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Lithium ion battery

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https://www.readbyqxmd.com/read/28926687/advanced-nanostructured-anode-materials-for-sodium-ion-batteries
#1
REVIEW
Qidi Wang, Chenglong Zhao, Yaxiang Lu, Yunming Li, Yuheng Zheng, Yuruo Qi, Xiaohui Rong, Liwei Jiang, Xinguo Qi, Yuanjun Shao, Du Pan, Baohua Li, Yong-Sheng Hu, Liquan Chen
Sodium-ion batteries (NIBs), due to the advantages of low cost and relatively high safety, have attracted widespread attention all over the world, making them a promising candidate for large-scale energy storage systems. However, the inherent lower energy density to lithium-ion batteries is the issue that should be further investigated and optimized. Toward the grid-level energy storage applications, designing and discovering appropriate anode materials for NIBs are of great concern. Although many efforts on the improvements and innovations are achieved, several challenges still limit the current requirements of the large-scale application, including low energy/power densities, moderate cycle performance, and the low initial Coulombic efficiency...
September 19, 2017: Small
https://www.readbyqxmd.com/read/28926228/facile-synthesis-of-unique-cellulose-triacetate-based-flexible-and-high-performance-gel-polymer-electrolyte-for-lithium-ion-batteries
#2
Trupti Nirmale, Indrapal Karbhal, Ramchandra S Kalubarme, Manjusha V Shelke, Anjani J Varma, Bharat Bhanudas Kale
Lithium ion batteries (LIBs) with polymer based electrolytes have attracted huge attention due to the possibility of fabricating intrinsically safer and flexible devices. However, economical and eco-friendly sustainable technology is an oncoming challenge to fulfill the ever increasing demand. To circumvent this issue, we have developed gel polymer electrolyte (GPE) based on renewable polymers like cellulose triacetate (CTA) and poly (polyethylene glycol methacrylate) p(PEGMA) by using a photo polymerization technique...
September 19, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28926220/facile-construction-of-novel-3-dimensional-graphene-amorphous-porous-carbon-hybrids-with-enhanced-lithium-storage-properties
#3
Daming Zhu, Huaqiu Liu, Lixuan Tai, Xiaonan Zhang, Sheng Jiang, Shumin Yang, Lin Yi, Wen Wen, Xiaolong Li
Nowadays, porous materials become essential to many technological applications. In this account, 3-dimensional skeleton composite materials consisted of a core-shell amorphous porous carbon/multi-layer graphene are synthesized by chemical vapor deposition on Ni foam using a facile one-step growth method. The data suggest that these composites have not only outstanding electrical and mechanical properties of the multi-layer graphene but also the mesoporous characteristics of the amorphous carbon. Moreover, the composited carbon materials perfectly inherit the macroporous structure of Ni foam, and the amorphous carbon core in the skeleton serves as a cushion to buffer the volume variation after the removal of Ni...
September 19, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28926060/mg-doped-li2fesio4-c-nanocomposites-synthesized-by-the-solvothermal-method-for-lithium-ion-batteries
#4
Ajay Kumar, O D Jayakumar, Jagannath, Parisa Bashiri, G A Nazri, Vaman M Naik, Ratna Naik
A series of porous Li2Fe1-xMgxSiO4/C (x = 0, 0.01, 0.02, 0.04) nanocomposites (LFS/C, 1Mg-LFS/C, 2Mg-LFS and 4Mg-LFS/C) have been synthesized via a solvo-thermal method using the Pluronic P123 polymer as an in situ carbon source. Rietveld refinement of the X-ray diffraction data of Li2Fe1-xMgxSiO4/C composites confirms the formation of the monoclinic P21 structure of Li2FeSiO4. The addition of Mg facilitates the growth of impurity-free Li2FeSiO4 with increased crystallinity and particle size. Despite having the same percentage of carbon content (∼15 wt%) in all the samples, the 1Mg-LFS/C nanocomposite delivered the highest initial discharge capacity of 278 mA h g(-1) (∼84% of the theoretical capacity) at the C/30 rate and also exhibited the best rate capability and cycle stability (94% retention after 100 charge-discharge cycles at 1C)...
September 19, 2017: Dalton Transactions: An International Journal of Inorganic Chemistry
https://www.readbyqxmd.com/read/28926044/running-out-of-lithium-a-route-to-differentiate-between-capacity-losses-and-active-lithium-losses-in-lithium-ion-batteries
#5
Florian Holtstiege, Andrea Wilken, Martin Winter, Tobias Placke
Active lithium loss (ALL) resulting in a capacity loss (QALL), which is caused by lithium consuming parasitic reactions like SEI formation, is a major reason for capacity fading and, thus, for a reduction of the usable energy density of lithium-ion batteries (LIBs). QALL is often equated with the accumulated irreversible capacity (QAIC). However, QAIC is also influenced by non-lithium consuming parasitic reactions, which do not reduce the active lithium content of the cell, but induce a parasitic current. In this work, a novel approach is proposed in order to differentiate between QAIC and QALL...
