keyword
https://read.qxmd.com/read/38565727/physicochemical-properties-and-heavy-metal-concentration-of-soils-along-enyigba-mining-site-in-ikwo-ebonyi-state-nigeria
#21
JOURNAL ARTICLE
Odera Chukwumaijem Okafor, Miracle Ogbonne Onwumere, Chidinma Susan Iroegbu, Charles Ndubuisi Mbah
This study assessed the physicochemical properties of soils and their levels of heavy metal contents in soils along the Enyigba mining site in Ikwo, Ebonyi State, Nigeria. A total of 96 samples of soil were taken at depths of 0 to 20 cm using a soil auger and core sampler at a horizontal spacing of 100 m between each location and examined using standard laboratory techniques. The control soil samples were taken from the Alex Ekwueme Federal University Experimental and Research Farm in Ebonyi State, at a distance of 50 m from each spot at a depth of 0 to 20 cm...
April 3, 2024: Environmental Monitoring and Assessment
https://read.qxmd.com/read/38561533/water-and-sediment-chemistry-drivers-of-chlorophyll-a-dynamics-within-a-ramsar-declared-floodplain-pan-wetland-system
#22
JOURNAL ARTICLE
Linton F Munyai, Lutendo Mugwedi, Ryan J Wasserman, Farai Dondofema, Eddie Riddell, Chad Keates, Tatenda Dalu
Floodplain pans are hydrologically dynamic in nature and characterised by variables such as chlorophyll-a (chl-a), water, and sediment chemistry over their hydroperiods. The present study investigated the spatio-temporal variations in water and sediment physico-chemical, and chlorophyll-a concentration characteristics of six floodplain pans found in the Ramsar declared Makuleke wetlands, Kruger National Park, South Africa. The water and sediment physico-chemical variable values were generally elevated during the high-water period, whereas chlorophyll-a concentrations varied across pans and hydroperiod...
April 1, 2024: Environmental Science and Pollution Research International
https://read.qxmd.com/read/38561357/atomic-reconstruction-for-realizing-stable-solar-driven-reversible-hydrogen-storage-of-magnesium-hydride
#23
JOURNAL ARTICLE
Xiaoyue Zhang, Shunlong Ju, Chaoqun Li, Jiazheng Hao, Yahui Sun, Xuechun Hu, Wei Chen, Jie Chen, Lunhua He, Guanglin Xia, Fang Fang, Dalin Sun, Xuebin Yu
Reversible solid-state hydrogen storage of magnesium hydride, traditionally driven by external heating, is constrained by massive energy input and low systematic energy density. Herein, a single phase of Mg2 Ni(Cu) alloy is designed via atomic reconstruction to achieve the ideal integration of photothermal and catalytic effects for stable solar-driven hydrogen storage of MgH2 . With the intra/inter-band transitions of Mg2 Ni(Cu) and its hydrogenated state, over 85% absorption in the entire spectrum is achieved, resulting in the temperature up to 261...
April 1, 2024: Nature Communications
https://read.qxmd.com/read/38556358/risk-factors-of-cetuximab-induced-hypomagnesemia-and-the-effect-of-magnesium-prophylaxis-in-patients-with-head-and-neck-cancer-a-retrospective-study
#24
JOURNAL ARTICLE
Ryosuke Matsukane, Risa Isshiki, Kimitaka Suetsugu, Haruna Minami, Kojiro Hata, Mioko Matsuo, Nobuaki Egashira, Takeshi Hirota, Takashi Nakagawa, Ichiro Ieiri
Hypomagnesemia is a characteristic adverse event of cetuximab in patients with head and neck cancer (HNC). However, there is limited information about its prevalence, risk factors, and preventive strategies. This study aimed to investigate the risk factors of hypomagnesemia and examine the preventive effects of prophylactic magnesium (Mg) administration. We initially investigated HNC patients treated with cetuximab between 2013 and 2019. Our institute started prophylactic Mg treatment (20-mEq Mg sulfate administration before cetuximab) in practice during this period...
