keyword
https://read.qxmd.com/read/38656766/three-dimensional-crystalline-organic-framework-stabilized-by-molecular-mortise-and-tenon-jointing
#1
JOURNAL ARTICLE
Xinru Sheng, Zeju Wang, Guan Sheng, Chongzhi Zhu, Ding Xiao, Tianyu Shan, Xuedong Xiao, Ming Liu, Guangfeng Li, Yihan Zhu, Jonathan L Sessler, Feihe Huang
Three-dimensional (3D) crystalline organic frameworks with complex topologies, high surface area, and low densities afford a variety of application prospects. However, the design and construction of these frameworks have been largely limited to systems containing polyhedron-shaped building blocks or those relying on component interpenetration. Here, we report the synthesis of a 3D crystalline organic framework based on molecular mortise-and-tenon jointing. This new material takes advantage of tetra(4-pyridylphenyl)ethylene and chlorinated bis(benzodioxaborole)benzene as building blocks and is driven by dative B-N bonds...
April 24, 2024: Journal of the American Chemical Society
https://read.qxmd.com/read/38653422/removal-and-fate-of-microplastics-in-permeable-pavements-an-experimental-layer-by-layer-analysis
#2
JOURNAL ARTICLE
Eduardo García-Haba, Alba Benito-Kaesbach, Carmen Hernández-Crespo, Carlos Sanz-Lazaro, Miguel Martín, Ignacio Andrés-Doménech
The increasing prevalence of microplastics (MP) in urban environments has raised concerns over their negative effects on ecosystems and human health. Stormwater runoff, and road dust and sediment, act as major vectors of these pollutants into natural water bodies. Sustainable urban drainage systems, such as permeable pavements, are considered as potential tools to retain particulate pollutants. This research evaluates at laboratory scale the efficiency of permeable interlocking concrete pavements (PICP) and porous concrete pavements (PCP) for controlling microplastics, including tire wear particles (TWP) which constitute a large fraction of microplastics in urban environments, simulating surface pollution accumulation and Mediterranean rainfall conditions...
April 21, 2024: Science of the Total Environment
https://read.qxmd.com/read/38645079/design-and-pilot-study-of-a-high-fidelity-medical-simulation-of-a-hospital-wide-cybersecurity-attack
#3
Brennan Marsh-Armstrong, Fernanda Pacheco, Christian Dameff, Jeffrey Tully
Background: Cybersecurity incidents affecting hospitals have grown in prevalence and consequence over the last two decades, increasing the importance of cybersecurity preparedness and response training to minimize clinical disruptions. This work describes the development, execution, and post-exercise assessment of a novel simulation scenario consisting of four interlocking intensive care unit (ICU) patient scenarios. This simulation was designed to demonstrate the management of acute pathologies without access to conventional treatment methods during a cybersecurity incident in order to raise clinician awareness of the increasing incidence and patient safety implications of such events...
April 5, 2024: Research Square
https://read.qxmd.com/read/38643655/sequential-treatment-of-concomitant-odontoid-fracture-and-lower-cervical-fracture-dislocation-a-case-report
#4
Yuanchen Zhu, Jin Qian, Hanfeng Hu, Feng Zhou, Huilin Yang, Jinhui Shi
INTRODUCTION AND IMPORTANCE: To report the sequential treatment of a Type II odontoid fracture combined with a severe lower cervical (C6-7) fracture-dislocation featuring bilateral facet joint interlocking. CASE PRESENTATION: A 58-year-old male who had suffered an injury in a car accident, He presented neck pain and extremity paralysis. His neurological function was classified as per the American Spinal Injury Association (ASIA) impairment scale as Grade A, indicating complete deficits below the C6 spinal cord level...
April 20, 2024: International Journal of Surgery Case Reports
https://read.qxmd.com/read/38641631/digital-quantification-of-the-mmse-interlocking-pentagon-areas-a-three-stage-algorithm
#5
JOURNAL ARTICLE
Namhee Kim, Timothy Truty, S Duke Han, Moonseong Heo, Aron S Buchman, David A Bennett, Shinya Tasaki
The Mini-Mental State Examination (MMSE) is a widely employed screening tool for the severity of cognitive impairment. Among the MMSE items, the pentagon copying test (PCT) requires participants to accurately replicate a sample of two interlocking pentagons. While the PCT is traditionally scored on a binary scale, there have been limited developments of granular scoring scale to assess task performance. In this paper, we present a novel three-stage algorithm, called Quantification of Interlocking Pentagons (QIP) which quantifies PCT performance by computing the areas of individual pentagons and their intersection areas, and a balance ratio between the areas of the two individual pentagons...
