Yulong Zheng, Rahul Venkatesh, Connor P Callaway, Campbell Viersen, Kehinde H Fagbohungbe, Aaron L Liu, Chad Risko, Elsa Reichmanis, Carlos Silva-Acuña
Linear and nonlinear optical line shapes reveal details of excitonic structure in polymer semiconductors. We implement absorption, photoluminescence, and transient absorption spectroscopies in DPP-DTT, an electron push-pull copolymer, to explore the relationship between their spectral line shapes and chain conformation, deduced from resonance Raman spectroscopy and from ab initio calculations. The viscosity of precursor polymer solutions before film casting displays a transition that suggests gel formation above a critical concentration...
December 12, 2023: Chemistry of Materials: a Publication of the American Chemical Society