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Water electrolytes

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https://www.readbyqxmd.com/read/28732164/electrochemical-intercalation-of-mg-2-into-anhydrous-and-hydrated-crystalline-tungsten-oxides
#1
Ruocun Wang, Ching-Chang Chung, Yang Liu, Jacob L Jones, Veronica Augustyn
The reversible intercalation of multivalent cations, especially Mg(2+), into a solid-state electrode is an attractive mechanism for next-generation energy storage devices. These reactions typically exhibit poor kinetics due to a high activation energy for interfacial charge-transfer and slow solid-state diffusion. Interlayer water in V2O5 and MnO2 has been shown to improve Mg(2+) intercalation kinetics in non-aqueous electrolytes. Here, the effect of structural water on Mg(2+) intercalation in non-aqueous electrolytes is examined in crystalline WO3 and the related hydrated and layered WO3·nH2O (n = 1, 2)...
July 21, 2017: Langmuir: the ACS Journal of Surfaces and Colloids
https://www.readbyqxmd.com/read/28731319/few-layered-mo-1-x-wxs2-hollow-nanospheres-on-ni3s2-nanorods-heterostructure-as-robust-electrocatalysts-for-overall-water-splitting
#2
Meiyong Zheng, Jing Du, Baopu Hou, Cai-Ling Xu
Owing to the unique optical, electronic and catalytic properties, MoS2 have received increasing interests in electrochemical water splitting. Herein, few-layered Mo(1-x)WxS2 hollow nanospheres modified Ni3S2 heterostructures are prepared through a facile hydrothermal method to further enhance the electro-catalytic performance of MoS2. The doping of W element optimizes the electronic structure of MoS2@Ni3S2, thus improves the conductivity and charge transfer ability of MoS2@Ni3S2. In addition, benefiting from the few-layered hollow structure of Mo(1-x)WxS2, the strong electronic interactions between Mo(1-x)WxS2 and Ni3S2, and the hierarchical structure of 1D nanorods and 3D Ni foam, massive active sites and fast ion and charge transportion are obtained...
July 21, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28729970/severe-cyclophosphamide-related-hyponatremia-in-a-patient-with-acute-glomerulonephritis
#3
Pasquale Esposito, Maria Valentina Domenech, Nicoletta Serpieri, Marta Calatroni, Ilaria Massa, Alessandro Avella, Edoardo La Porta, Luca Estienne, Elena Caramella, Teresa Rampino
Cyclophosphamide is frequently used to treat cancer, autoimmune and renal diseases, such as rapidly progressive glomerulonephritis. Its side effects are well-known, including bone marrow depression, infections, alopecia, sterility, bladder malignancy and hemorrhagic cystitis. Moreover, in some cases cyclophosphamide use has been related to the onset of hyponatremia, by development of a syndrome of inappropriate antidiuresis. Indeed, severe hyponatremia has been previously reported in patients treated with high-dose or moderate-dose of intravenous cyclophosphamide, while only few cases have been reported in patients treated with low dose...
July 6, 2017: World Journal of Nephrology
https://www.readbyqxmd.com/read/28728113/catalase-based-hydrogen-peroxide-biosensor-for-mercury-determination-by-inhibition-measurements
#4
Basant Elsebai, Mariana Emilia Ghica, Mohammed Nooredeen Abbas, Christopher M A Brett
A new amperometric hydrogen peroxide enzyme inhibition biosensor for the indirect determination of toxic mercury ions, Hg(2+), based on catalase immobilized on a glassy carbon electrode surface by cross-linking with glutaraldehyde and bovine serum albumin, is reported. The parameters influencing biosensor performance were optimized, including enzyme loading, the amount of hydrogen peroxide, the applied potential and electrolyte pH. It was shown that the inhibition of catalase by Hg(2+) species is irreversible, with a linear inhibition response between 5×10(-11) and 5×10(-10)M...
July 11, 2017: Journal of Hazardous Materials
https://www.readbyqxmd.com/read/28726969/a-fiber-asymmetric-supercapacitor-based-on-feooh-ppy-on-carbon-fibers-as-an-anode-electrode-with-high-volumetric-energy-density-for-wearable-applications
#5
Xuefei Gong, Shaohui Li, Pooi See Lee
Fiber supercapacitors are promising energy storage devices for wearable applications. However, the fiber supercapacitors are currently limited by the mediocre capacitance performances due to the use of typical carbon materials as the anode, sacrificing the volumetric energy density of the whole device. In addition, the inability to undergo washable cycles and poor self-discharge rate prevents the fiber-shaped supercapacitors from being a true energy textile and affects their practicability. Hence, the porous anode electrode FeOOH/PPy@CF has been firstly prepared with a high volumetric capacitance of 30...