2024: Biological & Pharmaceutical Bulletin
https://read.qxmd.com/read/38555611/-influence-of-the-rat-diet-enrichment-with-oat-%C3%AE-gucans-on-the-assimilation-of-b-group-vitamins-mineral-elements-and-lipid-metabolism
#25
JOURNAL ARTICLE
V M Kodentsova, O V Kosheleva, O A Vrzhesinskaya, G V Guseva, V A Zotov, S N Leonenko, N V Zhilinskaya
Despite the widespread use of oat β-glucans as ingredient of foods and dietary supplements, there is insufficient data on their effect on the metabolism of vitamins and minerals. The purpose of the study was to evaluate the effect of including oat bran with a high content of β-glucans (β-glucan) in the diet on the absorption of micronutrients and lipid metabolism in growing rats deficient in vitamins D, group B and trace elements (iron, copper, zinc). Material and methods . After the development of micronutrient deficiency (for 23 days), in order to assess the effect of oat bran (5%) with a high content of β-glucans on the correction of the micronutrient status of growing male Wistar rats (with initial body weight of 70...
2024: Voprosy Pitaniia
https://read.qxmd.com/read/38552517/medical-waste-incineration-fly-ash-based-magnesium-potassium-phosphate-cement-calcium-reinforced-chlorine-solidification-stabilization-mechanism-and-optimized-carbon-reduction-process-strategy
#26
JOURNAL ARTICLE
Runjie Liu, Shiwei Liu, Shichang Sun, Xing Cao, Junhao Lin, Juan Peng, Fei Ji, Rui Ma
The traditional solidification/stabilization (S/S) technology, Ordinary Portland Cement (OPC), has been widely criticized due to its poor resistance to chloride and significant carbon emissions. Herein, a S/S strategy based on magnesium potassium phosphate cement (MKPC) was developed for the medical waste incineration fly ash (MFA) disposal, which harmonized the chlorine stabilization rate and potential carbon emissions. The in-situ XRD results indicated that the Cl- was efficiently immobilized in the MKPC system with coexisting Ca2+ by the formation of stable Ca5 (PO4 )3 Cl through direct precipitation or intermediate transformation (the Cl- immobilization rate was up to 77...
March 28, 2024: Journal of Environmental Management
https://read.qxmd.com/read/38549477/healthy-and-sustainable-school-meals-proposal-for-a-new-quality-index-smi-le
#27
JOURNAL ARTICLE
Marta Jeruszka-Bielak, Magdalena Górnicka
INTRODUCTION AND OBJECTIVE: Provision of healthy and high-quality school meals is an important solution to improve children's health and well-being. Moreover, the meals provided at schools should not only meet dietary guidelines but also questions of sustainability. The aim of the study was to develop a new index to assess the quality of school meal menus, specifically their accordance with actual regulations, dietary guidelines and some sustainability goals. MATERIAL AND METHODS: The School Meal Index-Lunch Evaluation (SMI-LE) is an originally created index to evaluate the quality of 5-day school menus...
March 25, 2024: Annals of Agricultural and Environmental Medicine: AAEM
https://read.qxmd.com/read/38548382/increased-oxidative-stress-in-shoe-industry-workers-with-low-level-exposure-to-a-mixture-of-volatile-organic-compounds
#28
JOURNAL ARTICLE
Nina Umićević, Jelena Kotur-Stevuljević, Katarina Baralić, Danijela Đukić-Ćosić, Evica Antonijević Miljaković, Aleksandra Buha Đorđević, Marijana Ćurčić, Zorica Bulat, Biljana Antonijević
This study aimed to assess the redox status and trace metal levels in 49 shoe industry workers (11 men and 38 women) occupationally exposed to a mixture of volatile organic compounds (VOCs), which includes aliphatic hydrocarbons, aromatic hydrocarbons, ketones, esters, ethers, and carboxylic acids. All measured VOCs were below the permitted occupational exposure limits. The control group included 50 unexposed participants (25 men and 25 women). The following plasma parameters were analysed: superoxide anion (O2 •- ), advanced oxidation protein products (AOPP), total oxidative status (TOS), prooxidant-antioxidant balance (PAB), oxidative stress index (OSI), superoxide dismutase (SOD) and paraoxonase-1 (PON1) enzyme activity, total SH group content (SHG), and total antioxidant status (TAS)...
