Chen, Tong Wu, Jian Kang, Zhihui Xie
In this study, graphene oxide (GO) was modified via electrostatic interactions and chemical grafting by silica (SiO2 ), and two SiO2 @GO hybrids (GO-A and GO-B, respectively) with different structures were obtained and carefully characterized. Results confirmed the successful grafting of SiO2 onto the GO surface using both strategies. The distribution of SiO2 particles on the surface of GO-A was denser and more agglomerated, while it was more uniform on the surface of GO-B. Then, epoxy resin (EP)/GO composites were prepared...
April 16, 2024: ACS Omega
https://read.qxmd.com/read/38644964/air-stable-large-area-2d-metals-and-semiconductors
#4
REVIEW
Chengye Dong, Li-Syuan Lu, Yu-Chuan Lin, Joshua A Robinson
Two-dimensional (2D) materials are popular for fundamental physics study and technological applications in next-generation electronics, spintronics, and optoelectronic devices due to a wide range of intriguing physical and chemical properties. Recently, the family of 2D metals and 2D semiconductors has been expanding rapidly because they offer properties once unknown to us. One of the challenges to fully access their properties is poor stability in ambient conditions. In the first half of this Review, we briefly summarize common methods of preparing 2D metals and highlight some recent approaches for making air-stable 2D metals...
April 17, 2024: ACS Nanosci Au
https://read.qxmd.com/read/38644689/in-situ-loading-of-ni-3-znc-0-7-nanoparticles-with-carbon-nanotubes-to-3d-melamine-sponge-derived-hollow-carbon-skeleton-toward-superior-microwave-absorption-and-thermal-resistance
#5
JOURNAL ARTICLE
Ruilin Liu, YuKun Wang, Peng Wang, Hideo Kimura, Baolei Wang, Chuanxin Hou, Xueqin Sun, Wei Du, Xiubo Xie
The simple and low-cost construction of a 3D network structure is an ideal way to prepare high-performance electromagnetic wave (EMW) absorption materials. Herein, a series of carbon skeleton/carbon nanotubes/Ni3 ZnC0.7 composites (CS/CNTs/Ni3 ZnC0.7 ) are successfully prepared by in situ growth of Ni3 ZnC0.7 and CNTs on 3D melamine sponge carbon. With the increase of precursor, Ni3 ZnC0.7 nanoparticles nucleate and catalyze the generation of CNTs on the surface of the carbon skeleton. The minimum reflection loss (RL) value of the S60min composite (loading time of 60 min) reaches -86...
April 21, 2024: Small
https://read.qxmd.com/read/38642753/a-pam-hydrogel-surface-coated-hydroponic-bamboo-evaporator-with-efficient-thermal-utilization-for-solar-evaporation
#6
JOURNAL ARTICLE
Wenfang Cai, Wenting Wang, Jiaoli Ji, Yunhai Wang, Zhengjiang Wang, Jin Mao, Jing Wang, Mingkuan Zhang, Yapeng Liu, Qingyun Chen
Solar-driven interfacial water purification emerges as a sustainable technology for seawater desalination and wastewater treatment to address the challenge of water scarcity. Currently, the energy losses via radiation and convection to surrounding environment minimize its energy efficiency. Therefore, it is necessary to develop strategies to minimize the heat losses for efficient water purification. Here, a novel evaporator was developed through the in situ gelation of PAM hydrogel on the surface carbonized hydroponic bamboo (PSC) to promote energy efficiency...
April 18, 2024: Science of the Total Environment
https://read.qxmd.com/read/38639384/wearable-emi-shielding-composite-films-with-integrated-optimization-of-electrical-safety-biosafety-and-thermal-safety
#7
JOURNAL ARTICLE
Liang Li, Yongzhu Yan, Jufu Liang, Jinchuan Zhao, Chaoyi Lyu, Haoxiang Zhai, Xilong Wu, Guizhen Wang
Biomaterial-based flexible electromagnetic interference (EMI) shielding composite films are desirable in many applications of wearable electronic devices. However, much research focuses on improving the EMI shielding performance of materials, while optimizing the comprehensive safety of wearable EMI shielding materials has been neglected. Herein, wearable cellulose nanofiber@boron nitride nanosheet/silver nanowire/bacterial cellulose (CNF@BNNS/AgNW/BC) EMI shielding composite films with sandwich structure are fabricated via a simple sequential vacuum filtration method...
