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https://www.readbyqxmd.com/read/28332749/bioinspired-asymmetric-synthesis-of-hispidanin%C3%A2-a
#1
Fuzhuo Li, Qian Tu, Sijia Chen, Lei Zhu, Yu Lan, Jianxian Gong, Zhen Yang
The first enantiospecific synthesis of hispidanin A (4), a dimeric diterpenoid from the rhizomes of Isodon hispida, was achieved with a longest linear sequence of 12 steps in 6.5 % overall yield. A key component is the use of the abundant and naturally occurring diterpenoids (+)-sclareolide and (+)-sclareol as starting materials, which enables the gram-scale preparation of the key intermediates totarane (1) and s-trans-12E,14-labdadien-20,8β-olide (2). Subsequently a thermal or an erbium-catalyzed intermolecular Diels-Alder reaction of totarane (1) with labdadienolide (2) provide convergent and rapid access to the natural product hispidanin A (4)...
March 23, 2017: Angewandte Chemie
https://www.readbyqxmd.com/read/28325038/benefit-of-rare-earth-smart-doping-and-material-nanostructuring-for-the-next-generation-of-er-doped-fibers
#2
Inna Savelii, Laurent Bigot, Bruno Capoen, Cedric Gonnet, Corinne Chanéac, Ekaterina Burova, Alain Pastouret, Hicham El-Hamzaoui, Mohamed Bouazaoui
Erbium-doped fiber amplifiers (EDFAs) for harsh environments require to develop specific fabrication methods of Er (3+)-doped fibers (EDFs) so as to limit the impact of radiation-induced absorption. In this context, a compromise has to be found between the concentration of Erbium and the glass composition. On the one hand, high concentration of Er (3+) ions helps to reduce the length of the EDF and hence the cumulated attenuation but generally leads to luminescence quenching mechanisms that limit the performances...
December 2017: Nanoscale Research Letters
https://www.readbyqxmd.com/read/28303946/preparation-of-ho-3-tm-3-co-doped-lanthanum-tungsten-germanium-tellurite-glass-fiber-and-its-laser-performance-for-2-0%C3%A2-%C3%AE-m
#3
Dechun Zhou, Xuemei Bai, Hang Zhou
Ho(3+)/Tm(3+) co-doped 50TeO2-25GeO2-3WO3-5La2O3-3Nb2O5-5Li2O-9BaF2 glass fiber is prepared with the rod-tube drawing method of 15 μm core diameter and 125 μm inner cladding diameter applied in the 2.0 μm-infrared laser. The 2.0 μm luminescence properties of the core glass are researched and the fluorescence intensity variation for different Tm(3+) doping concentration is systematically analyzed. The results show that the 2.0 μm luminescence of Ho(3+) is greatly influenced by the doping concentration ratio of Ho(3+) to Tm(3+) and that the maximum fluorescence intensity of the core glass can be obtained and its emission cross section can reach 0...
March 17, 2017: Scientific Reports
https://www.readbyqxmd.com/read/28299490/molecular-effects-of-fractional-ablative-erbium-yag-laser-treatment-with-multiple-stacked-pulses-on-standardized-human-three-dimensional-organotypic-skin-models
#4
Laurenz Schmitt, P M Amann, Y Marquardt, R Heise, K Czaja, P A Gerber, T Steiner, F Hölzle, Jens Malte Baron
The molecular changes in gene expression following ablative laser treatment of skin lesions, such as atrophic scars and UV-damaged skin, are not completely understood. A standardized in vitro model of human skin, to study the effects of laser treatment on human skin, has been recently developed. Therefore, the aim of the investigation was to examine morphological and molecular changes caused by fractional ablative erbium:YAG laser treatment on an in vitro full-thickness 3D standardized organotypic model of human skin...
March 15, 2017: Lasers in Medical Science
https://www.readbyqxmd.com/read/28296519/congenital-melanocytic-nevus-on-the-lower-eyelid-treated-with-continuous-wave-and-superpulsed-co2-laser-followed-by-erbium-laser
#5
Vito Abrusci, Valentina Benzecry
There are several therapeutic options to treat congenital melanocytic nevi. The motivations for the treatment of small- to medium-sized congenital nevi located on the face or other sensitive areas are frequently cosmetic. The choice of therapy depends on the operator's expertise and on the likelihood of improved cosmesis. We report a case of a medium-sized congenital nevi located on the lower eyelid, successfully treated with a combination of ablative lasers with a single surgical procedure. We achieved an excellent clinical and cosmetic result...
