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https://www.readbyqxmd.com/read/28226212/h2s-modified-fe-ti-spinel-a-recyclable-magnetic-sorbent-for-recovering-gaseous-elemental-mercury-from-the-flue-gas-as-a-co-benefit-of-the-wet-electrostatic-precipitators
#1
Sijie Zou, Yong Liao, Shangchao Xiong, Nan Huang, Yang Geng, Shijian Yang
The non-recyclability of the sorbents used to capture Hg0 from the flue gas causes a high operation cost and the potential risk of exposure to Hg. The installment of wet electrostatic precipitators (WESPs) in coal-fired plants makes the recovery of spent sorbents for recycling and the centralized control of Hg pollution possible. In this work, H2S-modified Fe-Ti spinel was developed as a recyclable magnetic sorbent to recover Hg0 from the flue gas as a co-benefit of the WESP. Although Fe-Ti spinel exhibited poor Hg0 capture activity in the temperature range of the flue gas downstream of the flue gas desulfurization (FGD), H2S-modified Fe-Ti spinel exhibited excellent Hg0 capture performance with an average adsorption rate of 1...
February 22, 2017: Environmental Science & Technology
https://www.readbyqxmd.com/read/28225181/two-phase-reactions-in-microdroplets-without-the-use-of-phase-transfer-catalysts
#2
Xin Yan, Heyong Cheng, Richard N Zare
Many important chemical transformations occur in two-phase reactions, which are widely used in chemical, pharmaceutical, and polymer manufacturing. We present an efficient method for performing two-phase reactions in microdroplets sheared by sheath gas without using a phase-transfer catalyst. This avoids disadvantages such as thermal instability, high cost, and, especially, the need to separate and recycle the catalysts. We show that various alcohols can be oxidized to the corresponding aldehydes and ketones within milliseconds in moderate to good yields (50-75 %)...
February 22, 2017: Angewandte Chemie
https://www.readbyqxmd.com/read/28225130/systematic-investigation-on-the-intracellular-trafficking-network-of-polymeric-nanoparticles
#3
Jinxie Zhang, Danfeng Chang, Yao Yang, Xudong Zhang, Wei Tao, Lijuan Jiang, Xin Liang, Hsiangi Tsai, Laiqiang Huang, Lin Mei
Polymeric nanoparticles such as PLGA-based nanoparticles are emerging as promising carriers for controlled drug delivery. However, little is known about the intracellular trafficking network of polymeric nanoparticles. Here, more than 30 Rab proteins were used as markers of multiple trafficking vesicles in endocytosis, exocytosis and autophagy to investigate in detail the intracellular trafficking pathways of PLGA nanoparticles. We observed that coumarin-6-loaded PLGA nanoparticles were internalized by the cells mainly through caveolin and clathrin-dependent endocytosis and Rab34-mediated macropinocytosis...
February 22, 2017: Nanoscale
https://www.readbyqxmd.com/read/28225117/gold-nanoparticles-and-the-corresponding-filter-membrane-as-chemosensors-and-adsorbents-for-dual-signal-amplification-detection-and-fast-removal-of-mercury-ii
#4
Gaosong Chen, Jun Hai, Hao Wang, Weisheng Liu, Fengjuan Chen, Baodui Wang
Nowadays, the development of a multifunction system for the simultaneous multiple signal amplification detection and fast removal of Hg(2+) remains a major challenge. Herein, we for the first time used gold nanoparticles (Au NPs) and the corresponding filter membrane as chemosensors and adsorbents for dual signal amplification detection and fast removal of Hg(2+). Such a system was based on the formation of gold amalgam and a gold amalgam-based reaction between rhodamine B (RhB) and NaBH4 with fluorescence and colorimetric sensing functions...
February 22, 2017: Nanoscale
https://www.readbyqxmd.com/read/28224988/post-endocytic-sorting-of-plexin-d1-controls-signal-transduction-and-development-of-axonal-and-vascular-circuits
#5
Katja Burk, Erik Mire, Anaïs Bellon, Mélanie Hocine, Jeremy Guillot, Filipa Moraes, Yutaka Yoshida, Michael Simons, Sophie Chauvet, Fanny Mann
Local endocytic events involving receptors for axon guidance cues play a central role in controlling growth cone behaviour. Yet, little is known about the fate of internalized receptors, and whether the sorting events directing them to distinct endosomal pathways control guidance decisions. Here, we show that the receptor Plexin-D1 contains a sorting motif that interacts with the adaptor protein GIPC1 to facilitate transport to recycling endosomes. This sorting process promotes colocalization of Plexin-D1 with vesicular pools of active R-ras, leading to its inactivation...
