keyword
https://read.qxmd.com/read/38535675/influence-of-concentration-surface-charge-and-natural-water-components-on-the-transport-and-adsorption-of-polystyrene-nanoplastics-in-sand-columns
#1
JOURNAL ARTICLE
Gabriela Hul, Hande Okutan, Philippe Le Coustumer, Stéphan Ramseier Gentile, Stéphane Zimmermann, Pascal Ramaciotti, Pauline Perdaems, Serge Stoll
Information about the influence of surface charges on nanoplastics (NPLs) transport in porous media, the influence of NPL concentrations on porous media retention capacities, and changes in porous media adsorption capacities in the presence of natural water components are still scarce. In this study, laboratory column experiments are conducted to investigate the transport behavior of positively charged amidine polystyrene (PS) latex NPLs and negatively charged sulfate PS latex NPLs in quartz sand columns saturated with ultrapure water and Geneva Lake water, respectively...
March 15, 2024: Nanomaterials
https://read.qxmd.com/read/38527887/laboratory-and-field-evaluation-of-a-low-cost-optical-particle-sizer
#2
JOURNAL ARTICLE
Mingzhen Tang, Yicheng Shen, Yanzhen Ge, Jian Gao, Chong Wang, Liqing Wu, Shuchun Si
Low-cost sensors are widely used to collect high-spatial-resolution particulate matter data that traditional reference monitoring devices cannot. In addition to the mass concentration, the number concentration and size distribution are also fundamental in determining the origin and hazard level of particulate pollution. Therefore, low-cost optical sensors have been improved to establish optical particle sizers (OPSs). In this study, a low-cost OPS, the Nova SDS029, is introduced, and it is evaluated in comparison to two reference instruments-the GRIMM 11-D and the TSI 3330...
August 2024: Journal of Environmental Sciences (China)
https://read.qxmd.com/read/38500437/prediction-models-for-the-flux-decay-profile-and-initial-flux-of-microfiltration-for-therapeutic-proteins
#3
JOURNAL ARTICLE
Kota Inoue, Yumiko Masuda, Tetsuo Torisu, Koichi Nonaka, Susumu Uchiyama
Microfiltration (MF) is an essential step during biopharmaceutical manufacturing. However, unexpected flux decay can occur. Although the flux decay profile and initial flux are important factors determining MF filterability, predicting them accurately is challenging, as the root cause of unexpected flux decay remains elusive. In this study, the methodology for developing a prediction model of flux decay profiles was established. First, the filtration profiles of different monodisperse polystyrene latex and silica beads of various sizes were evaluated...
March 19, 2024: Biotechnology and Bioengineering
https://read.qxmd.com/read/38313494/correction-to-electrical-and-thermal-properties-of-surface-modified-copper-nanowire-polystyrene-nanocomposites-through-latex-blending
#4
Hyeon Sik Eom, Dong Won Kim, Keon-Soo Jang, Seong Jae Lee
[This corrects the article DOI: 10.1021/acsomega.3c06775.].
January 30, 2024: ACS Omega
https://read.qxmd.com/read/38276716/do-surface-charges-on-polymeric-filters-and-airborne-particles-control-the-removal-of-nanoscale-aerosols-by-polymeric-facial-masks
#5
JOURNAL ARTICLE
Zhaobo Zhang, Mahmut S Ersan, Paul Westerhoff, Pierre Herckes
The emergence of facial masks as a critical health intervention to prevent the spread of airborne disease and protect from occupational nanomaterial exposure highlights the need for fundamental insights into the interaction of nanoparticles (<200 nm) with modern polymeric mask filter materials. While most research focuses on the filtration efficiency of airborne particles by facial masks based on pore sizes, pressure drop, or humidity, only a few studies focus on the importance of aerosol surface charge versus filter surface charge and their role in the net particle filtration efficiency of mask filters...
December 19, 2023: Toxics
https://read.qxmd.com/read/38213133/actual-amount-adsorbed-as-estimated-from-the-surface-excess-isotherm
#6
JOURNAL ARTICLE
Seishi Shimizu, Nobuyuki Matubayasi
The amount of adsorption at equilibrium is commonly used for reporting solid/solution isotherms, despite the admonishment by the International Union of Pure and Applied Chemistry (IUPAC) against equating the surface excess (i.e., the measurable quantity for sorption, signifying the competitive sorption of adsorbate and solvent) with the actual amount adsorbed. The consensus, more generally stated, is that the surface excess cannot be divided into individual isotherms for sorbate and solvent unless simplifying model assumptions are introduced...