February 17, 2017: Journal of Cosmetic and Laser Therapy: Official Publication of the European Society for Laser Dermatology
https://www.readbyqxmd.com/read/28275785/-histological-evaluations-on-periapical-tissues-after-irradiation-by-erbium-doped-yttrium-aluminum-garnet-laser-in-labradors-dogs
#6
Hao-Ming Wang, Meng-Qi Zhou, Jin Hong
PURPOSE: To investigate the thermal effects on periapical tissues of Labrador dogs after intra-canal irradiation by erbium-doped yttrium aluminum garnet (Er:YAG) laser at different powers based on the antibacterial experiment of Enterococcus faecalis and Escherichia coli in root canals with an isthmus, to assess the histological changes, and to prove the safety for clinical applications. METHODS: Two hundred root canals of 10 healthy adult Labradors dogs were selected and divided into 5 groups...
December 2016: Shanghai Kou Qiang Yi Xue, Shanghai Journal of Stomatology
https://www.readbyqxmd.com/read/28275279/influence-of-laser-activated-irrigation-with-two-erbium-lasers-on-bond-strength-of-inidividually-formed-fiber-reinforced-composite-posts-to-root-canal-dentin
#7
Ivana Parčina, Amižić, Ivana Miletić, Andrei C Ionescu, Eugenio Brambilla, Dragana Gabrić, Anja Baraba
OBJECTIVE: The aim of this in vitro study was to investigate the effect of laser activated irrigation (LAI) using two erbium lasers on bond strength of individually formed fiber-reinforced composite (FRC) posts to root canal dentin. MATERIALS AND METHODS: Twenty-seven single-rooted human teeth were endodontically treated and after post space preparation divided into three groups (n=9 per group), according to the pre-treatment of post space preparation: 1) Conventional syringe irrigation (CSI) and saline; 2) Er...
December 2016: Acta Stomatologica Croatica
https://www.readbyqxmd.com/read/28239750/light-and-laser-treatment-modalities-for-disseminated-superficial-actinic-porokeratosis-a-systematic-review
#8
Gregory A Aird, Jenna L Sitenga, Austin Huy Nguyen, Adam Vaudreuil, Christopher J Huerter
Treatment of disseminated superficial actinic porokeratosis (DSAP) is poorly standardized. The present review seeks to comprehensively discuss the potential for laser and light modalities in the treatment of DSAP. A systematic review of light and laser treatment modalities was conducted to include 26 cases of patients with DSAP. Systematic review resulted in 14 articles to be included. Photodynamic therapy (PDT) overall was the least successful treatment modality, with clinical improvement seen in a minority of patients (MAL-PDT: N = 9 patients, 33...
February 27, 2017: Lasers in Medical Science
https://www.readbyqxmd.com/read/28231079/vaginal-erbium-laser-as-second-generation-thermotherapy-for-the-genitourinary-syndrome-of-menopause-a-pilot-study-in-breast-cancer-survivors
#9
Marco Gambacciani, Marco Levancini
OBJECTIVE: The aim of this study was to evaluate the efficacy and acceptability of a second generation of vaginal laser treatment, the vaginal erbium laser, as a nonablative photothermal therapy for the management of genitourinary syndrome of menopause in postmenopausal breast cancer survivors. METHODS: The study was performed using an erbium laser crystal yttrium-aluminum-garnet (XS Fotona Smooth, Fotona, Ljubljana, Slovenia) with a wavelength of 2,940 nm. Forty-three postmenopausal breast cancer survivors were treated with three laser applications every 30 days...
March 2017: Menopause: the Journal of the North American Menopause Society
https://www.readbyqxmd.com/read/28223745/intense-pulsed-light-alone-and-in-combination-with-erbium-yttrium-aluminum-garnet-laser-on-small-to-medium-sized-congenital-melanocytic-nevi-single-center-experience-based-on-retrospective-chart-review
#10
Mi So Lee, Hee Jin Jun, Sang Hyun Cho, Jeong Deuk Lee, Hei Sung Kim
BACKGROUND: Treatment of congenital melanocytic nevi (CMN) with intense pulsed light (IPL) has recently produced promising results. OBJECTIVE: To evaluate the clinical and histological outcomes of small-to-medium sized CMN treated with IPL alone and in combination with erbium: yttrium-aluminum-garnet (Er: YAG) laser. METHODS: We performed a retrospective chart review of 26 small-to-medium sized CMN treated as described above. The reduction in visible pigmentation, signs of recurrence and any adverse skin changes were evaluated by two independent clinicians...