February 22, 2017: Nature Communications
https://www.readbyqxmd.com/read/28224002/secretion-and-endocytosis-in-pollen-tubes-models-of-tip-growth-in-the-spot-light
#6
REVIEW
Gleb Grebnev, Maria Ntefidou, Benedikt Kost
Pollen tube tip growth is a widely used model ideally suited to study cellular processes underlying polarized cell expansion. Local secretion supplying material for plasma membrane (PM) and cell wall extension is essential for this process. Cell wall biogenesis requires fusion of secretory vesicles with the PM at an about 10× higher rate than PM extension. Excess material is therefore incorporated into the PM, which needs to be reinternalized through endocytosis. The classical model of tip growth proposes that exocytosis occurs at the apex and that newly incorporated PM material is transported to adjacent lateral regions, where excess material is endocytically recycled...
2017: Frontiers in Plant Science
https://www.readbyqxmd.com/read/28223451/mycobacterium-tuberculosis-proteasome-accessory-factor-a-pafa-can-transfer-prokaryotic-ubiquitin-like-protein-pup-between-substrates
#7
Susan Zhang, Kristin E Burns-Huang, Guido V Janssen, Huilin Li, Huib Ovaa, Lizbeth Hedstrom, K Heran Darwin
The protein degradation machinery of Mycobacterium tuberculosis includes a proteasome and a ubiquitin-like protein (Pup). Proteasome accessory factor A (PafA) attaches Pup to proteins to target them for degradation by the proteasome. Free Pup is unstable and never observed in extracts of M. tuberculosis, an observation that led us to hypothesize that PafA may need alternative sources of Pup. Here, we show that PafA can move Pup from one proteasome substrate, inositol 1-phosphate synthetase (Ino1), to two different proteins, malonyl coenzyme A (CoA)-acyl carrier protein transacylase (FabD) and lonely guy (Log)...
February 21, 2017: MBio
https://www.readbyqxmd.com/read/28223134/investigation-of-activity-and-stability-of-papain-by-adsorption-on-multi-wall-carbon-nanotubes
#8
Ahmad Homaei, Fayezeh Samari
Papain was non- covalently immobilized on multi-walled carbon nanotubes (MWCNTs). Its stabilities and catalytic activity for casein degradation were comprehensively investigated. Compared to free papain, the nano- enzyme exhibited significantly improved thermal, pH and recycling stability. Comparisons of the kinetic parameters between free papain and the heterogeneous enzyme revealed that the Km value of the immobilized papain experienced a slight increase, which suggested that the MWCNTs did not significantly hinder papain's access to substrate or release of product...
February 13, 2017: International Journal of Biological Macromolecules
https://www.readbyqxmd.com/read/28223133/bio-based-materials-with-novel-characteristics-for-tissue-engineering-applications-a-review
#9
REVIEW
Luis Bedian, Angel M Villalba Rodríguez, Gustavo Hernández Vargas, Roberto Parra-Saldivar, Hafiz M N Iqbal
Recently, a wider spectrum of bio-based materials and materials-based novel constructs and systems has been engineered with high interests. The key objective is to help for an enhanced/better quality of life in a secure way by avoiding/limiting various adverse effects of some in practice traditional therapies. In this context, different methodological approaches including in-vitro, in-vivo, and ex-vivo techniques have been exploited, so far. Among them, bio-based therapeutic constructs are of supreme interests for an enhanced and efficient delivery in the current biomedical sector of the modern world...