March 1, 2024: Arhiv za Higijenu Rada i Toksikologiju
https://read.qxmd.com/read/38546167/advancing-lithium-magnesium-separation-pioneering-swelling-embedded-cation-exchange-membranes-based-on-sulfonated-poly-ether-ether-ketone
#29
JOURNAL ARTICLE
Hao Qian, Geting Xu, Shanshan Yang, Edison Huixiang Ang, Quan Chen, Chenfei Lin, Junbin Liao, Jiangnan Shen
With the continuous advancement of electrodialysis (ED) technology, there arises a demand for improved monovalent cation exchange membranes (CEMs). However, limitations in membrane materials and structures have resulted in the low selectivity of monovalent CEMs, posing challenges in the separation of Li+ and Mg2+ . In this investigation, a designed CEM with a swelling-embedded structure was created by integrating a polyelectrolyte containing N-oxide Zwitterion into a sulfonated poly(ether ether ketone) (SPEEK) membrane, leveraging the notable solubility characteristic of SPEEK...
March 28, 2024: ACS Applied Materials & Interfaces
https://read.qxmd.com/read/38545239/dietary-inflammatory-index-of-obese-individuals-with-obstructive-sleep-apnea-a-descriptive-study
#30
JOURNAL ARTICLE
Bianca Aparecida de Sousa, Beatriz Martins Vicente, Amália Almeida Bastos, Sandra Maria Lima Ribeiro, Rita de Cássia de Aquino, Marcus Vinícius Dos Santos Quaresma, Sergio Tufik, Marco Túlio De-Mello, Camila Maria de Melo
The objective of the present study was to describe the dietary inflammatory profile and its correlations with sleep parameters of obese individuals with obstructive sleep apnea (OSA). Forty individuals underwent nocturnal polysomnography, anthropometric measurements, body composition by plethysmography, assessment of food consumption by three-day food records, and blood collection for the lipid, glycemic and hormonal profile. Food consumption data were evaluated semiquantitatively, quantitalively assessment, and calculation of the dietary inflammatory index (DII) was perfomed...
March 2024: Sleep Science
https://read.qxmd.com/read/38542888/efficient-recovery-of-phosphate-from-water-media-by-iron-magnesium-functionalized-lignite-adsorption-evaluation-mechanism-revelation-and-potential-application-exploration
#31
JOURNAL ARTICLE
Wenbo An, Qiqi Wang, He Chen, Yifan Liu, Xuechun Hu, Junzhen Di
Selective phosphorus removal from aquatic media has become an ideal strategy to mitigate eutrophication and meet increasingly stringent discharge requirements. To achieve phosphorus control and resource utilization of low-calorific-value lignite, iron and magnesium salts were used to functionalize lignite, and iron-magnesium functionalized lignite (called IM@BC) was prepared for phosphate recovery from water media. The adsorption properties of IM@BC were systematically evaluated, especially the influence of ambient pH and co-existing ions...
March 12, 2024: Molecules: a Journal of Synthetic Chemistry and Natural Product Chemistry
https://read.qxmd.com/read/38541739/could-life-have-started-on-mars-planetary-conditions-that-assemble-and-destroy-protocells
#32
JOURNAL ARTICLE
Francesca C A Cary, David W Deamer, Bruce F Damer, Sarah A Fagents, Kathleen C Ruttenberg, Stuart P Donachie
Early Mars was likely habitable, but could life actually have started there? While cellular life emerged from prebiotic chemistry through a pre-Darwinian selection process relevant to both Earth and Mars, each planet posed unique selection 'hurdles' to this process. We focus on drivers of selection in prebiotic chemistry generic to Earth-like worlds and specific to Mars, such as an iron-rich surface. Iron, calcium, and magnesium cations are abundant in hydrothermal settings on Earth and Mars, a promising environment for an origin of life...