February 2017: Annals of Dermatology
https://www.readbyqxmd.com/read/28214427/intense-2-7%C3%AE-m-emission-in-er-3-doped-zinc-fluoride-glass
#11
Feifei Huang, Yanyan Guo, Ying Tian, Shiqing Xu, Junjie Zhang
A novel erbium ion doped zinc fluoride glass was prepared. 2.7μm emission and transmittance properties together with thermal ability were investigated. An enhanced 2.7μm emission was observed by introducing ZnF2 in the ZrF4-based fluoride glass. Meanwhile, the J-O parameters and branching ratios (β) of Er(3+)-doped zinc fluoride glass were calculated and analyzed. The present Er(3+)-doped zinc fluoride glass with large emission cross-section (0.92×10(-20)cm(2)) and long decay lifetime (2.05ms) at 2.7μm indicates that it have very promising applications for solid state lasers around 3μm...
February 10, 2017: Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
https://www.readbyqxmd.com/read/28211471/phosphorene-quantum-dot-saturable-absorbers-for-ultrafast-fiber-lasers
#12
J Du, M Zhang, Z Guo, J Chen, X Zhu, G Hu, P Peng, Z Zheng, H Zhang
We fabricate ultrasmall phosphorene quantum dots (PQDs) with an average size of 2.6 ± 0.9 nm using a liquid exfoliation method involving ultrasound probe sonication followed by bath sonication. By coupling the as-prepared PQDs with microfiber evanescent light field, the PQD-based saturable absorber (SA) device exhibits ultrafast nonlinear saturable absorption property, with an optical modulation depth of 8.1% at the telecommunication band. With the integration of the all-fiber PQD-based SA, a continuous-wave passively mode-locked erbium-doped (Er-doped) laser cavity delivers stable, self-starting pulses with a pulse duration of 0...
February 17, 2017: Scientific Reports
https://www.readbyqxmd.com/read/28210823/non-ablative-erbium-yag-laser-for-the-treatment-of-type-iii-stress-urinary-incontinence-intrinsic-sphincter-deficiency
#13
Adrian Gaspar, Hugo Brandi
The objective of this pilot study was to determine the safety and efficacy of a new non-ablative erbium YAG laser procedure for the treatment of type III stress urinary incontinence (intrinsic sphincter deficiency) in women. Twenty-two patients with a Valsalva leak point pressure less than 60 cm H2O were recruited and treated with a non-ablative erbium laser delivering low fluence pulses inside the whole length of the urethra through a specially designed cannula. Treatment consisted of two treatment sessions with a 3-week interval in-between...
April 2017: Lasers in Medical Science
https://www.readbyqxmd.com/read/28195287/erbium-ion-implantation-into-diamond-measurement-and-modelling-of-the-crystal-structure
#14
Jakub Cajzl, Pavla Nekvindová, Anna Macková, Petr Malinský, David Sedmidubský, Michal Hušák, Zdeněk Remeš, Marián Varga, Alexander Kromka, Roman Böttger, Jiří Oswald
Diamond is proposed as an extraordinary material usable in interdisciplinary fields, especially in optics and photonics. In this contribution we focus on the doping of diamond with erbium as an optically active centre. In the theoretical part of the study based on DFT simulations we have developed two Er-doped diamond structural models with 0 to 4 carbon vacancies in the vicinity of the Er atom and performed geometry optimizations by the calculation of cohesive energies and defect formation energies. The theoretical results showed an excellent agreement between the calculated and experimental cohesive energies for the parent diamond...
February 14, 2017: Physical Chemistry Chemical Physics: PCCP
https://www.readbyqxmd.com/read/28186148/measurement-of-absolute-frequency-of-continuous-wave-terahertz-radiation-in-real-time-using-a-free-running-dual-wavelength-mode-locked-erbium-doped-fibre-laser
#15
Guoqing Hu, Tatsuya Mizuguchi, Xin Zhao, Takeo Minamikawa, Takahiko Mizuno, Yuli Yang, Cui Li, Ming Bai, Zheng Zheng, Takeshi Yasui
A single, free-running, dual-wavelength mode-locked, erbium-doped fibre laser was exploited to measure the absolute frequency of continuous-wave terahertz (CW-THz) radiation in real time using dual THz combs of photo-carriers (dual PC-THz combs). Two independent mode-locked laser beams with different wavelengths and different repetition frequencies were generated from this laser and were used to generate dual PC-THz combs having different frequency spacings in photoconductive antennae. Based on the dual PC-THz combs, the absolute frequency of CW-THz radiation was determined with a relative precision of 1...