April 19, 2024: Scientific Reports
https://read.qxmd.com/read/38638110/gender-systems-in-the-putin-autocracy
#6
JOURNAL ARTICLE
Elizabeth A Wood
Over the last 23 years, Russian President Vladimir Putin's autocracy has revealed a set of interlocking gender systems that have come to the fore particularly vividly since the full-scale invasion of Ukraine on February 24, 2022. How, this article asks, have the masculinist cultural and political practices of the Putin regime undermined democratic practices and engagement broadly speaking? How have they organized Russian state and society in ways that have led to today's war in Ukraine with its massive destruction, violence, and brutality? And have there been earlier signals that should have warned observers that this regime might undertake such a war of aggression? Drawing on public, mass media data, this article analyzes the gendered structures of power in Russia that have contributed to the degeneration of democracy in three main areas: (1) male-on-male domination in discourse and practice that supports Putin's personal rule and emasculates his enemies; (2) the elevation of male power clans, including the President's personal praetorian guard and the Russian private military companies; and (3) the overall taming and emasculation of the Russian Parliament combined with the elevation of tough women deputies, whom I call the Baba Commissars...
2024: Frontiers in sociology
https://read.qxmd.com/read/38636212/relationship-between-social-support-and-self-perceived-burden-in-patients-with-obstructive-sleep-apnea-an-analysis-of-chain-mediated-effects
#7
JOURNAL ARTICLE
Jie Kong, Chunguang Liang, Ying Zhao, Qing Chen, Huameng Xv, Xiangru Yan, Hui Zhang, Huiying Zhang
OBJECTIVE: To estigate the relationship between social support, self-efficacy, coping style, and self-perceived burden and the mechanisms that underlie the action in Chinese OSA patients. METHODS: Between October 2022 and June 2023,316 OSA patients from two hospitals were surveyed. Data were collected using the General Demographic Characteristics Questionnaire, Social Support Rating Scale (SSRS), Self-Efficacy for Chronic Disease Scale (SECD6), and Simple Coping Style Questionnaire (SCSQ)...
April 11, 2024: Sleep Medicine
https://read.qxmd.com/read/38635355/constructing-a-novel-moderately-modulus-rigid-flexible-structure-with-synergistic-reinforcement-on-the-carbon-fiber-surface-to-enhance-the-mechanical-properties-of-carbon-fiber-epoxy-composites-at-elevated-temperatures
#8
JOURNAL ARTICLE
Peifeng Feng, Lichun Ma, Mingguang Zhang, Yiling Quan, Mingzhuan Li, Xin Zhou, Xingyao Liu, Xigao Jian, Jian Xu
To improve the mechanical performance of carbon fiber (CF)/epoxy composites in high-temperature environments, a moderately modulus gradient modulus interlayer was constructed at the interface phase region of composites. This involved the design of a "rigid-flexible" synergistic reinforcement structure, incorporating rigid nanoparticle GO@CNTs and a flexible polymer polynaphthyl ether nitrile ketone onto the CF surface. Notably, at 180 °C, compared to commercial CF composites, the CF-GO@CNTs-PPENK composites displayed a remarkable improvement in their mechanical characteristics (interfacial shear, interlaminar shear, flexural strength, and modulus), achieving enhancements of 173...
April 18, 2024: ACS Applied Materials & Interfaces
https://read.qxmd.com/read/38631082/a-novel-surgical-technique-for-removal-of-intramedullary-nails-when-there-is-a-failure-of-the-proximal-extraction-device-report-of-two-cases-and-review-of-literature
#9
REVIEW
Devendra Pathrot, Sunil Mannual, Srinath K M, Chidendra M Shettar
Diaphyseal fractures of the tibia is a common injury with an incidence of 16.9/100,000 population. Surgical treatment with intramedullary interlocking nail is the treatment of choice in closed diaphyseal tibial injuries. Removal of the nail is required in non-union, infected implant, implant failure or during exchange nailing procedure. Implant removal surgery presents some unique challenges to the Orthopaedic surgeons like broken nails, broken screws and failure of the extraction devices to engage with the threads of the nail due to stripping of the threads in the proximal part of the nail...
April 4, 2024: Injury
https://read.qxmd.com/read/38630641/mass-produced-skin-inspired-piezoresistive-sensing-array-with-interlocking-interface-for-object-recognition
#10
JOURNAL ARTICLE
Shenglong Wang, Yelan Yao, Weili Deng, Xiang Chu, Tao Yang, Guo Tian, Yong Ao, Yue Sun, Boling Lan, Xiarong Ren, Xuelan Li, Tianpei Xu, Longchao Huang, Yang Liu, Jun Lu, Weiqing Yang
E-skins, capable of responding to mechanical stimuli, hold significant potential in the field of robot haptics. However, it is a challenge to obtain e-skins with both high sensitivity and mechanical stability. Here, we present a bioinspired piezoresistive sensor with hierarchical structures based on polyaniline/polystyrene core-shell nanoparticles polymerized on air-laid paper. The combination of laser-etched reusable templates and sensitive materials that can be rapidly synthesized enables large-scale production...