January 11, 2024: Langmuir: the ACS Journal of Surfaces and Colloids
https://read.qxmd.com/read/38135422/development-and-evaluation-of-an-online-monitoring-single-particle-optical-particle-counter-with-polarization-detection
#7
JOURNAL ARTICLE
Weijie Yao, Xiaole Pan, Yu Tian, Hang Liu, Yuting Zhang, Shandong Lei, Junbo Zhang, Yinzhou Zhang, Lin Wu, Yele Sun, Zifa Wang
We developed a single-particle optical particle counter with polarization detection (SOPC) for the real-time measurement of the optical size and depolarization ratio (defined as the ratio of the vertical component to the parallel component of backward scattering) of atmospheric particles, the polarization ratio (DR) value can reflect the irregularity of the particles. The SOPC can detect aerosol particles with size larger than 500 nm and the maximum particle count rate reaches ∼1.8 × 105  particles per liter...
April 2024: Journal of Environmental Sciences (China)
https://read.qxmd.com/read/38107942/electrical-and-thermal-properties-of-surface-modified-copper-nanowire-polystyrene-nanocomposites-through-latex-blending
#8
JOURNAL ARTICLE
Hyeon Sik Eom, Dong Won Kim, Keon-Soo Jang, Seong Jae Lee
The incorporation of conductive nanofillers into an insulating polymer matrix commonly leads to nanocomposites with good electrical, thermal, and mechanical properties. In this study, copper nanowires (CuNWs) and polystyrene (PS) microspheres were synthesized along with the fabrication of CuNW/PS polymer nanocomposites. The electrical, thermal, mechanical, rheological, and morphological properties of the CuNW/PS nanocomposites were examined. The CuNWs were homogeneously dispersed in the PS matrix through latex blending...
December 12, 2023: ACS Omega
https://read.qxmd.com/read/38033267/aggregate-size-modulates-the-oil-water-interfacial-behavior-of-a-myofibrillar-protein-toward-the-thicker-interface-film-and-disulfide-bond
#9
JOURNAL ARTICLE
Haozhen Zhang, Weiyi Zhang, Xinglian Xu, Xue Zhao
Myofibrillar protein (MP) aggregate models have been established to elucidate the correlation between their aggregate sizes and interfacial properties. The interfacial layer thickness was measured by the polystyrene latex method and quartz crystal microbalance with dissipation measurement. Interfacial conformations were then characterized in situ (front-surface fluorescence spectroscopy) and ex situ (reactive sulfhydryl group and secondary structure measurement following MP displacement). The viscoelasticity of the interfacial film and its resistance to surfactant-induced competitive displacement were reflected by the dilatational rheology and dynamic interfacial tension with the bulk phase exchange...
November 30, 2023: Langmuir: the ACS Journal of Surfaces and Colloids
https://read.qxmd.com/read/37798623/a-novel-reagent-for-the-screening-of-haptoglobin-deficient-blood-donors
#10
JOURNAL ARTICLE
Naoko Watanabe-Okochi, Ayaka Sato, Akira Okuyama, Go Tomiyoshi, Yumi Suzuki, Yukiko Watanabe, Kaori Kitsukawa, Masako Anazawa, Takashige Shimoyamada, Daisuke Takahashi, Takayuki Onodera, Makoto Uchikawa, Nelson-Hirokazu Tsuno, Kazuo Muroi
BACKGROUND AND OBJECTIVES: In Japan, the prevalence of haptoglobin deficiency is approximately 1 in 4000. Haptoglobin-deficient individuals may produce anti-haptoglobin from allo-immunization, leading to serious transfusion reactions. Therefore, implementation of a consistent supply of haptoglobin-deficient fresh frozen plasma is crucial. We developed a novel reagent to facilitate large-scale identification of haptoglobin-deficient individuals as potential donors of plasma products. MATERIALS AND METHODS: We established mouse monoclonal anti-haptoglobin-producing cell lines (three clones) using the hybridoma method by immunizing mice with the haptoglobin protein...