July 20, 2017: Nanoscale
https://www.readbyqxmd.com/read/28725324/cardiorenal-syndrome-role-of-arginine-vasopressin-and-vaptans-in-heart-failure
#6
REVIEW
Poornima Vinod, Vinod Krishnappa, Abigail M Chauvin, Anshika Khare, Rupesh Raina
Heart and kidney failure continued to be of increasing prevalence in today's society, and their comorbidity has synergistic effect on the morbidity and mortality of patients. Cardiorenal syndrome (CRS) is a complex disease with multifactorial pathophysiology. Better understanding of this pathophysiological network is crucial for the successful intervention to prevent advancement of the disease process. One of the major factors in this process is neurohormonal activation, predominantly involving renin-angiotensin-aldosterone system (RAAS) and arginine vasopressin (AVP)...
June 2017: Cardiology Research
https://www.readbyqxmd.com/read/28723154/interruption-of-hydrogen-bonding-networks-of-water-in-carbon-nanotubes-due-to-strong-hydration-shell-formation
#7
Yoshifumi Oya, Kenji Hata, Tomonori Ohba
We present the structures of NaCl aqueous solution in carbon nanotubes with diameters of 1, 2, and 3 nm based on an analysis performed using X-ray diffraction and canonical ensemble Monte Carlo simulations. Anomalously longer nearest-neighbor distances were observed in the electrolyte for the 1-nm-diameter carbon nanotubes; in contrast, in the 2 and 3 nm carbon nanotubes, the nearest-neighbor distances were shorter than those in the bulk electrolyte. We also observed similar properties for water in carbon nanotubes, which was expected because the main component of the electrolyte was water...
July 19, 2017: Langmuir: the ACS Journal of Surfaces and Colloids
https://www.readbyqxmd.com/read/28722787/synthesis-and-direct-sintering-of-nanosized-miv-miii-o2-x-hydrated-oxides-as-electrolyte-ceramics
#8
Nicolas Clavier, Yanis Cherkaski, Julien Martinez, Sophie Costis, Théo Cordara, Fabienne Audubert, Laurent Brissonneau, Nicolas Dacheux
Highly reactive and nanosized Th1-xYxO2-x/2 or Ce0.8Ln0.2O1.9 mixed oxides were prepared through the initial precipitation of hydroxide precursors which were further dried under vacuum. Whatever the chemical system investigated, the characterization of the powdered samples evidenced a rapid aging process leading to hydrated oxides. The thermal behavior of these samples was further investigated and first showed a two-step dehydration process, with the successive departure of adsorbed then constitutive water, both yielding a drastic drop of the powders reactivity (i...
July 19, 2017: Chemphyschem: a European Journal of Chemical Physics and Physical Chemistry
https://www.readbyqxmd.com/read/28722461/-disorders-of-water-and-electrolyte-metabolism-and-changes-in-acid-base-balance-in-patients-with-ascitic-liver-cirrhosis
#9
Halima Gottfriedová, Miroslava Horáčková, Milena Čáslavská, Julius Špičák, Otto Schück
In patients with advanced cirrhosis with ascites disorders of water and electrolyte metabolism are often present and they are associated with changes in acid-base balance. These changes can be very complicated, their diagnosis and treatment difficult. Dilutional hyponatremia is the most common disorder. Hyponatremia in these patients is associated with increased morbidity and mortality before and after liver transplantation. Other common disorders include hyperchloremic acidosis, hypokalemia, metabolic alkalosis, lactic acidosis, respiratory alkalosis...
2017: Casopís Lékar̆ů C̆eských
https://www.readbyqxmd.com/read/28721942/induced-dipole-in-vanadium-doped-zinc-oxide-nanosheets-and-its-effects-on-photoelectrochemical-water-splitting
#10
Song Mi Lee, Sung-Ho Shin, Junghyo Nah, Min Hyung Lee
Appropriate control of energy band bending at the interface between semiconductors and electrolytes are closely related to performance of photoelectrochemical (PEC) water splitting. Dipoles formed near the surface of semiconductors induces energy band bending at the interface. Energy band bending control has been demonstrated by employing charged molecules and piezoelectric materials. However, chemical and piezoelectric approaches have demerit of chemical instability and inducement of instantaneous dipole, respectively...