February 13, 2017: International Journal of Biological Macromolecules
https://www.readbyqxmd.com/read/28223080/novel-process-combining-anaerobic-aerobic-digestion-and-ion-exchange-resin-for-full-recycling-of-cassava-stillage-in-ethanol-fermentation
#10
Xinchao Yang, Ke Wang, Huijun Wang, Jianhua Zhang, Zhonggui Mao
A novel cleaner ethanol production process has been developed. Thin stillage is treated initially by anaerobic digestion followed by aerobic digestion and then further treated by chloride anion exchange resin. This allows the fully-digested and resin-treated stillage to be completely recycled for use as process water in the next ethanol fermentation batch, which eliminates wastewater discharges and minimizes consumption of fresh water. The method was evaluated at the laboratory scale. Process parameters were very similar to those found using tap water...
February 17, 2017: Waste Management
https://www.readbyqxmd.com/read/28223076/leaching-of-rare-earth-elements-from-fluorescent-powder-using-the-tea-fungus-kombucha
#11
Stefanie Hopfe, Katrin Flemming, Falk Lehmann, Robert Möckel, Sabine Kutschke, Katrin Pollmann
In most modern technologies such as flat screens, highly effective magnets and lasers, as well as luminescence phosphors, Rare Earth Elements (REE) are used. Unfortunately no environmentally friendly recycling process exists so far. In comparison to other elements the interaction of microorganisms with REE has been studied to a less extent. However, as REE are ubiquitously present in nature it can be assumed that microorganisms play an important role in the biogeochemistry of REE. This study investigates the potential of organic acid-producing microbes for extracting REE from industrial waste...
February 17, 2017: Waste Management
https://www.readbyqxmd.com/read/28223075/gender-perspective-on-the-factors-predicting-recycling-behavior-implications-from-the-theory-of-planned-behavior
#12
Ceren Oztekin, Gaye Teksöz, Savas Pamuk, Elvan Sahin, Dilek Sultan Kilic
This study aimed to assess the role of some socio-psychological attributes in explaining recycling behavior of Turkish university community from a gender perspective within the context of the theory of planned behavior with an additional variable (past experience). The recycling behavior of whole sample, females and males, has been examined in 3 sessions -depending on the arguments that explain gendered pattern of private and public environmental behavior and sticking to the fact why females' stronger environmental values, beliefs, and attitudes do not translate consistently into greater engagement in public behavior...
February 17, 2017: Waste Management
https://www.readbyqxmd.com/read/28222979/from-macro-to-microplastics-analysis-of-eu-regulation-along-the-life-cycle-of-plastic-bags
#13
REVIEW
Ida M Steensgaard, Kristian Syberg, Sinja Rist, Nanna B Hartmann, Alessio Boldrin, Steffen Foss Hansen
Plastic pollution and its environmental effects has received global attention the recent years. However, limited attention has so far been directed towards how plastics are regulated in a life cycle perspective and how regulatory gaps can be addressed in order to limit and prevent environmental exposure and hazards of macro- and microplastics. In this paper, we map European regulation taking outset in the life cycle perspective of plastic carrier bags: from plastic bag production to when it enters the environment...
February 17, 2017: Environmental Pollution
https://www.readbyqxmd.com/read/28222383/simultaneous-biogas-upgrading-and-centrate-treatment-in-an-outdoors-pilot-scale-high-rate-algal-pond
#14
Esther Posadas, David Marín, Saúl Blanco, Raquel Lebrero, Raúl Muñoz
The bioconversion of biogas to biomethane coupled to centrate treatment was evaluated in an outdoors pilot scale high rate algal pond interconnected to an external CO2-H2S absorption column (AC) via settled broth recirculation. CO2-removal efficiencies ranged from 50 to 95% depending on the alkalinity of the cultivation broth and environmental conditions, while a complete H2S removal was achieved regardless of the operational conditions. A maximum CH4 concentration of 94% with a limited O2 and N2 stripping was recorded in the upgraded biogas at recycling liquid/biogas ratios in the AC of 1 and 2...
February 11, 2017: Bioresource Technology
https://www.readbyqxmd.com/read/28222298/vascular-morphogenesis-an-integrin-and-fibronectin-highway
#15
Hellyeh Hamidi, Johanna Ivaska
A new study shows that endothelial cells use synaptic-like machinery to control polarized secretion and deposition of newly synthesised fibronectin. This process is coupled to active integrin recycling to the same locations and is fundamental for vascular development in zebrafish.
