Ying-Ying Wu, Zhao-Yang Li, Shuang Peng, Zi-Yi Zhang, Hao-Ming Cheng, Hang Su, Wen-Qi Hou, Feng-Lei Yang, Shu-Qi Wu, Osamu Sato, Jing-Wei Dai, Wei Li, Xian-He Bu
Spin-crossover (SCO) materials exhibit remarkable potential as bistable switches in molecular devices. However, the spin transition temperatures ( T c ) of known compounds are unable to cover the entire ambient temperature spectrum, largely limiting their practical utility. This study reports an exemplary two-dimensional SCO solid solution system, [Fe III (H 0.5 L Cl ) 2 - 2 x (H 0.5 L F ) 2 x ]·H 2 O (H 0.5 L X = 5- X -2-hydroxybenzylidene-hydrazinecarbothioamide, X = F or Cl, x = 0 to 1), in which the adjacent layers are adhered via hydrogen bonding...
February 27, 2024: Journal of the American Chemical Society