July 19, 2017: Nanotechnology
https://www.readbyqxmd.com/read/28721404/accurate-determination-of-the-charge-transfer-efficiency-of-photoanodes-for-solar-water-splitting
#11
Dino Klotz, Daniel A Grave, Avner Rothschild
The oxygen evolution reaction (OER) at the surface of semiconductor photoanodes is critical for photoelectrochemical water splitting. This reaction involves photo-generated holes that oxidize water via charge transfer at the photoanode/electrolyte interface. However, a certain fraction of the holes that reach the surface recombine with electrons from the conduction band, giving rise to the surface recombination loss. The charge transfer efficiency, ηt, defined as the ratio between the flux of holes that contribute to the water oxidation reaction and the total flux of holes that reach the surface, is an important parameter that helps to distinguish between bulk and surface recombination losses...
July 19, 2017: Physical Chemistry Chemical Physics: PCCP
https://www.readbyqxmd.com/read/28715742/development-of-high-performance-supercapacitor-electrode-derived-from-sugar-industry-spent-wash-waste
#12
Ashesh Mahto, Rajeev Gupta, Krishna Kanta Ghara, Divesh N Srivastava, Pratyush Maiti, Kalpana D, Paul Zavala-Revira, R Meena, S K Nataraj
This study aims at developing supercapacitor materials from sugar and distillery industry wastes, thereby mediating waste disposal problem through reuse. In a two-step process, biomethanated spent wash (BMSW) was acid treated to produce solid waste sludge and waste water with significantly reduced total organic carbon (TOC) and biological oxygen demand (BOD) content. Further, waste sludge was directly calcined in presence of activating agent ZnCl2 in inert atmosphere resulting in high surface area (730-900m(2)g(-1)) carbon of unique hexagonal morphology...
June 23, 2017: Journal of Hazardous Materials
https://www.readbyqxmd.com/read/28713194/drought-priming-improves-subsequent-more-severe-drought-in-a-drought-sensitive-cultivar-of-olive-cv-ch%C3%A3-toui
#13
Mariem Ben Abdallah, Kawther Methenni, Issam Nouairi, Mokhtar Zarrouk, Nabil Ben Youssef
Drought is a major factor limiting crop production worldwide. The objective of this study was to test whether pre-exposure to drought can enhance the subsequent drought response of a drought-sensitive variety of olive cv. Chétoui. Seven-months old olive plants were grown in a controlled conditions and divided into control plants (irrigated daily), primed plants (PP, primed by exposure to drought for 21 days, re-watered for 60 days and then exposed to water depletion for 30 days) and non-primed plants (NPP, well watered for 81 days and immediately followed by intermediate drought as PP)...
July 14, 2017: Scientia Horticulturae
https://www.readbyqxmd.com/read/28712552/insights-into-head-column-field-amplified-sample-stacking-part-ii-study-of-the-behavior-of-the-electrophoretic-system-after-electrokinetic-injection-of-cationic-compounds-across-a-short-water-plug
#14
Jozef Šesták, Wolfgang Thormann
Part I on head-column field-amplified sample stacking comprised a detailed study of the electrokinetic injection of a weak base across a short water plug into a phosphate buffer at low pH. The water plug is converted into a low conductive acidic zone and cationic analytes become stacked at the interface between this and a newly formed phosphoric acid zone. The fundamentals of electrokinetic processes occurring thereafter were studied experimentally and with computer simulation and are presented as part II. The configuration analyzed represents a discontinuous buffer system...
June 30, 2017: Journal of Chromatography. A
https://www.readbyqxmd.com/read/28710950/citric-acid-assisted-phytoextraction-of-chromium-by-sunflower-morpho-physiological-and-biochemical-alterations-in-plants
#15
Mujahid Farid, Shafaqat Ali, Muhammad Rizwan, Qasim Ali, Farhat Abbas, Syed Asad Hussain Bukhari, Rashid Saeed, Longhua Wu
Soil and water contamination from heavy metals and metalloids is one of the most discussed and burning global issues due to its potential to cause the scarcity of healthy food and safe water. The scientific community is proposing a range of lab and field based physical, chemical and biological solutions to remedy metals and metalloids contaminated soils and water. The present study finds out a possibility of Chromium (Cr) extraction by sunflower from spiked soil under chelating role of citric acid (CA). The sunflower plants were grown under different concentrations of Cr (0, 5, 10 & 20mgkg(-1)) and CA (0, 2...