April 19, 2024: Advanced Science (Weinheim, Baden-Wurttemberg, Germany)
https://read.qxmd.com/read/38636762/redox-active-nis-bacterial-cellulose-nanofiber-composite-separators-with-superior-rate-capability-for-lithium-ion-batteries
#8
JOURNAL ARTICLE
Yun Zhang, Wei Du, Dezhan Ye, Jiangang Zhou, Weilin Xu, Jie Xu
Separator is an essential component of lithium-ion batteries (LIBs), which is placed between the electrodes to impede their electrical contact and provide the transport channels for lithium ions. Traditionally, the separator contributes the overall mass of LIBs, thereby reducing the gravimetric capacity of the devices. Herein, a dual-layer redox-active cellulose separator is designed and fabricated to enhance the electrochemical performances of LIBs by introducing NiS. The presented separator is composed of an insulating bacterial cellulose (BC) nanofiber layer and a conductive, and redox-active NiS@BC/carbon nanotubes layer...
April 16, 2024: International Journal of Biological Macromolecules
https://read.qxmd.com/read/38632871/fast-solution-blow-spinning-of-lotus-leaf-inspired-sio-2-nanofiber-sponge-for-high-efficiency-purification
#9
JOURNAL ARTICLE
Qingyang Li, Mengzhe Bao, Wenbin Li, Chong He
Massive production of SiO2 nanofibers with both high durability and exceptional performance remains a significant challenge. Herein, a novel approach was introduced to achieve the massive production of SiO2 nanofibers with lotus-leaf-inspired surfaces by combining solution blowing spinning (SBS) and the polymer-derived ceramics method. Based on the SBS technique, three types of precursor nanofiber products were fast spined with methyl silsesquioxane polymer and polymethyl hydrogen siloxane employed as Si sources...
April 17, 2024: ACS Applied Materials & Interfaces
https://read.qxmd.com/read/38632864/effects-of-thermal-insulation-on-recovery-and-comfort-of-patients-undergoing-holmium-laser-lithotripsy
#10
JOURNAL ARTICLE
Xiaoling Chen, Libin He, Xiao Yu, Yuqing Bo, Lei Yu, Qiumei Chen, Zhuoer Zhao
BACKGROUND Patients with urolithiasis often undergo transurethral ureteroscopic holmium laser lithotripsy, a procedure that can be affected by perioperative thermal management. This study examines the impact of compound thermal insulation management on patient recovery and comfort during transurethral ureteroscopic holmium laser lithotripsy. MATERIAL AND METHODS In this study, 551 patients who underwent transurethral ureteroscopic holmium laser lithotripsy from April 2019 to December 2022 were randomly assigned to either an observation group (n=276) or control group (n=275)...
April 18, 2024: Medical Science Monitor: International Medical Journal of Experimental and Clinical Research
https://read.qxmd.com/read/38632336/correlation-driven-nonequilibrium-exciton-site-transition-in-a-wse-2-ws-2-moir%C3%A3-supercell
#11
JOURNAL ARTICLE
Jinjae Kim, Jiwon Park, Hyojin Choi, Taeho Kim, Soonyoung Cha, Yewon Lee, Kenji Watanabe, Takashi Taniguchi, Jonghwan Kim, Moon-Ho Jo, Hyunyong Choi
Moiré superlattices of transition metal dichalcogenides offer a unique platform to explore correlated exciton physics with optical spectroscopy. Whereas the spatially modulated potentials evoke that the exciton resonances are distinct depending on a site in a moiré supercell, there have been no clear demonstration how the moiré excitons trapped in different sites dynamically interact with the doped carriers; so far the exciton-electron dynamic interactions were presumed to be site-dependent. Thus, the transient emergence of nonequilibrium correlations are open questions, but existing studies are limited to steady-state optical measurements...
