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https://www.readbyqxmd.com/read/29778163/impacts-of-sodium-hydroxide-and-sodium-hypochlorite-aging-on-polyvinylidene-fluoride-membranes-fabricated-with-different-methods
#1
Qilong Wu, Xihui Zhang, Guodong Cao
This study compared the effects of chemical aging on the polyvinylidene fluoride (PVDF) membranes fabricated with the methods of non-solvent induced phase separation (NIPS) (named NIPS-PVDF) and thermally induced phase separation (TIPS) (named TIPS-PVDF). The chemical solutions of sodium hypochlorite (NaClO) and sodium hydroxide (NaOH) were chosen at the concentration of 5000mg/L. The equivalence of 5 and 10years was respectively selected as the time of aging. The physicochemical evolutions of membrane aging are characterized on the base of morphology analysis, chemical components, permeation ability and mechanical properties...
May 2018: Journal of Environmental Sciences (China)
https://www.readbyqxmd.com/read/29777821/regional-cardiac-function-analysis-from-tagged-mri-images-comparison-of-techniques-harmonic-phase-harp-versus-sinusoidal-modeling-sinmod-analysis
#2
El-Sayed H Ibrahim, Jadranka Stojanovska, Azza Hassanein, Claire Duvernoy, Pierre Croisille, Rodica Pop-Busui, Scott D Swanson
Cardiac MRI tagging is a valuable technique for evaluating regional heart function. Currently, there are a number of different techniques for analyzing the tagged images. Specifically, k-space-based analysis techniques showed to be much faster than image-based techniques, where harmonic-phase (HARP) and sine-wave modeling (SinMod) stand as two famous techniques of the former group, which are frequently used in clinical studies. In this study, we compared HARP and SinMod and studied inter-observer variability between the two techniques for evaluating myocardial strain and apical-to-base torsion in numerical phantom, nine healthy controls, and thirty diabetic patients...
May 16, 2018: Magnetic Resonance Imaging
https://www.readbyqxmd.com/read/29777765/in-vitro-and-in-vivo-evaluation-of-an-oral-sustained-release-hepatoprotective-caffeine-loaded-w-o-pickering-emulsion-formula-containing-wheat-germ-oil-and-stabilized-by-magnesium-oxide-nanoparticles
#3
Heba Elmotasem, Hala K Farag, Abeer A A Salama
The objective of this study was to innovate an effective oral sustained release hepatoprotective formula for - the water soluble drug - caffeine. Caffeine is rapidly absorbed and eliminated which dictates frequent administration to achieve adequate therapeutic effect. A w/o Pickering emulsion incorporating caffeine in the internal phase was primed. It contained wheat germ oil and was stabilized by synthesized magnesium oxide nanoparticles (MgO NPs). Components selection was based on their antioxidant, hepatoprotective and anticarcinogenic effects...
May 16, 2018: International Journal of Pharmaceutics
https://www.readbyqxmd.com/read/29776110/n-sma-smc-phase-transitions-probed-by-a-pair-of-elastically-bound-colloids
#4
Muhammed Rasi M, K P Zuhail, Arun Roy, Surajit Dhara
The competing effect of surface anchoring of dispersed microparticles and elasticity of nematic and cholesteric liquid crystals has been shown to stabilize a variety of topological defects. Here we study a pair of colloidal microparticles with homeotropic and planar surface anchoring across N-SmA-SmC phase transitions. We show that below the SmA-SmC phase transition the temperature dependence of interparticle separation (D) of colloids with homeotropic anchoring shows a power-law behavior; D∼(1-T/T_{AC})^{α}, with an exponent α≈0...
March 2018: Physical Review. E
https://www.readbyqxmd.com/read/29776094/tunable-hybrid-optical-modes-in-a-bounded-cholesteric-liquid-crystal-with-a-twist-defect
#5
Maxim V Pyatnov, Stepan Ya Vetrov, Ivan V Timofeev
Coupling between the defect mode of a cholesteric liquid crystal and the localized mode of a cholesteric liquid crystal-phase plate-metal structure is theoretically demonstrated. It is shown that the transmittance spectrum can be tuned by changing the twist-defect angle and helix pitch, which are governed by external factors. The spectra for different circular polarizations of the incident light are different; specifically, at the nondiffracting polarization, there is no defect-mode transmittance peak.