February 20, 2017: Current Biology: CB
https://www.readbyqxmd.com/read/28221781/the-relationship-between-organic-loading-and-effects-on-fish-reproduction-for-pulp-mill-effluents-across-canada
#16
Pierre H Martel, Brian I O'Connor, Tibor G Kovacs, Michael R Van Den Heuvel, Joanne L Parrott, Mark E McMaster, Deborah L MacLatchy, Glen J Van Der Kraak, L Mark Hewitt
This study builds upon the work of a multiagency consortium tasked with determining cost effective solutions for the effects of pulp mill effluents on fish reproduction. A laboratory fathead minnow egg production test and chemical characterization tools were used to benchmark eighty-one effluents from twenty mills across Canada, representing the major pulping, bleaching and effluent treatment technologies. For Kraft and mechanical pulp mills, effluents containing less than 20 mg/L BOD5 were found to have the greatest probability of having no effects...
February 21, 2017: Environmental Science & Technology
https://www.readbyqxmd.com/read/28220791/quantification-of-re-absorption-and-re-emission-processes-to-determine-photon-recycling-efficiency-in-perovskite-single-crystals
#17
Yanjun Fang, Haotong Wei, Qingfeng Dong, Jinsong Huang
Photon recycling, that is, iterative self-absorption and re-emission by the photoactive layer itself, has been speculated to contribute to the high open-circuit voltage in several types of high efficiency solar cells. For organic-inorganic halide perovskites that have yielded highly efficient photovoltaic devices, however, it remains unclear whether the photon recycling effect is significant enough to improve solar cell efficiency. Here we quantitatively evaluate the re-absorption and re-emission processes to determine photon recycling efficiency in hybrid perovskite with its single crystals by measuring the ratio of the re-emitted photons to the initially excited photons, which is realized by modulating their polarization to differentiate them...
February 21, 2017: Nature Communications
https://www.readbyqxmd.com/read/28220385/selective-adsorption-and-recycle-of-cu-2-from-aqueous-solution-by-modified-sugarcane-bagasse-under-dynamic-condition
#18
Jia-Dong Chen, Jun-Xia Yu, Fen Wang, Jia-Qi Tang, Yue-Fei Zhang, Yuan-Lai Xu, Ru-An Chi
Tetraethylenepentamine modified sugarcane bagasse was prepared and applied to test its feasibility in removing and recovering Cu(2+) from wastewater under dynamic condition. Results showed that the Cu(2+) could be selectively absorbed from wastewater by the modified SCB fixed bed column. To understand the adsorption mechanism, Cd(2+) had been selected as the model interfering ion to investigate how co-ions influence the adsorption of Cu(2+) on the sorbent. It was observed that the adsorption capacity of the sorbent for Cu(2+) (0...
February 20, 2017: Environmental Science and Pollution Research International
https://www.readbyqxmd.com/read/28219320/microorganism-and-agricultural-based-biosorbents-towards-removal-of-cadmium-from-waste-water-an-overview
#19
Souvik Pal, Subhankar Mukherjee, Nabarun Bhattacharyya
BACKGROUND: Non-degradable and persistent nature of Cadmium (Cd) poses high toxicity to human, plants and animals. Several industrial processes generated wastes are the main anthropogenic pathway through which Cd enters into the environment. Although, World Health Organization (WHO) has set the limit of Cd in drinking water is 0.005 mg L-1, the industrial activities release much higher concentrations of metal ions to the water stream than the prescribed limits, which leads to the increasing health hazards and environmental pollution...
February 20, 2017: Recent Patents on Biotechnology
https://www.readbyqxmd.com/read/28219298/microwave-assisted-surface-modification-for-the-separation-of-polycarbonate-from-polymethylmethacrylate-and-polyvinyl-chloride-waste-plastics-by-flotation
#20
Luoluo Huang, Hui Wang, Chongqing Wang, Junyao Zhao, Bo Zhang
Microwave-assisted potassium permanganate modification (MPPM) was used for the flotation separation of polycarbonate (PC) from polyvinyl chloride (PVC) and polymethylmethacrylate (PMMA) waste plastics. The separation process was optimized by investigating the potassium permanganate concentration, treatment time, flotation time and frother concentration. MPPM selectively reduced the flotation recovery of PC. The optimum conditions were determined to be: potassium permanganate concentration, 2 mM/L; treatment time, 1 min; frother concentration, 17...
March 2017: Waste Management & Research
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