Lucy E Enslin, Kallol Purkait, Maria Dalla Pozza, Bruno Saubamea, Pierre Mesdom, Hendrik G Visser, Gilles Gasser, Marietjie Schutte-Smith
Eight rhenium(I) tricarbonyl aqua complexes with the general formula fac -[Re(CO)3 ( N,N '-bid)(H2 O)][NO3 ] ( 1-8 ), where N,N '-bid is (2,6-dimethoxypyridyl)imidazo[4,5- f ]1,10-phenanthroline ( L1 ), (indole)imidazo[4,5- f ]1,10-phenanthroline ( L2 ), (5-methoxyindole)-imidazo[4,5- f ]1,10-phenanthroline ( L3 ), (biphenyl)imidazo[4,5- f ]1,10-phenanthroline ( L4 ), (fluorene)imidazo[4,5- f ]1,10-phenanthroline ( L5 ), (benzo[ b ]thiophene)imidazo[4,5- f ]1,10-phenanthroline ( L6 ), (5-bromothiazole)imidazo[4,5- f ]1,10-phenanthroline ( L7 ), and (4,5-dimethylthiophene)imidazo[4,5- f ]1,10-phenanthroline ( L8 ), were synthesized and characterized using 1 H and 13 C{1 H} NMR, FT-IR, UV/Vis absorption spectroscopy, and ESI-mass spectrometry, and their purity was confirmed by elemental analysis...
July 25, 2023: Inorganic Chemistry