April 17, 2024: ACS Nano
https://read.qxmd.com/read/38625182/metacontingency-terminology-philosophical-assumptions-and-the-scientific-dialogue-a-response-to-ardila-s%C3%A3-nchez-and-hayes-2023
#11
JOURNAL ARTICLE
Angelo A S Sampaio, Verônica Bender Haydu
Ardila-Sánchez and Hayes (2023, this issue) discuss how differing philosophical assumptions might reflect on differing metacontingency terminology and debate some of the arguments presented by Sampaio and Haydu (2023). We respond by restating the urgent need to clarify the definition of cultural milieu, which is illustrated by an argument about discriminative stimuli as components of the cultural milieu. We clarify that the differences in metacontingency terminology that we did not emphasize were related to interlocking behavioral contingencies (IBCs) and cultural consequences, and not to cultural milieu and group-rule generation...
May 18, 2023: Behavior and social issues
https://read.qxmd.com/read/38623556/illegal-interlocks-among-life-science-company-boards-of-directors
#12
JOURNAL ARTICLE
Anoop Manjunath, Nathan Kahrobai, Mark A Lemley, Ishan Kumar
Competition between life science companies is critical to ensure innovative therapies are efficiently developed. Anticompetitive behavior may harm scientific progress and, ultimately, patients. One well-established category of anticompetitive behavior is the 'interlocking directorate'. It is illegal for companies' directors to 'interlock' by also serving on the boards of competitors. We evaluated overlaps in the board membership of 2,241 public life science companies since 2000. We show that a robust network of interlocking companies is present among these firms...
2024: Journal of Law and the Biosciences
https://read.qxmd.com/read/38622039/are-extra-locking-bolts-or-fibular-plating-more-important-in-extreme-nailing-of-distal-tibia-fractures-a-cadaveric-biomechanical-analysis
#13
JOURNAL ARTICLE
Daniel J Cunningham, Joshua E Lawrence, Murali Kovvur, Kristin E Turner, Giovanni Oppizzi, Dali Xu, Li-Qun Zhang, Daniel J Johnson, Peter Mittwede, Aresh Sepehri, Jordan Brand, Robert V O'Toole, Mark J Gage
OBJECTIVES: In far-distal extra-articular tibia fracture "extreme" nailing, debate surrounds the relative biomechanical performance of plating the fibula compared with extra distal interlocks. This study aimed to evaluate several constructs for extreme nailing including one interlock (one medial-lateral interlock), one interlock + plate (one medial-lateral interlock with lateral fibula compression plating), and two interlocks (one medial-lateral interlock and one anterior-posterior interlock)...
April 4, 2024: Injury
https://read.qxmd.com/read/38621564/sustainable-high-strength-and-dimensionally-stable-composites-through-in-situ-regulation-and-reconstitution-of-bamboo-derived-lignin-and-hemicellulose-contents
#14
JOURNAL ARTICLE
Shanyu Han, Xiaoyi Chen, Fuming Chen, Zhichao Lou, Xueyong Ren, Hanzhou Ye, Ge Wang
The development of modern construction and transportation industries demands increasingly high requirements for thin, lightweight, high-strength, and highly tough composite materials, such as metal carbides and concrete. Bamboo is a green, low-carbon, fast-growing, renewable, and biodegradable material with high strength and toughness. However, the density of its inner layer is low due to the functional gradient (the volume fraction of vascular bundles decreases from the outer layer to the inner layer), resulting in low performance, high compressibility, and significant amounts of bamboo waste...
April 13, 2024: International Journal of Biological Macromolecules
https://read.qxmd.com/read/38616813/unraveling-the-influence-of-topology-and-spatial-confinement-on-equilibrium-and-relaxation-properties-of-interlocked-ring-polymers
#15
JOURNAL ARTICLE
Michele Caraglio, Cristian Micheletti, Enzo Orlandini
We use Langevin dynamics simulations to study linked ring polymers in channel confinement. We address the in- and out-of-equilibrium behavior of the systems for varying degrees of confinement and increasing topological and geometrical complexity of the interlocking. The main findings are three. First, metric observables of different link topologies collapse onto the same master curve when plotted against the crossing number, revealing a universal response to confinement. Second, the relaxation process from initially stretched states is faster for more complex links...