September 19, 2017: Physical Chemistry Chemical Physics: PCCP
https://www.readbyqxmd.com/read/28925924/in-situ-preparation-of-fe-sub-3-sub-o-sub-4-sub-in-a-carbon-hybrid-of-graphene-nanoscrolls-and-carbon-nanotubes-as-high-performance-anode-material-for-lithium-ion-batteries
#6
Yuewen Liu, Ahmad Hassan Siddique, Heran Huang, Qile Fang, Wei Deng, Xufeng Zhou, Huanming Lu, Z P Liu
A new conductive carbon hybrid combining both graphene nanoscrolls and carbon nanotubes (rGNSs-CNTs) is prepared, and used to host Fe3O4 nanoparticles through an in situ synthesis method. As an anode material for LIBs, the obtained Fe3O4@rGNSs-CNTs shows good electrochemical performance. At a current density of 0.1 A g-1, the anode material shows a high reversible capacity of 1232.9 mAh g-1 after 100 cycles. Even at a current density of 1 A g-1, it still achieves a high reversible capacity of 812.3 mAh g-1 after 200 cycles...
September 19, 2017: Nanotechnology
https://www.readbyqxmd.com/read/28925694/polyoxometalates-templated-metal-ag-carbene-frameworks-anodic-material-for-lithium-ion-batteries
#7
Jingquan Sha, Peipei Zhu, Xiya Yang, Xueni Li, Xiao Li, Mingbo Yue, Kunfeng Zhou
A POMs templated 3D Ag-carbene framework with lvt-a topology was hydrothermally synthesized. The POMs templated MCF combining the advantages of POMs, MOFs, and carbene not only shows excellent thermal and chemical stabilities but also possesses a good discharge capacity of 481 mAh·g(-1) after 100 cycles applied as anode material in LIBs.
September 19, 2017: Inorganic Chemistry
https://www.readbyqxmd.com/read/28922572/s-doped-tise2-nanoplates-fe3-o4-nanoparticles-heterostructure
#8
Jun Yang, Yufei Zhang, Yizhou Zhang, Jinjun Shao, Hongbo Geng, Yu Zhang, Yun Zheng, Mani Ulaganathan, Zhengfei Dai, Bing Li, Yun Zong, Xiaochen Dong, Qingyu Yan, Wei Huang
2D Sulfur-doped TiSe2 /Fe3 O4 (named as S-TiSe2 /Fe3 O4 ) heterostructures are synthesized successfully based on a facile oil phase process. The Fe3 O4 nanoparticles, with an average size of 8 nm, grow uniformly on the surface of S-doped TiSe2 (named as S-TiSe2 ) nanoplates (300 nm in diameter and 15 nm in thickness). These heterostructures combine the advantages of both S-TiSe2 with good electrical conductivity and Fe3 O4 with high theoretical Li storage capacity. As demonstrated potential applications for energy storage, the S-TiSe2 /Fe3 O4 heterostructures possess high reversible capacities (707...
September 18, 2017: Small
https://www.readbyqxmd.com/read/28922528/mass-production-and-pore-size-control-of-holey-carbon-microcages
#9
Lei Zhang, Xiaoxiao Liu, Yuhai Dou, Binwei Zhang, Huiling Yang, Shixue Dou, Huakun Liu, Yunhui Huang, Xianluo Hu
Architectural control of porous solids, such as porous carbon cages, has received considerable attention for versatile applications because of their attractive ability to interact with liquids and gases not only at the surface, but throughout the bulk. Here we report a scalable, facile spray-pyrolysis route to synthesize holey carbon microcages with mosquito-net-like shells. Using the surfaces of water droplets as the growth templates, styrene-butadiene rubber macromolecules are controllably cross-linked, and size-tunable holes on the carbon shells are generated...
September 18, 2017: Angewandte Chemie
https://www.readbyqxmd.com/read/28920941/reversible-magnesium-and-aluminium-ions-insertion-in-cation-deficient-anatase-tio2
#10
Toshinari Koketsu, Jiwei Ma, Benjamin J Morgan, Monique Body, Christophe Legein, Walid Dachraoui, Mattia Giannini, Arnaud Demortière, Mathieu Salanne, François Dardoize, Henri Groult, Olaf J Borkiewicz, Karena W Chapman, Peter Strasser, Damien Dambournet
In contrast to monovalent lithium or sodium ions, the reversible insertion of multivalent ions such as Mg(2+) and Al(3+) into electrode materials remains an elusive goal. Here, we demonstrate a new strategy to achieve reversible Mg(2+) and Al(3+) insertion in anatase TiO2, achieved through aliovalent doping, to introduce a large number of titanium vacancies that act as intercalation sites. We present a broad range of experimental and theoretical characterizations that show a preferential insertion of multivalent ions into titanium vacancies, allowing a much greater capacity to be obtained compared to pure TiO2...
