Meijia Xu, Zheng-Yang Hu, Xiaoyang Liang, Yifan Zhu, Honghe Ding, Jun Hu, Jinfeng Xu, Zhen Zhu, Zi-Ang Wu, Xinwei Zhao, Weijun Guo, Kaiqi Nie, Yifan Ye, Junfa Zhu, Zhi-Pan Liu, Xiong Zhou, Kai Wu
Acetylene production from mixed α-olefins emerges as a potentially green and energy-efficient approach with significant scientific value in the selective cleavage of C-C bonds. On the Pd(100) surface, it is experimentally revealed that C2 to C4 α-olefins undergo selective thermal cleavage to form surface acetylene and hydrogen. The high selectivity toward acetylene is attributed to the 4-fold hollow sites which are adept at severing the terminal double bonds in α-olefins to produce acetylene...
April 22, 2024: Journal of the American Chemical Society