April 9, 2024: Macromolecules
https://read.qxmd.com/read/38615392/coatless-modification-of-3d-printed-ti6al4v-implants-through-tailored-cu-ion-implantation-combined-with-uv-photofunctionalization-to-enhance-cell-attachment-osteogenesis-and-angiogenesis
#16
JOURNAL ARTICLE
Jiedong Wang, Zehao Jing, Chuan Yin, Zhengguang Wang, Shengxin Zeng, Xiaolin Ma, Yufeng Zheng, Hong Cai, Zhongjun Liu
The three-dimensional-printed Ti6Al4V implant (3DTi) has been widely accepted for the reconstruction of massive bone defects in orthopedics owing to several advantages, such as its tailored shape design, avoiding bone graft and superior bone-implant interlock. However, the osteoinduction activity of 3DTi is inadequate when applied clinically even though it exhibits osteoconduction. This study developes a comprehensive coatless strategy for the surface improvement of 3DTi through copper (Cu) ion implantation and ultraviolet (UV) photofunctionalization to enhance osteoinductivity...
April 6, 2024: Colloids and Surfaces. B, Biointerfaces
https://read.qxmd.com/read/38615140/interlocking-intramedullary-nail-for-forearm-diaphyseal-fractures-in-adults-a-systematic-review-and-meta-analysis-of-outcomes-and-complications
#17
Ali Lari, Yousef Hassan, Abdulwahab Altammar, Ali Esmaeil, Abdulaziz Altammar, Carlos Prada, Ali Jarragh
PURPOSE: The purpose of this systematic review is to examine the outcomes, complications, and potential advantages of using anatomical interlocking intramedullary nails (IMN) in the treatment of radius and ulnar shaft diaphyseal fractures in adults. METHODS: Medline, Embase, Web of Science, and Cumulative Index to Nursing and Allied Health Literature (CINAHL) databases were searched between January 2000 and January 2023. Studies meeting criteria were observational or randomized controlled trials evaluating outcomes in IMN for adult diaphyseal forearm fractures...
April 13, 2024: Journal of Orthopaedics and Traumatology: Official Journal of the Italian Society of Orthopaedics and Traumatology
https://read.qxmd.com/read/38611265/a-novel-nanofiber-hydrogel-adhesive-based-on-carboxymethyl-cellulose-modified-by-adenine-and-thymine
#18
JOURNAL ARTICLE
Chong Xie, Runde Yang, Xing Wan, Haorong Li, Liangyao Ge, Xiaofeng Li, Guanglei Zhao
Natural polymer-based adhesive hydrogels have garnered significant interest for their outstanding strength and versatile applications, in addition to being eco-friendly. However, the adhesive capabilities of purely natural products are suboptimal, which hampers their practical use. To address this, we engineered carboxymethyl cellulose (CMC) surfaces with complementary bases, adenine (A) and thymine (T), to facilitate the self-assembly of adhesive hydrogels (CMC-AT) with a nanofiber configuration. Impressively, the shear adhesive strength reached up to 6...
April 7, 2024: Polymers
https://read.qxmd.com/read/38607039/the-role-of-the-nlrp3-inflammasome-in-the-molecular-and-biochemical-mechanisms-of-cervical-ripening-a-comprehensive-review
#19
REVIEW
Wojciech Flis, Maciej W Socha
The uterine cervix is one of the key factors involved in ensuring a proper track of gestation and labor. At the end of the gestational period, the cervix undergoes extensive changes, which can be summarized as a transformation from a non-favorable cervix to one that is soft and prone to dilation. During a process called cervical ripening, fundamental remodeling of the cervical extracellular matrix (ECM) occurs. The cervical ripening process is a derivative of many interlocking and mutually driving biochemical and molecular pathways under the strict control of mediators such as inflammatory cytokines, nitric oxide, prostaglandins, and reactive oxygen species...
March 29, 2024: Cells
https://read.qxmd.com/read/38602795/telling-a-scientific-story-and-governing-the-population-the-kallikak-story-and-the-historical-mutations-of-the-eugenic-discourse
#20
JOURNAL ARTICLE
Thom Axelsson, Jonas Qvarsebo
In this article, we follow the trails of 20th-century psychologist Henry Herbert Goddard's influential study of the Kallikak family. Goddard's study is treated as a scientific story with two interlocking dimensions: One is the actual story of the Kallikak family, with literary elements such as setting, plot, and characters. The other dimension is the broader eugenic discourse, a powerful scientific narrative that calls for action in relation to society and the population. The purpose of the article is twofold...
April 11, 2024: History of Psychology
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