April 17, 2024: Nature Communications
https://read.qxmd.com/read/38629431/strained-silicon-technology-non-destructive-high-lateral-resolution-characterization-through-tip-enhanced-raman-spectroscopy
#12
JOURNAL ARTICLE
Giancarlo La Penna, Chiara Mancini, Anacleto Proietti, Luca Buccini, Daniele Passeri, Narciso Gambacorti, Jérôme Richy, Marco Rossi
The semiconductor industry is undergoing a transformative phase, marked by the relentless drive for miniaturization and a constant demand for higher performance and energy efficiency. However, the reduction of metal-oxide-semiconductor field-effect transistor sizes for advanced technology nodes below 10 nm presents several challenges. In response, strained silicon technology has emerged as a key player, exploiting strain induction in the silicon crystal lattice to improve device performance. At the same time, there has been a growing need for characterization techniques that allow in-line monitoring of sample conditions during semiconductor manufacturing, as an alternative to traditional methods such as transmission electron microscopy or high-resolution X-ray diffraction, which have several limitations in terms of measurement time and sample destructiveness...
April 17, 2024: Applied Spectroscopy
https://read.qxmd.com/read/38628480/detection-of-sars-cov-2-n-protein-using-agnps-modified-aligned-silicon-nanowires-biosers-chip
#13
JOURNAL ARTICLE
Sadok Kouz, Amal Raouafi, Awatef Ouhibi, Nathalie Lorrain, Makram Essafi, Manel Mejri, Noureddine Raouafi, Adel Moadhen, Mohammed Guendouz
The SARS-CoV-2 (COVID-19) pandemic had a strong impact on societies and economies worldwide and tests for high-performance detection of SARS-CoV-2 biomarkers are still needed for potential future outbreaks of the disease. In this paper, we present the different steps for the design of an aptamer-based surface-enhanced Raman scattering (BioSERS) sensing chip capable of detecting the coronavirus nucleocapsid protein (N protein) in spiked phosphate-buffered solutions and real samples of human blood serum. Optimization of the preparation steps in terms of the aptamer concentration used for the functionalization of the silver nanoparticles, time for affixing the aptamer, incubation time with target protein, and insulation of the silver active surface with cysteamine, led to a sensitive BioSERS chip, which was able to detect the N protein in the range from 1 to 75 ng mL-1 in spiked phosphate-buffered solutions with a detection limit of 1 ng mL-1 within 30 min...
April 10, 2024: RSC Advances
https://read.qxmd.com/read/38626015/a-novel-improved-total-variation-algorithm-for-the-elimination-of-scratch-type-defects-in-high-voltage-cable-cross-sections
#14
JOURNAL ARTICLE
Aihua Yu, Lina Shan, Wen Zhu, Jing Jie, Beiping Hou
In the quality inspection process of high-voltage cables, several commonly used indicators include cable length, insulation thickness, and the number of conductors within the core. Among these factors, the count of conductors holds particular significance as a key determinant of cable quality. Machine vision technology has found extensive application in automatically detecting the number of conductors in cross-sectional images of high-voltage cables. However, the presence of scratch-type defects in cut high-voltage cable cross-sections can significantly compromise the precision of conductor count detection...
2024: PloS One
https://read.qxmd.com/read/38624129/enhanced-thermal-conductivity-of-epoxy-resin-by-incorporating-three-dimensional-boron-nitride-thermally-conductive-network
#15
JOURNAL ARTICLE
Xubin Wang, Changhai Zhang, Tiandong Zhang, Chao Tang, Qingguo Chi
Packaging insulation materials with high thermal conductivity and excellent dielectric properties are favorable to meet the high demand and rapid development of third generation power semiconductors. In this study, we propose to improve the thermal conductivity of epoxy resin (EP) by incorporating a three-dimensional boron nitride thermally conductive network. Detailedly, polyurethane foam (PU) was used as a supporter, and boron nitride nanosheets (BNNSs) were loaded onto the PU supporter through chemical bonding (BNNS@PU)...