September 18, 2017: Nature Materials
https://www.readbyqxmd.com/read/28920669/in-situ-studies-of-solid-electrolyte-interphase-sei-formation-on-crystalline-carbon-surfaces-by-neutron-reflectometry-and-atomic-force-microscopy
#11
Miriam Steinhauer, Michael Stich, Mario Kurniawan, Beatrix-Kamelia Seidlhofer, Marcus Trapp, Andreas Bund, Norbert Wagner, K Andreas Friedrich
The solid electrolyte interphase (SEI) is a complex and fragile passivation layer with crucial importance for the functionality of lithium-ion batteries. Due to its fragility and reactivity, the use of in situ techniques is preferable for the determination of the SEI's true structure and morphology during its formation. In this study, we use in situ neutron reflectometry (NR) and in situ atomic force microscopy (AFM) to investigate the SEI formation on a carbon surface. It was found that a lithium rich adsorption layer is already present at the open circuit voltage on the carbon sample surface and that the first decomposition products start to deposit close to this potential...
September 18, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28920625/simultaneous-modulation-of-surface-composition-oxygen-vacancies-and-assembly-in-hierarchical-co3o4-mesoporous-nanostructures-for-lithium-storage-and-electrocatalytic-oxygen-evolution
#12
Hongyu Sun, Yanyan Zhao, Kristian Mølhave, Minwei Zhang, Jingdong Zhang
We developed a facile solution reductive method to simultaneously tune the surface composition, oxygen vacancies and three dimensional assembly in Co3O4 hierarchical nanostructures. The controllable surface composition, oxygen vacancies together with hierarchical micro/nanoarchitectures resulted in superior electrochemical properties when used as the anode materials for lithium-ion batteries and as an electrocatalyst for the oxygen evolution reaction. The excellent electrochemical performance is attributed to the synergistic effects of novel hierarchical morphology, crystal structure of the active materials, the improvement of intrinsic conductivity and inner surface area induced by the oxygen vacancies...
September 18, 2017: Nanoscale
https://www.readbyqxmd.com/read/28920439/multi-material-3d-printing-of-graphene-based-electrodes-for-electrochemical-energy-storage-using-thermo-responsive-inks
#13
Victoria García Rocha, Esther Garcia-Tunon, Cristina Botas, Foivos Markoulidis, Ezra Feilden, Eleonora D'Elia, Na Ni, Milo Sebastian Peter Shaffer, Eduardo Saiz
The current lifestyles, increasing population and limited resources result in energy research being at the forefront of worldwide grand challenges, increasing the demand for sustainable and more efficient energy devices. In this context, Additive Manufacturing brings the possibility of making electrodes and electrical energy storage (EES) devices in any desired 3D shape and dimensions, while preserving the multifunctional properties of the active materials in terms of surface area and conductivity. This paves the way to optimized and more efficient designs for energy devices...
September 18, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28917860/carbon-materials-derived-from-chitosan-cellulose-cryogel-supported-zeolite-imidazole-frameworks-for-potential-supercapacitor-application
#14
Zehui Li, Lan Yang, Hongbin Cao, Yu Chang, Kexin Tang, Zhiqin Cao, Junjun Chang, Youpeng Cao, Wenbo Wang, Meng Gao, Chenming Liu, Dagang Liu, He Zhao, Yi Zhang, Mingjie Li
In order to promote sustainable development, green and renewable clean energy technologies continue to be developed to meet the growing demand for energy, such as supercapacitor, fuel cells and lithium-ion battery. It is urgent to develop appropriate nanomaterials for these energy technologies to reduce the volume of the device, improve the efficiency of energy conversion and enlarge the energy storage capacity. Here, chitosan/cellulose carbon cryogel (CCS/CCL) were designed and synthesized. Through the introduction of zeolite imidazole frameworks (ZIFs) into the chitosan/cellulose cryogels, the obtained materials showed a microstructure of ZIF-7 (a kind of ZIFs) coated chitosan/cellulose fibers (CS/CL)...
