Hanlin Wu, Huifei Zhai, Sheng Li, Maurice Sorolla, Gregory T McCandless, Daniel Peirano Petit, Julia Y Chan, Bing Lv
A new ternary nonstoichiometric Zr6.5 Pt6 Se19 has been discovered as a part of effort to dope Zr into the layered transitional metal chalcogenide PtSe2 . With a new structure type ( oC 68), it is the first Pt-based ternary chalcogenide with group 4 elements (Ti, Zr, and Hf). The crystal structure adopts the orthorhombic space group Cmmm with lattice parameters of a = 15.637(6) Å, b = 26.541(10) Å, c = 3.6581(12) Å, and V = 1518.2(9) Å3 . This unusual structure consists of several building units: chains of edge-sharing selenium trigonal prisms and octahedra centered by zirconium atoms, chains of corner-shared square pyramid, and square planar centered by Pt atoms...
May 27, 2020: Inorganic Chemistry