March 2018: Physical Review. E
https://www.readbyqxmd.com/read/29775817/janus-graphene-oxide-nanosheet-a-promising-additive-for-enhancement-of-polymeric-membranes-performance-prepared-via-phase-inversion
#6
Mahdi Akbari, Mojtaba Shariaty-Niassar, Takeshi Matsuura, Ahmad Fauzi Ismail
Although polymeric membranes find important role in water and waste water treatment in recent years, their fouling is still an important problem. Application of hydrophilic nanoparticles (NPs) is one of the proposed methods for reducing fouling of membranes but their dispersion and stability in hydrophobic polymer matrix is challenging. In this study Janus functionalization of the NPs was introduced as a promising technique toward achieving this goal. Polysulfone (PSf) membranes containing various concentrations of graphene oxide (GO) nanosheets and Janus graphene oxide (Janus GO) nanosheets (as additives) were fabricated via phase inversion...
May 15, 2018: Journal of Colloid and Interface Science
https://www.readbyqxmd.com/read/29775372/polar-kerr-effect-from-time-reversal-symmetry-breaking-in-the-heavy-fermion-superconductor-pros_-4-sb_-12
#7
E M Levenson-Falk, E R Schemm, Y Aoki, M B Maple, A Kapitulnik
We present polar Kerr effect measurements of the filled skutterudite superconductor PrOs_{4}Sb_{12}. Simultaneous ac susceptibility measurements allow us to observe the superconducting transition under the influence of heating from the optical beam. A nonzero Kerr angle θ_{K} develops below the superconducting transition, saturating at ∼300  nrad at low temperatures. This result is repeated across several measurements of multiple samples. By extrapolating the measured θ_{K}(T) to zero optical power, we are able to show that the Kerr angle onset temperature in one set of measurements is consistent with the transition to the B phase at T_{C2}...
May 4, 2018: Physical Review Letters
https://www.readbyqxmd.com/read/29775325/absence-of-long-range-order-in-a-triangular-spin-system-with-dipolar-interactions
#8
Ahmet Keleş, Erhai Zhao
The antiferromagnetic Heisenberg model on the triangular lattice is perhaps the best known example of frustrated magnets, but it orders at low temperatures. Recent density matrix renormalization group (DMRG) calculations find that the next nearest neighbor interaction J_{2} enhances the frustration, and it leads to a spin liquid for J_{2}/J_{1}∈(0.08,0.15). In addition, a DMRG study of a dipolar Heisenberg model with longer range interactions gives evidence for a spin liquid at a small dipole tilting angle θ∈[0,10°)...
May 4, 2018: Physical Review Letters
https://www.readbyqxmd.com/read/29774618/direct-laser-writing-of-graphene-made-from-chemical-vapor-deposition-for-flexible-integratable-micro-supercapacitors-with-ultrahigh-power-output
#9
Jianglin Ye, Huabing Tan, Shuilin Wu, Kun Ni, Fei Pan, Jie Liu, Zhuchen Tao, Yan Qu, Hengxing Ji, Patrice Simon, Yanwu Zhu
High-performance yet flexible micro-supercapacitors (MSCs) hold great promise as miniaturized power sources for increasing demand of integrated electronic devices. Herein, this study demonstrates a scalable fabrication of multilayered graphene-based MSCs (MG-MSCs), by direct laser writing (DLW) of stacked graphene films made from industry-scale chemical vapor deposition (CVD). Combining the dry transfer of multilayered CVD graphene films, DLW allows a highly efficient fabrication of large-areal MSCs with exceptional flexibility, diverse planar geometry, and capability of customer-designed integration...
May 17, 2018: Advanced Materials
https://www.readbyqxmd.com/read/29773812/strain-induced-electronic-structure-variation-in-methyl-ammonium-lead-iodide-perovskite
#10
Le Zhang, Wei Geng, Chuan-Jia Tong, Xueguang Chen, Tengfei Cao, Mingyang Chen
Methyl-ammonium lead iodide perovskite (CH3 NH3 PbI3 ) has drawn great attention due to its excellent photovoltaic properties. Because of its loosely compacted structure, the structural, electronic and optical properties of CH3 NH3 PbI3 are sensitive to external modulations. Strain effects on CH3 NH3 PbI3 are fully investigated by the first principles calculations. The results indicate that the inorganic framework deforms under compression or stretch and the embedded organic CH3 NH3 + molecules rotate correspondingly...