March 20, 2024: Life
https://read.qxmd.com/read/38541547/numerical-investigation-on-precipitation-hardening-of-mg-gd-alloys
#33
JOURNAL ARTICLE
Yulong Ge, Chunyan Yang, Yuwei Ma, Yang Chen, Manoj Gupta
The second-phase particles in magnesium alloys could affect the mechanical properties of the material significantly. In this work, 3D finite element models with explicit incorporation of second-phase particles are established. The simulations are calibrated with the experimental results of the Mg-1Gd alloy. The influences of factors, such as the particle distribution, size, and orientation of cylindrical particles, on precipitation hardening are investigated in detail. Three interface conditions between particles and the matrix-perfect bonding and high- and low-strength bonding-are studied at the same time...
March 19, 2024: Materials
https://read.qxmd.com/read/38537380/leaf-diffusional-capacity-largely-contributes-to-the-reduced-photosynthesis-in-rice-plants-under-magnesium-deficiency
#34
JOURNAL ARTICLE
Haimei Zhou, Jiang Peng, Wanling Zhao, Yongjun Zeng, Kailiu Xie, Guanjun Huang
Numerous studies have clarified the impacts of magnesium (Mg) on leaf photosynthesis from the perspectives of protein synthesis, enzymes activation and carbohydrate partitioning. However, it still remains largely unknown how stomatal and mesophyll conductances (gs and gm , respectively) are regulated by Mg. In the present study, leaf gas exchanges, leaf hydraulic parameters, leaf structural traits and cell wall composition were examined in rice plants grown under high and low Mg treatments to elucidate the impacts of Mg on gs and gm ...
March 26, 2024: Plant Physiology and Biochemistry: PPB
https://read.qxmd.com/read/38534358/diverse-prophage-elements-of-salmonella-enterica-serovars-show-potential-roles-in-bacterial-pathogenicity
#35
JOURNAL ARTICLE
Kirstie Andrews, Toby Landeryou, Thomas Sicheritz-Pontén, Janet Yakubu Nale
Nontyphoidal salmonellosis is an important foodborne and zoonotic infection that causes significant global public health concern. Diverse serovars are multidrug-resistant and encode several virulence indicators; however, little is known on the role prophages play in driving these traits. Here, we extracted prophages from seventy-five Salmonella genomes which represent the fifteen important serovars in the United Kingdom. We analyzed the intact prophages for the presence of virulence genes and established their genomic relationships...
March 14, 2024: Cells
https://read.qxmd.com/read/38533740/releasing-free-anions-by-high-donor-number-cosolvent-in-noncorrosive-electrolytes-of-commercially-available-magnesium-salts
#36
JOURNAL ARTICLE
Jianhua Xiao, Xinxin Zhang, Haiyan Fan, Qiyuan Lin, Zi Shyun Ng, Wenjie Chen, Yuegang Zhang
Passivation of the magnesium (Mg) anode in the chloride-free electrolytes using commercially available Mg salts is a critical issue for rechargeable Mg batteries. Herein, a high donor number cosolvent of 1-methylimidazolium (MeIm) is introduced into Mg(TFSI)2 - and Mg(HMDS)2 -based electrolytes to address the passivation problem and realize highly reversible Mg plating/stripping. Theoretical calculations and experimental characterization results reveal that the strong coordination ability of MeIm with Mg2+ can weaken the anion-cation interactions and promote the formation of free anions that have higher reduction stability, thus significantly suppressing anion-derived passivation layer formation...