February 10, 2017: Scientific Reports
https://www.readbyqxmd.com/read/28169535/direct-evidence-for-coupled-surface-and-concentration-quenching-dynamics-in-lanthanide-doped-nanocrystals
#16
Noah J J Johnson, Sha He, Shuo Diao, Emory M Chan, Hongjie Dai, Adah Almutairi
Luminescence quenching at high dopant concentrations generally limits the dopant concentration to less than 1-5 mol% in lanthanide-doped materials, and this remains a major obstacle in designing materials with enhanced efficiency/brightness. In this work, we provide direct evidence that the major quenching process at high dopant concentrations is the energy migration to the surface (i.e., surface quenching) as opposed to the common misconception of cross-relaxation between dopant ions. We show that after an inert epitaxial shell growth, erbium (Er(3+)) concentrations as high as 100 mol% in NaY(Er)F4/NaLuF4 core/shell nanocrystals enhance the emission intensity of both upconversion and downshifted luminescence across different excitation wavelengths (980, 800, and 658 nm), with negligible concentration quenching effects...
February 17, 2017: Journal of the American Chemical Society
https://www.readbyqxmd.com/read/28166434/a-systematic-review-of-comparative-studies-of-co2anderbium-yag-lasers-in-resurfacing-facial-rhytides-wrinkles
#17
Kee-Hsin Chen, Ka-Wai Tam, I-Fan Chen, Shihping Kevin Huang, Pei-Chuan Tzeng, Hsian-Jenn Wang, Chiehfeng Cliff Chen
BACKGROUND: Laser resurfacing is used to minimize wrinkles, solar scars, and sequelae of acne. OBJECTIVE: Purpose of the systemic review was to compare resurfacing outcomes of CO2 laser and erbium: yttrium-aluminum-garnet (erb:YAG) laser therapies. METHODS AND MATERIALS: Medline, Cochrane, EMBASE, Google Scholar databases were searched until April 9, 2015 using the following terms: laser, carbon dioxide/CO2, facial wrinkles, rhytides, erbium-doped yttrium aluminum garnet/erbium:YAG/Er:YAG...
February 6, 2017: Journal of Cosmetic and Laser Therapy: Official Publication of the European Society for Laser Dermatology
https://www.readbyqxmd.com/read/28158036/two-octave-spanning-supercontinuum-generation-in-stoichiometric-silicon-nitride-waveguides-pumped-at-telecom-wavelengths
#18
Marco A G Porcel, Florian Schepers, Jörn P Epping, Tim Hellwig, Marcel Hoekman, René G Heideman, Peter J M van der Slot, Chris J Lee, Robert Schmidt, Rudolf Bratschitsch, Carsten Fallnich, Klaus-J Boller
We demonstrate supercontinuum generation in stoichiometric silicon nitride (Si<sub>3</sub>N<sub>4</sub> in SiO<sub>2</sub>) integrated optical waveguides, pumped at telecommunication wavelengths. The pump laser is a mode-locked erbium fiber laser at a wavelength of 1.56 µm with a pulse duration of 120 fs. With a waveguide-internal pulse energy of 1.4 nJ and a waveguide with 1.0 µm × 0.9 µm cross section, designed for anomalous dispersion across the 1500 nm telecommunication range, the output spectrum extends from the visible, at around 526 nm, up to the mid-infrared, at least to 2...
January 23, 2017: Optics Express
https://www.readbyqxmd.com/read/28158014/tunable-erbium-doped-microbubble-laser-fabricated-by-sol-gel-coating
#19
Yong Yang, Fuchuan Lei, Sho Kasumie, Linhua Xu, Jonathan M Ward, Lan Yang, Síle Nic Chormaic
In this work, we show that the application of a sol-gel coating renders a microbubble whispering gallery resonator into an active device. During the fabrication of the resonator, a thin layer of erbium-doped sol-gel is applied to a tapered microcapillary, then a microbubble with a wall thickness of 1.3 μm is formed with the rare earth ions diffused into its wall. The doped microbubble is pumped at 980 nm and lases in the emission band of the Er<sup>3+</sup> ions at 1535 nm. The laser wavelength can be shifted by aerostatic pressure tuning of the whispering gallery modes of the microbubble...
January 23, 2017: Optics Express
https://www.readbyqxmd.com/read/28157873/co-precipitation-of-rare-earth-doped-y-sub-2-sub-o-sub-3-sub-and-mgo-nanocomposites-for-mid-infrared-solid-state-lasers
#20
Victoria L Blair, Zackery D Fleischman, Larry D Merkle, Nicholas Ku, Carli A Moorehead
Mid-infrared, solid-state laser materials face three main challenges: (1) need to dissipate heat generated in lasing; (2) luminescence quenching by multiphonon relaxation; and (3) trade-off in high thermal conductivity and small maximum phonon energy. We are tackling these challenges by synthesizing a ceramic nanocomposite in which multiple phases will be incorporated into the same structure. The undoped majority species, MgO, will be the main carrier of high thermal conductivity, and the minority species, Er:Y<sub>2</sub>O<sub>3</sub>, will have low maximum phonon energy...
January 20, 2017: Applied Optics
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