María Andérez-Fernández, Lydia K Vogt, Steffen Fischer, Wei Zhou, Haijun Jiao, Marcel Garbe, Saravanakumar Elangovan, Kathrin Junge, Henrik Junge, Ralf Ludwig, Matthias Beller
For the first time, structurally defined manganese pincer complexes catalyze the dehydrogenation of aqueous methanol to hydrogen and carbon dioxide, which is a transformation of interest with regard to the implementation of a hydrogen and methanol economy. Excellent long-term stability was demonstrated for the Mn-PNPiPr catalyst, as a turnover of more than 20 000 was reached. In addition to methanol, other important hydrogen carriers were also successfully dehydrogenated.
December 2, 2016: Angewandte Chemie