July 12, 2017: Ecotoxicology and Environmental Safety
https://www.readbyqxmd.com/read/28710594/addressing-a-common-misconception-ammonium-acetate-as-neutral-ph-buffer-for-native-electrospray-mass-spectrometry
#16
Lars Konermann
Native ESI-MS involves the transfer of intact proteins and biomolecular complexes from solution into the gas phase. One potential pitfall is the occurrence of pH-induced changes that can affect the analyte while it is still surrounded by solvent. Most native ESI-MS studies employ neutral aqueous ammonium acetate solutions. It is a widely perpetuated misconception that ammonium acetate buffers the analyte solution at neutral pH. By definition, a buffer consists of a weak acid and its conjugate weak base. The buffering range covers the weak acid pKa ± 1 pH unit...
July 14, 2017: Journal of the American Society for Mass Spectrometry
https://www.readbyqxmd.com/read/28710130/dead-or-alive-using-membrane-failure-and-chlorophyll-fluorescence-to-predict-mortality-from-drought
#17
Carmela Rosaria Guadagno, Brent E Ewers, Heather N Speckman, Timothy L Aston, Bridger J Huhn, Stanley B DeVore, Joshua T Ladwig, Rachel N Strawn, Cynthia Weinig
Climate models predict widespread increases in both drought intensity and duration in the next decades. Although water deficiency is one of the greatest environmental pressures to plant survival, limited understanding of how plants respond to extreme drought impedes adequate forecasts of how increasing aridity will impact both forest and crop productivity. Drought induces a suite of physiological responses; however, we lack an accurate mechanistic description of plant response to lethal drought that would improve predictive understanding of the timing of lethal drought with climate change...
July 14, 2017: Plant Physiology
https://www.readbyqxmd.com/read/28709053/transport-and-retention-of-biochar-nanoparticles-in-a-paddy-soil-under-environmentally-relevant-solution-chemistry-conditions
#18
Ming Chen, Dengjun Wang, Fan Yang, Xiaoyun Xu, Nan Xu, Xinde Cao
Land application of biochar has been increasingly recommended as a powerful strategy for carbon sequestration and soil remediation. However, the biochar particles, especially those in the nanoscale range, may migrate or carry the inherent contaminants along the soil profile, posing a potential risk to the groundwater. This study investigated the transport and retention of wood chip-derived biochar nanoparticles (NPs) in water-saturated columns packed with a paddy soil. The environmentally-relevant soil solution chemistry including ionic strength (0...
July 11, 2017: Environmental Pollution
https://www.readbyqxmd.com/read/28705586/capillary-zone-electrophoresis-determination-of-aniline-and-pyridine-in-sewage-samples-using-transient-isotachophoresis-with-a-system-induced-terminator
#19
Takanari Hattori, Hideo Okamura, Satoshi Asaoka, Keiichi Fukushi
Transient isotachophoresis (tITP) with a system-induced terminator (SIT) was developed for capillary zone electrophoresis (CZE) determination of aniline (An(+)) and pyridine (Py(+)) in sewage samples. After sample injection, a water vial was set at the sample-inlet side. Then voltage was applied to generate a system-induced terminator (H(+)). Experiments and simulations revealed a concentration effect by tITP with an SIT: background electrolyte (BGE) - 100mM acetic acid (AcOH) and 50mM NaOH (pH 4.6); detection wavelength - 200nm for An(+) and 254nm for Py(+); vacuum injection period - 15s (190nL); SIT generation - 10kV applied for 80s with the sample inlet side anode; separation voltage - 20kV with the sample inlet side anode...
July 4, 2017: Journal of Chromatography. A
https://www.readbyqxmd.com/read/28702099/strategies-for-early-metabolic-disturbances-in-patients-with-an-end-jejunostomy-or-end-ileostomy-experience-from-a-specialized-home-parenteral-nutrition-hpn-center
#20
Michał Ławiński, Dominika Haraszczuk, Aleksandra Gradowska, Justyna Z Kostro, Agnieszka Bzikowska, Jacek Sobocki
INTRODUCTION: An end stoma syndrome is usually the result of an intentional surgical intervention in the course of staged treatment or a complication of surgery. These patients most frequently suffer from water and electrolyte disturbances, malnutrition syndromes caused by malabsorption of trace elements and/or vitamins, and undernutrition. AIM: To present early metabolic disturbances observed in patients with an end jejunostomy or end ileostomy syndrome on the first day of their hospitalization in a specialist Home Parenteral Nutrition (HPN) center...
2017: Przegla̜d Gastroenterologiczny
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