May 17, 2018: Scientific Reports
https://www.readbyqxmd.com/read/29773349/robot-assisted-training-using-hybrid-assistive-limb%C3%A2-for-cerebral-palsy
#11
Mayumi Matsuda, Nobuaki Iwasaki, Yuki Mataki, Hirotaka Mutsuzaki, Kenichi Yoshikawa, Kazushi Takahashi, Keiko Enomoto, Kumiko Sano, Aoi Kubota, Tomohiro Nakayama, Junko Nakayama, Haruka Ohguro, Masafumi Mizukami, Kazuhide Tomita
PURPOSE: The Hybrid Assistive Limb® (HAL®, CYBERDYNE) is a wearable robot that provides assistance to a patient while they are walking, standing, and performing leg movements based on the wearer's intended movement. The effect of robot-assisted training using HAL® for cerebral palsy (CP) is unknown. Therefore, we assessed the effect of robot-assisted training using HAL® on patients with CP, and compared walking and gross motor abilities between pre-intervention and post-intervention...
May 14, 2018: Brain & Development
https://www.readbyqxmd.com/read/29772723/evolution-of-grain-interfaces-in-annealed-duplex-stainless-steel-after-parallel-cross-rolling-and-direct-rolling
#12
Ming Wang, Haoqing Li, Yujing Tian, Hong Guo, Xiaoying Fang, Yuebin Guo
Changes in various grain interfaces, including the grain boundary and phase boundary, are a strong indication of microstructural changes, particularly ultra-fined grains achieved by large strain deformation and subsequent annealing. After direct rolling and cross rolling with the same strain of ε = 2, the distributions of the interfaces in annealed UNS S32304 duplex stainless steel were investigated using electron backscatter diffraction (EBSD) in this study. The ferrite experienced continued recovery, and a high density of low-angle grain boundaries (LAGBs) was produced...
May 16, 2018: Materials
https://www.readbyqxmd.com/read/29770636/factors-associated-with-outcomes-of-combined-phacoemulsification-and-ahmed-glaucoma-valve-implantation
#13
Junki Kwon, Kyung Rim Sung
PURPOSE: To evaluate outcomes and factors associated with surgical failure in patients who underwent combined phacoemulsification and Ahmed glaucoma valve (AGV) implantation. METHODS: This retrospective and longitudinal study enrolled 40 eyes (38 patients) that underwent combined phacoemulsification and AGV implantation. Visual acuity, intraocular pressure (IOP), and number of antiglaucoma medications were evaluated preoperatively and postoperatively. Complete success was defined as a last follow-up IOP of 6 to 21 mmHg without medication, qualified success as an IOP of 6 to 21 mmHg with medication, and failure as an IOP of >21 or <6 mmHg...
May 15, 2018: Korean Journal of Ophthalmology: KJO
https://www.readbyqxmd.com/read/29769595/turbulence-and-cavitation-suppression-by-quaternary-ammonium-salt-additives
#14
Homa Naseri, Kieran Trickett, Nicholas Mitroglou, Ioannis Karathanassis, Phoevos Koukouvinis, Manolis Gavaises, Robert Barbour, Dale Diamond, Sarah E Rogers, Maurizio Santini, Jin Wang
We identify the physical mechanism through which newly developed quaternary ammonium salt (QAS) deposit control additives (DCAs) affect the rheological properties of cavitating turbulent flows, resulting in an increase in the volumetric efficiency of clean injectors fuelled with diesel or biodiesel fuels. Quaternary ammonium surfactants with appropriate counterions can be very effective in reducing the turbulent drag in aqueous solutions, however, less is known about the effect of such surfactants in oil-based solvents or in cavitating flow conditions...
May 16, 2018: Scientific Reports
https://www.readbyqxmd.com/read/29769558/high-speed-fourier-ptychographic-microscopy-based-on-programmable-annular-illuminations
#15
Jiasong Sun, Chao Zuo, Jialin Zhang, Yao Fan, Qian Chen
High-throughput quantitative phase imaging (QPI) is essential to cellular phenotypes characterization as it allows high-content cell analysis and avoids adverse effects of staining reagents on cellular viability and cell signaling. Among different approaches, Fourier ptychographic microscopy (FPM) is probably the most promising technique to realize high-throughput QPI by synthesizing a wide-field, high-resolution complex image from multiple angle-variably illuminated, low-resolution images. However, the large dataset requirement in conventional FPM significantly limits its imaging speed, resulting in low temporal throughput...
May 16, 2018: Scientific Reports
https://www.readbyqxmd.com/read/29768838/mesoporous-cds-via-network-of-self-assembled-nanocrystals-synthesis-characterization-and-enhanced-photoconducting-property
#16
Astam K Patra, Biplab Banerjee, Asim Bhaumik
Semiconduction nanoparticles are intensively studied due to their huge potential in optoelctronic applications. Here we report an efficient chemical route for hydrothermal synthesis of aggregated mesoporous cadmium sulfide (CdS) nanoparticles using supramolecular-assembly of ionic and water soluble sodium salicylate as the capping agent. The nanostructure, mesophase, optical property and photoconductivity of these mesoporous CdS materials have been characterized by using small and wide angle powder X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), N2-sorption, Raman analysis, Fourier transformed infrared (FT-IR), UV-Visible DSR spectroscopy, and photoconductivity measurement...