October 5, 2023: Vox Sanguinis
https://read.qxmd.com/read/37782503/particle-adsorption-using-a-quartz-crystal-microbalance-with-dissipation-by-applying-a-kelvin-voigt-based-viscoelastic-model-and-the-gauss-newton-method
#11
JOURNAL ARTICLE
Ippei Furikado, Jan Forsman, Tommy Nylander
The use of a quartz crystal microbalance with dissipation (QCM-D) to study the adsorption of particles larger than 100 nm, such as liposomes, viruses, and nano/micro-plastics, remains challenging owing to the lack of appropriate models for data evaluation. This study presents a method for quantifying the adsorption of negatively charged polystyrene latex (100 nm-1 μm) at the solid-liquid interface. The validity of a viscoelastic model based on Kelvin-Voigt theory was assessed, and the model was used to evaluate particle adsorption data obtained from QCM-D measurements...
October 2, 2023: Analytical Chemistry
https://read.qxmd.com/read/37752655/-latex-agglutination-as-an-alternative-to-the-hemagglutination-reaction-of-influenza-viruses
#12
JOURNAL ARTICLE
P A Ivanov, A V Lyashko, S A Ionov, D N Shcherbinin, I A Rudneva, A A Shilov, N I Bunkova, M M Shmarov, T A Timofeeva
As an alternative to the classical method of erythrocyte hemagglutination, a latex agglutination assay based on the interaction of influenza viruses with the sialoglycoprotein fetuin immobilized on the surface of polystyrene microspheres has been developed. Twelve influenza A virus strains of different subtypes and two influenza B viruses of different lines were tested. Simultaneous titration of viruses using the classical hemagglutination test and the proposed latex agglutination assay showed similar sensitivity and a high degree of correlation (R = 0...
2023: Molekuliarnaia Biologiia
https://read.qxmd.com/read/37747841/visible-light-initiated-dispersion-photopolymerization-of-styrene
#13
JOURNAL ARTICLE
Rémi Canterel, Jacques Lalevée, Elodie Bourgeat-Lami, Emmanuel Lacôte, Muriel Lansalot
Polystyrene (PS) particles were synthesized in ethanol/water mixture by dispersion polymerization using visible light irradiation, with either a N-heterocyclic carbene borane-based photoinitiating system (PIS) or a disulfide. With the full PIS and poly(ethylene glycol) methyl ether methacrylate (PEGMA) as stabilizer, the size distributions were broad and the amount of PEGMA had a strong impact on the experiment reproducibility. The addition of a base solved the problem, leading to faster polymerizations, narrower size distributions and larger particles...
September 25, 2023: Angewandte Chemie
https://read.qxmd.com/read/37724929/design-of-a-high-counting-efficiency-sensor-for-1-0-cubic-feet-per-minute-laser-particle-counter
#14
JOURNAL ARTICLE
Yanchang Zheng, Guo Wu, Yesheng Chen, Yuelin Lu, Cheng Li, Guibo Wan, Rongxin Yin
Based on the theory of Mie scattering, an optical sensor for a 1.0 cubic feet per minute laser particle counter is developed in this paper. First, an illumination optical path relying on aspherical lens and cylindrical lens for laser shaping was designed, and a narrow optical spot with the illumination in the vertical direction of the photosensitive area approximately distributed as a flat top was obtained. Second, the scattering light path was designed by using the theory of Mie scattering and geometric optics method...
September 1, 2023: Review of Scientific Instruments
https://read.qxmd.com/read/37704797/the-presence-of-microplastics-in-the-gills-and-gastrointestinal-tract-of-mackerel-rastrelliger-kanagurta-cuvier-1816-from-jakarta-bay-indonesia
#15
JOURNAL ARTICLE
Yulia Irnidayanti, Agoes Soegianto, Aurigha Haidar Brabo, Fabian Muhammad Abdilla, Trisnadi Widyaleksono Catur Putranto, Carolyn Melissa Payus
This study examined the characteristics of microplastics (MPs) in the gills and gastrointestinal tract (GIT) of mackerel (Rastrelliger kanagurta) captured in Jakarta Bay, Indonesia. All 120 fish contained MPs, with fragment > fiber > film being the most prevalent types, in that order. The total abundances of fragments, fibers, and films in the gills were as follows: 4.8 ± 1.6, 1.0 ± 0.7, and 0.3 ± 0.3, respectively. The total abundances of fragments, fibers, and films in the GIT were 5...