March 27, 2024: ACS Applied Materials & Interfaces
https://read.qxmd.com/read/38527380/synthesis-and-biological-activity-of-thiophene-bioisosteres-of-natural-styryl-lactone-goniofufurone-and-related-compounds
#37
JOURNAL ARTICLE
Mirjana Popsavin, Sanja Djokić, Ivana Kovačević, Slađana M Stanisavljević, Vesna Kojić, Marko V Rodić, Lidija Aleksić, Jelena Kesić, Bojana Srećo Zelenović, Velimir Popsavin, Dimitar S Jakimov
Ten new thiophene derivatives related to goniofufurone have been obtained by multistep synthesis starting from d-glucose. The critical step of the synthesis was the Grignard reaction of 2-thienyl magnesium bromide with a protected dialdose, yielding the C-5 epimeric thiophene derivatives 9 and 10. The mixture was oxidized to the 5-keto derivative 11, which after deprotection was converted to the corresponding keto-lactone 14. Stereoselective reduction of 14 afforded the thiophene mimic of goniofufurone 3. Esterification of 3 with cinnamic or 4-fluorocinnamic acid gave hybrids 5-7...
March 21, 2024: European Journal of Medicinal Chemistry
https://read.qxmd.com/read/38525063/theoretical-study-on-the-role-of-magnesium-chloride-complexes-induced-by-different-magnesium-to-chlorine-ratios-in-magnesium-sulfur-batteries
#38
JOURNAL ARTICLE
Xiaoli Jiang, Panyu Zhang, Liyuan Jiang, Xinxin Zhao, Jianbao Wu
In magnesium-sulfur batteries, electrolyte exploration is vital for developing high-energy-density, safe, and reliable batteries. This study focused on cyclic THF and chain DME, representative solvents in ether electrolytes. MgCl2 , an ideal anionic salt, forms mono-nuclear (MgCl2 (DME)2 ), bi-nuclear ([Mg2 (μ-Cl)2 (DME)4 ]2+ ), and tri-nuclear ([Mg3 (μ-Cl)4 (DME)5 ]2+ ) complexes in DME. With increasing salt concentration, these complexes sequentially form. Under lower salt concentrations, THF and MgCl2 form mono-nuclear complexes ([MgCl2 (THF)4 ]) and continue to form bi-nuclear complexes ([Mg2 (μ-Cl)3 (THF)6 ]+ )...
March 20, 2024: RSC Advances
https://read.qxmd.com/read/38522271/selenium-increases-antimony-uptake-in-ramie-boehmeria-nivea-l-by-enhancing-the-physiological-antioxidative-and-ionomic-mechanisms
#39
JOURNAL ARTICLE
Yi Lu, Fangyuan Peng, Yingyang Wang, Zhaoguang Yang, Haipu Li
Ramie (Boehmeria nivea L.) is a promising phytoremediation candidate due to its high tolerance and enrichment capacity for antimony (Sb). However, challenges arise as Sb accumulated mainly in roots, complicating soil extraction. Under severe Sb contamination, the growth of ramie may be inhibited. Strategies are needed to enhance Sb accumulation in ramie's aboveground parts and improve tolerance to Sb stress. Considering the beneficial effects of selenium (Se) on plant growth and enhancing resistance to abiotic stresses, this study aimed to investigate the potential use of Se in enhancing Sb uptake by ramie...
March 23, 2024: Journal of Environmental Management
https://read.qxmd.com/read/38522190/a-facile-electrochemical-immunosensor-based-on-edta-pb-2-complexation-reaction
#40
JOURNAL ARTICLE
Shuli Zhang, Ze Zhang, Qichen Xiong, Jiaqing Wang, Hongliang Han, Zhanfang Ma
The sensitivity of electrochemical (EC) sensors has been improved through the development of multiple approaches. However, the majority of EC sensors were limited in their practical application by high costs or tedious procedures. Herein, based on ethylenediaminetetraacetic acid (EDTA)-Pb2+ complexation reaction, a facile and affordable immunosensor was designed. Pb2+ -magnesium silicate hydrate was served as the sensing substrate. The immunorecognition process was carried out in the Eppendorf tube, and antibody-functionalized Pb2+ -polydopamine was utilized as immunoprobe...
March 19, 2024: Talanta
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