January 1, 2018: Journal of Nanoscience and Nanotechnology
https://www.readbyqxmd.com/read/29768815/selective-hydrogenation-of-cinnamaldehyde-over-platinum-nanosheets-intercalated-between-graphite-layers
#17
Mami Horie, Kazuki Takahashi, Hidetaka Nanao, Masayuki Shirai
Platinum nanosheets between graphite layers were prepared by a thermal treatment of the mixture of platinum chloride (IV) and graphite powder under 0.3 MPa of chlorine at 723 K for 7 days, followed by the reduction under 40 kPa of hydrogen at 573 K for 1 h. Two-dimensional platinum metal nanosheets of 1-3 nm thickness and of 100-200 nm width were intercalated between graphite layers (Pt-GIC). The platinum nanosheets had a number of hexagonal holes and edges with angle of 120°. Liquid phase hydrogenation of cinnamaldehyde (CAL) was studied over Pt-GIC which was compared with that over platinum metal particles supported on graphite layers (Pt/Gmix)...
January 1, 2018: Journal of Nanoscience and Nanotechnology
https://www.readbyqxmd.com/read/29768016/cisplatin-encapsulation-generates-morphologically-different-multi-compartments-in-the-internal-nanostructures-of-non-lamellar-liquid-crystalline-self-assemblies
#18
Intan Diana Mat Azmi, Jesper Ostergaard, Stefan Sturup, Bente Gammelgaard, Arto Urtti, Seyed Moein Moghimi, Anan Yaghmur
Cisplatin (cis-diamminedichloroplatinum (II)) is among the most potent cytotoxic agents used in cancer chemotherapy. The encapsulation of cisplatin in lipid-based drug carriers has been challenging owing to its low solubility in both aqueous and lipid phases. Here, we investigated cisplatin encapsulation in non-lamellar liquid crystalline (LC) nanodispersions formed from a ternary mixture of phytantriol (PHYT), vitamin E (Vit E) and an anionic phospholipid [either phosphatidylglycerol (DSPG) or phosphatidylserine (DPPS)]...
May 16, 2018: Langmuir: the ACS Journal of Surfaces and Colloids
https://www.readbyqxmd.com/read/29765904/cyclic-fatigue-resistance-torsional-resistance-and-metallurgical-characteristics-of-m3-rotary-and-m3-pro-gold-niti-files
#19
Eugenio Pedullà, Fabio Lo Savio, Giusy Rita Maria La Rosa, Gabriele Miccoli, Elena Bruno, Silvia Rapisarda, Seok Woo Chang, Ernesto Rapisarda, Guido La Rosa, Gianluca Gambarini, Luca Testarelli
Objectives: To evaluate the mechanical properties and metallurgical characteristics of the M3 Rotary and M3 Pro Gold files (United Dental). Materials and Methods: One hundred and sixty new M3 Rotary and M3 Pro Gold files (sizes 20/0.04 and 25/0.04) were used. Torque and angle of rotation at failure ( n = 20) were measured according to ISO 3630-1. Cyclic fatigue resistance was tested by measuring the number of cycles to failure in an artificial stainless steel canal (60° angle of curvature and a 5-mm radius)...
May 2018: Restorative Dentistry & Endodontics
https://www.readbyqxmd.com/read/29765825/early-career-surgical-practice-for-cerebellopontine-angle-tumors-in-the-era-of-radiosurgery
#20
Giannantonio Spena, Tommaso Sorrentino, Roberto Altieri, Luca Redaelli de Zinis, Roberto Stefini, Pier Paolo Panciani, Marco Fontanella
We analyzed the outcomes of patients with large cerebellopontine angle (CPA) tumors treated by a skull-base team in which two surgeons (one neurosurgeon and one otological surgeon) were in the beginning of their careers (<40 years old). Data of patients operated on between April 2012 and March 2016 were reviewed. All factors related to surgical training were considered. Thirty-one patients had vestibular schwannomas, while 26 had meningiomas. Mean tumor diameter was 30.6 mm (range, 23-49 mm) for schwannomas and 35 mm (range, 22-51 mm) for meningiomas...
June 2018: Journal of Neurological Surgery. Part B, Skull Base
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