November 1, 2017: Carbohydrate Polymers
https://www.readbyqxmd.com/read/28915483/sulphur-and-nitrogen-dual-doped-mesoporous-carbon-hybrid-coupling-with-graphite-coated-cobalt-and-cobalt-sulfide-nanoparticles-rational-synthesis-and-advanced-multifunctional-electrochemical-properties
#15
Anquan Zhu, Pengfei Tan, Lulu Qiao, Yi Liu, Yongjin Ma, Jun Pan
Doping-type carbon matrixes not only play a vital role on their electrochemical properties, but also are capable of suppressing the crush and aggregation phenomenon in the electrode reaction process for pristine metallic compound. Herein, graphite coated cobalt and cobalt sulfide nanoparticles decorating on sulphur and nitrogen dual-doped mesoporous carbon (Co@Co9S8/S-N-C) was fabricated by a combined hydrothermal reaction with pyrolysis method. Benefited from g-C3N4 template and original synthetic route, as-obtained Co@Co9S8/S-N-C possessed high specific surface area (751...
September 8, 2017: Journal of Colloid and Interface Science
https://www.readbyqxmd.com/read/28915021/novel-approach-for-in-situ-recovery-of-lithium-carbonate-from-spent-lithium-ion-batteries-using-vacuum-metallurgy
#16
Jiefeng Xiao, Jia Li, Zhenming Xu
Lithium is a rare metal because of geographical scarcity and technical barrier. Recycling lithium resource from spent lithium ion batteries (LIBs) is significant for lithium deficiency and environmental protection. A novel approach for recycling lithium element as Li2CO3 from spent LIBs is proposed. Firstly, the electrode materials pre-obtained by mechanical separation are pyrolyzed under inclosed vacuum condition. During this process, the Li is released as Li2CO3 from the crystal structure of lithium transition metal oxides due to the collapse of oxygen-framework...
September 15, 2017: Environmental Science & Technology
https://www.readbyqxmd.com/read/28915007/synthesis-and-properties-of-2d-carbon-graphdiyne
#17
Zhiyu Jia, Yongjun Li, Zicheng Zuo, Huibiao Liu, Changshui Huang, Yuliang Li
Graphdiyne (GDY) is a flat material comprising sp(2)- and sp-hybridized carbon atoms with high degrees of π conjugation that features uniformly distributed pores. It is interesting not only from a structural point of view but also from the perspective of its electronic, chemical, mechanical, and magnetic properties. We have developed an in situ homocoupling reaction of hexaethynylbenzene on Cu foil for the fabrication of large-area ordered films of graphdiyne. These films are uniform and composed of graphdiyne multilayers...
September 15, 2017: Accounts of Chemical Research
https://www.readbyqxmd.com/read/28914945/amorphous-crystalline-hybrid-moo2-nanosheets-for-high-energy-lithium-ion-capacitors
#18
Xu Zhao, Hong-En Wang, Jian Cao, Wei Cai, Jiehe Sui
A carbon-free MoO2 nanosheet with amorphous/crystalline hybrid domain was synthesized, and demonstrated to be an efficient host material for lithium-ion capacitors. Discrepant crystallinity in MoO2 shows unique boundaries, which can improve Li-ion diffusion through the electrode. Improved rate capacities and cycling stability open the door to design of high-performance lithium ion capacitor bridging batteries and supercapacitors.
September 15, 2017: Chemical Communications: Chem Comm
https://www.readbyqxmd.com/read/28914490/a-catalytic-microwave-process-for-superfast-preparation-of-high-quality-reduced-graphene-oxide
#19
Runze Liu, Yu Zhang, Zhenjian Ning, Yuxi Xu
Herein we report that a small amount of graphite can unexpectedly act as the catalyst to greatly promote the microwave exfoliation and reduction of graphite oxide in ambient air. The reaction can be finished in a few seconds in contrast to more than ten minutes without catalyst. Meanwhile, the catalytic microwave exfoliated graphite oxide (CMEGO) shows much better quality than the traditional microwave exfoliated graphite oxide, including a much higher exfoliation degree with thinner graphene sheets and higher specific surface area (886 m2/g vs 466 m2/g), a much larger C/O ratio (19...
September 15, 2017: Angewandte Chemie
https://www.readbyqxmd.com/read/28910075/mechanochemical-synthesis-of-pedot-pss-hydrogels-for-aqueous-formulation-of-li-ion-battery-electrodes
#20
Georgiana Sandu, Bruno Ernould, Julien Rolland, Nathalie Cheminet, Jeremy Brassinne, Pratik Das, Yaroslav Filinchuk, Luhua Cheng, Lidiya Komsiyska, Philippe Dubois, Sorin Melinte, Jean-François Gohy, Roberto Lazzaroni, Alexandru Vlad
Water-soluble binders can enable greener and cost effective Li-ion battery manufacturing by eliminating the standard fluorine-based formulations and associated organic solvents. The issue with water-based dispersions, however, remains the difficulty to stabilize them, requiring additional processing complexity. Herein, we show that mechanochemical conversion of a regular poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) water-based dispersion produces a hydrogel that meets all the requirements as binder for lithium-ion battery electrode manufacture...
September 14, 2017: ACS Applied Materials & Interfaces
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