April 21, 2024: Journal of Chemical Physics
https://read.qxmd.com/read/38621105/slow-light-enhanced-brillouin-scattering-with-integrated-bragg-grating
#16
JOURNAL ARTICLE
Mingyu Xu, Peng Lei, Yunhui Bai, Zhangyuan Chen, Xiaopeng Xie
Advancements in photonic integration technology have enabled the effective excitation of simulated Brillouin scattering (SBS) on a single chip, boosting Brillouin-based applications such as microwave photonic signal processing, narrow-linewidth lasers, and optical sensing. However, on-chip circuits still require large pump power and centimeter-scale waveguide length to achieve a considerable Brillouin gain, making them both power-inefficient and challenging for integration. Here, we exploit the slow-light effect to significantly enhance SBS, presenting the first, to the best of our knowledge, demonstration of a slow-light Brillouin-active waveguide on the silicon-on-insulator (SOI) platform...
April 15, 2024: Optics Letters
https://read.qxmd.com/read/38615326/controllable-synthesis-of-transferable-ultrathin-bi-2-ge-si-o-5-dielectric-alloys-with-composition-tunable-high-%C3%AE%C2%BA-properties
#17
JOURNAL ARTICLE
Jiabiao Chen, Zhaochao Liu, Zunxian Lv, Yameng Hou, Xiang Chen, Lan Lan, Tong-Huai Cheng, Lei Zhang, Yingnan Duan, Huixia Fu, Xuewen Fu, Feng Luo, Jinxiong Wu
Two-dimensional (2D) alloys hold great promise to serve as important components of 2D transistors, since their properties allow continuous regulation by varying their compositions. However, previous studies are mainly limited to the metallic/semiconducting ones as contact/channel materials, but very few are related to the insulating dielectrics. Here, we use a facile one-step chemical vapor deposition (CVD) method to synthesize ultrathin Bi2 Si x Ge1- x O5 dielectric alloys, whose composition is tunable over the full range of x just by changing the relative ratios of the GeO2 /SiO2 precursors...
April 14, 2024: Journal of the American Chemical Society
https://read.qxmd.com/read/38612138/regenerative-superhydrophobic-coatings-for-enhanced-performance-and-durability-of-high-voltage-electrical-insulators-in-cold-climates
#18
JOURNAL ARTICLE
Helya Khademsameni, Reza Jafari, Anahita Allahdini, Gelareh Momen
Superhydrophobic coatings can be a suitable solution for protecting vulnerable electrical infrastructures in regions with severe meteorological conditions. Regenerative superhydrophobicity, the ability to regain superhydrophobicity after being compromised or degraded, could address the issue of the low durability of these coatings. In this study, we fabricated a superhydrophobic coating comprising hydrophobic aerogel microparticles and polydimethylsiloxane (PDMS)-modified silica nanoparticles within a PDMS matrix containing trifluoropropyl POSS (F-POSS) and XIAMETER PMX-series silicone oil as superhydrophobicity-regenerating agents...
April 2, 2024: Materials
https://read.qxmd.com/read/38612131/engineering-heterostructured-fe-co-p-arrays-for-robust-sodium-storage
#19
JOURNAL ARTICLE
Zidi Xiao, Lin Gao, Shaohui Li
Transition metal phosphides attract extensive concerns thanks to their high theoretical capacity in sodium ion batteries (SIBs). Nevertheless, the substantial volume fluctuation of metal phosphides during cycling leads to severe capacity decay, which largely hinders their large-scale deployment. In this regard, heterostructured Fe-Co-P (FeP/Co2 P) arrays are firstly constructed in this work for SIBs. The novel self-supported construction without insulated binders favors fast charge migration and Na+ ion diffusion...
April 1, 2024: Materials
https://read.qxmd.com/read/38612064/fabrication-of-metal-contacts-on-silicon-nanopillars-the-role-of-surface-termination-and-defectivity
#20
JOURNAL ARTICLE
Federico Giulio, Antonio Mazzacua, Luca Calciati, Dario Narducci
The application of nanotechnology in developing novel thermoelectric materials has yielded remarkable advancements in material efficiency. In many instances, dimensional constraints have resulted in a beneficial decoupling of thermal conductivity and power factor, leading to large increases in the achievable thermoelectric figure of merit (ZT). For instance, the ZT of silicon increases by nearly two orders of magnitude when transitioning from bulk single crystals to nanowires. Metal-assisted chemical etching offers a viable, low-cost route for preparing silicon nanopillars for use in thermoelectric devices...
March 28, 2024: Materials
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