Mariya Aleksich, Daniel W Paley, Elyse A Schriber, Will Linthicum, Vanessa Oklejas, David W Mittan-Moreau, Ryan P Kelly, Patience A Kotei, Anita Ghodsi, Raymond G Sierra, Andrew Aquila, Frédéric Poitevin, Johannes P Blaschke, Mohammad Vakili, Christopher J Milne, Fabio Dall'Antonia, Dmitry Khakhulin, Fernando Ardana-Lamas, Frederico Lima, Joana Valerio, Huijong Han, Tamires Gallo, Hazem Yousef, Oleksii Turkot, Ivette J Bermudez Macias, Thomas Kluyver, Philipp Schmidt, Luca Gelisio, Adam R Round, Yifeng Jiang, Doriana Vinci, Yohei Uemura, Marco Kloos, Mark Hunter, Adrian P Mancuso, Bryan D Huey, Lucas R Parent, Nicholas K Sauter, Aaron S Brewster, J Nathan Hohman
New synthetic hybrid materials and their increasing complexity have placed growing demands on crystal growth for single-crystal X-ray diffraction analysis. Unfortunately, not all chemical systems are conducive to the isolation of single crystals for traditional characterization. Here, small-molecule serial femtosecond crystallography (smSFX) at atomic resolution (0.833 Å) is employed to characterize microcrystalline silver n- alkanethiolates with various alkyl chain lengths at X-ray free electron laser facilities, resolving long-standing controversies regarding the atomic connectivity and odd-even effects of layer stacking...
July 31, 2023: Journal of the American Chemical Society