Tian Ma, Xiang Ma, Zhengguo Lin, Jiayao Zhang, Peng Yang, Tibor Csupász, Imre Tóth, Sonja Misirlic-Dencic, Andjelka M Isakovic, David Lembo, Manuela Donalisio, Ulrich Kortz
Three gallium(III)- and thallium(III)-containing polyoxopalladates (POPs) have been synthesized and structurally characterized in the solid state and in solution, namely, the phosphate-capped 12-palladate nanocubes [XPd12 O8 (PO4 )8 ]13- (X = GaIII , GaPd 12 P 8 ; X = TlIII , TlPd 12 P 8 ) and the 23-palladate double-cube [Tl2 III Pd23 P14 O70 (OH)2 ]20- ( Tl 2 Pd 23 P 14 ). The cuboid POPs, GaPd 12 P 8 and TlPd 12 P 8 , are solution stable as verified by the respective 31 P, 71 Ga, and 205 Tl nuclear magnetic resonance (NMR) spectra...
August 9, 2023: Inorganic Chemistry