Youssef Draoui, Smaail Radi, Mohamed El Massaoudi, Yousra Bahjou, Sabir Ouahhoud, Samira Mamri, Marilena Ferbinteanu, Redouane Benabbes, Mariusz Wolff, Koen Robeyns, Yann Garcia
Four mononuclear complexes (H3 O){[NiL3 ](ClO4 )3 } ( 1 ), [CoL3 ](ClO4 )2 ·2H2 O ( 2 ), [CdL2 Cl2 ] ( 3 ) and [CuL3 ](NO3 )2 ( 4 ) have been prepared employing a newly synthesized 1,2,4-triazole ligand: 3-(3,5-dimethyl-1 H -pyrazol-1-yl)-1 H -1,2,4-triazole ( L ). The structures of the complexes, which crystallized in P63/m ( 1 ), P-1 ( 2 ), P1 ( 3 ), and P21/c ( 4 ), are reviewed within the context of the cooperative effect of the hydrogen bonding network and counter anions on the supramolecular formations...
September 25, 2023: Molecules: a Journal of Synthetic Chemistry and Natural Product Chemistry