September 13, 2023: Bulletin of Environmental Contamination and Toxicology
https://read.qxmd.com/read/37703259/nanoplastics-released-from-daily-used-silicone-and-latex-products-during-mechanical-breakdown
#16
JOURNAL ARTICLE
Mikael T Ekvall, Isabella Gimskog, Egle Kelpsiene, Alice Mellring, Alma Månsson, Martin Lundqvist, Tommy Cedervall
Waste of polymer products, especially plastics, in nature has become a problem that caught the awareness of the general public during the last decade. The macro- and micro polymers in nature will be broken down by naturally occurring events such as mechanical wear and ultra-violet (UV) radiation which will result in the generation of polymeric particles in the nano-size range. We have recently shown that polystyrene and high-density polyethylene macroplastic can be broken down into nano-sized particles by applying mechanical force from an immersion blender...
2023: PloS One
https://read.qxmd.com/read/37687483/hydrophobic-thermal-shock-and-corrosion-resistant-xsbr-latex-modified-lightweight-class-g-cement-composites-in-geothermal-well-energy-storage-systems
#17
JOURNAL ARTICLE
Toshifumi Sugama, Tatiana Pyatina
Energy losses can be significantly reduced if thermally insulating cement is used for energy storage and recovery. The thermal conductivity (TC) of the currently used cement is between 1 and 1.2 W/mK. In this study we assessed the ability of polystyrene (PS)-polybutadiene (PB)-polyacrylic acid (PAA) terpolymer (cross-linked styrene-butadiene rubber, XSBR) latex to improve thermal insulating properties and thermal shock (TS) resistance of class G ordinary Portland cement (OPC) and fly ash cenosphere (FCSs) composites in the temperature range of 100-175 °C...
August 24, 2023: Materials
https://read.qxmd.com/read/37672672/immunoaffinity-lc-ms-ms-quantification-of-the-sepsis-biomarker-procalcitonin-using-magnetic-and-polystyrene-bead-immobilized-polyclonal-antibodies
#18
JOURNAL ARTICLE
Tölke Sebastian-Alexander, Masetto Thomas, Reuschel Thomas, Grimmler Matthias, Bindila Laura, Schneider Klaus
Procalcitonin (PCT) is a biomarker for bacterial sepsis, and accurate quantification of PCT is critical for sepsis diagnosis and treatment. Immunological PCT quantification methods are routinely used in clinical laboratories, yet there is a need for harmonization of PCT quantification protocols. An orthogonal method to clinical immunological assays, such as LC-MS/MS, is required. In this study, a highly sensitive and robust immunoaffinity LC-MRM quantitative method for detecting procalcitonin in human serum has been developed...
September 6, 2023: Journal of Proteome Research
https://read.qxmd.com/read/37582251/development-of-a-methodology-for-the-quantification-of-re-aerosolization-of-a-biological-contaminate-surrogate-particle-from-military-uniform-fabric
#19
JOURNAL ARTICLE
George Cooksey, Jeremy Slagley, Casey Cooper, Douglas Lewis, Alisha Helm
In a mass casualty medical evacuation after a bioaerosol (BA) dispersal event, a decontamination (DC) method is needed that can both decontaminate and prevent biological particle (BP) re-aerosolization (RA) off of contaminated clothes. However, neither the efficacy of current DC methods, nor the risk of BP RA is greatly explored in existing literature. The goals of this study were to develop a repeatable method to quantify the RA of a biological contaminant off military uniform fabric swatches, and to test the efficacy of one DC protocol (high-volume, low-pressure water) using 1 µm polystyrene latex (PSL) spheres as a surrogate...
August 15, 2023: Journal of Occupational and Environmental Hygiene
https://read.qxmd.com/read/37446139/comprehensive-comparison-of-the-capacity-of-functionalized-sepharose-magnetic-core-and-polystyrene-nanoparticles-to-immuno-precipitate-procalcitonin-from-human-material-for-the-subsequent-quantification-by-lc-ms-ms
#20
JOURNAL ARTICLE
Thomas Masetto, Kai Matzenbach, Thomas Reuschel, Sebastian-Alexander Tölke, Klaus Schneider, Lea Marie Esser, Marco Reinhart, Laura Bindila, Christoph Peter, Matthias Grimmler
Sepsis is a life-threatening organ dysfunction caused by a dysregulated host response to infection. The fast and accurate diagnosis of sepsis by procalcitonin (PCT) has emerged as an essential tool in clinical medicine. Although in use in the clinical laboratory for a long time, PCT quantification has not yet been standardized. The International Federation of Clinical Chemistry working group on the standardization of PCT (IFCC-WG PCT) aims to provide an LC-MS/MS-based reference method as well as the highest metrological order reference material to address this diagnostic need...
June 30, 2023: International Journal of Molecular Sciences
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