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https://www.readbyqxmd.com/read/29667669/structural-characterization-and-antitumor-activity-of-a-novel-se-polysaccharide-from-selenium-enriched-cordyceps-gunnii
#1
Huiqing Sun, Zhenyuan Zhu, Yali Tang, Yuanyuan Ren, Qiaoying Song, Yun Tang, Yongmin Zhang
Selenium (Se) has been recognized as an essential element. Animals and humans absorb and retain more organic Se than inorganic Se. Bio-transformation is a major approach to transform inorganic Se to organic Se. Cordyceps gunnii (C. gunnii), well known as a Chinese edible and medicinal fungus, has a variety of biological functions. C. gunnii and selenium were combined through liquid-fermentation to obtain selenium-enriched C. gunnii. A novel Se-polysaccharide (SeCPS-II) was extracted from selenium-enriched C...
April 18, 2018: Food & Function
https://www.readbyqxmd.com/read/29667053/effect-of-different-bulking-agents-on-water-variation-and-thermal-balance-and-their-respective-contribution-to-bio-generated-heat-during-long-term-storage-sludge-biodrying-process
#2
Tiantian Liu, Chongwei Cui, Junguo He, Jian Tang
Biodrying was first used for the post-treatment of long-term storage sludge with vinasse as bulking agents. The effect of different bulking agents on water and heat variation and their respective contributions to bio-generated heat during storage sludge biodrying were investigated. Three different bulking agents (beer lees and distillers grains, with conventional straw used for comparison) were mixed with storage sludge for biodrying for an 18-day period. The results revealed the treatment with beer lees as bulking agent achieved the best performance with the highest water removal capacity (658 g kg-1 initial water)...
April 17, 2018: Environmental Science and Pollution Research International
https://www.readbyqxmd.com/read/29665728/influence-of-solvent-on-the-yield-and-chemical-composition-of-liquid-products-of-hydrothermal-liquefaction-of-arthrospira-platensis-as-revealed-by-fourier-transform-ion-cyclotron-resonance-mass-spectrometry
#3
Mikhail S Vlaskin, Anatoly V Grigorenko, Yury I Kostyukevich, Evgeny N Nikolaev, Gleb N Vladimirov, Nadezhda I Chernova, Sophia V Kiseleva, Oleg S Popel, Andrey Z Zhuk
Yields of liquid products (bio-oil and residual organics in aqueous solution) of hydrothermal liquefaction (at 300℃ and 60 min) of own cultivated Arthrospira platensis using different solvents have been determined. Nonpolar hexane, moderately polar dichloromethane, and relatively more polar acetonitrile have been used. High-resolution mass spectrometry based on linear quadrupole ion trap and Fourier transform mass spectrometer (LTQ FT) has been used for liquid sample characterization. Concentration of bio-oil in a unit of solvent volume after solvent extraction took the following arrangement: acetonitrile > dichloromethane > hexane...
January 1, 2018: European Journal of Mass Spectrometry
https://www.readbyqxmd.com/read/29662844/mineral-elements-bio-accessibility-and-antioxidant-indices-of-blanched-basella-rubra-at-different-phases-of-in-vitro-gastrointestinal-digestion
#4
Sule Ola Salawu, Bukola Eugenia Olukemi, Ikuosho Charity Asikhia, Akintunde Afolabi Akindahunsi
The present investigation was designed to evaluate the mineral element bio-accessibility and antioxidant indices of blanched Basella rubra at different phases of simulated in vitro digestion (oral, gastric, and intestinal). The phenolic composition of processed vegetable was determined using high-performance liquid chromatography (HPLC)-diode-array detection method. Mineral composition, total phenolic content (TPC), total flavonoid content (TFC), ferric reducing antioxidant power (FRAP), and total antioxidant activity (TAA) of the in vitro digested blanched and raw vegetable were also determined...
March 2018: Preventive Nutrition and Food Science
https://www.readbyqxmd.com/read/29661536/thioether-bridged-arylalkyl-linked-n-phenylpyrazole-derivatives-design-synthesis-insecticidal-activities-structure-activity-relationship-and-molecular-modeling-studies
#5
Chengcheng Fei, Yanfei Chen, Zhiyan Jiang, Dingxin Jiang
Owing to thioether diverse physicochemical properties by non-covalent interactions with bio-macromolecules, thioether derivatives containing heterocyclic moiety are known for their interesting insecticidal bioactivities and attracting considerable attention as neuroactive insecticides. Here we synthesis a series of novel thioether bridged N-phenylpyrazole derivatives incorporating various (hetero)aromatic substituents into 4-position of the pyrazole ring. Structure-activity relationship (SAR) studies resulted in compounds 6d and 7d with the most potent insecticidal activity among the series containing various substituted benzene substituents (LC50  = 13...
April 12, 2018: Bioorganic & Medicinal Chemistry Letters
https://www.readbyqxmd.com/read/29661305/bio-inspired-hydrophobic-modification-of-cellulose-nanocrystals-with-castor-oil
#6
Qianqian Shang, Chengguo Liu, Yun Hu, Puyou Jia, Lihong Hu, Yonghong Zhou
This work presents an efficient and environmentally friendly approach to generate hydrophobic cellulose nanocrystals (CNC) using thiol-containing castor oil (CO-SH) as a renewable hydrophobe with the assist of bio-inspired dopamine at room temperature. The modification process included the formation of the polydopamine (PDA) buffer layer on CNC surfaces and the Michael addition reaction between the catechol moieties of PDA coating and thiol groups of CO-SH. The morphology, crystalline structure, surface chemistry, thermal stability and hydrophobicity of the modified CNC were charactered by TEM, XRD, FT-IR, solid-state 13 C NMR, XPS, TGA and contact angle analysis...
July 1, 2018: Carbohydrate Polymers
https://www.readbyqxmd.com/read/29660860/managing-india-s-small-landholder-farms-for-food-security-and-achieving-the-4-per-thousand-target
#7
Arun Jyoti Nath, Rattan Lal, Gudeta Weldesemayat Sileshi, Ashesh Kumar Das
The "4 per Thousand" initiative was launched at the 21st Conference of Parties (COP21) in December 2015 to address global climate change through the aspirational goal of increasing soil organic carbon (SOC) stock of the world to 40-cm depth by an average annual rate of 4%. Small landholders (SLHs), often faced with difficult bio-physical and socio-economic conditions, are the principal managers of soil in India. There are 117 million SLHs representing 85% of the total operational holdings, cultivating over 72 million ha of land, and meeting 50-60% of India's food requirement...
April 11, 2018: Science of the Total Environment
https://www.readbyqxmd.com/read/29660264/selective-fragmentation-of-biore%C3%AF-nery-corncob-lignin-into-p-hydroxycinnamic-esters-with-a-supported-znmoo4-catalyst
#8
Shuizhong Wang, Wa Gao, Helong Li, Ling-Ping Xiao, Run-Cang Sun, Guoyong Song
Lignin is the largest renewable resource of bio-aromatics, and catalytic fragmentation of lignin into phenolic monomers is increasingly recognized as an important starting point for lignin valorization. Herein, we reported zinc molybdate (ZnMoO4) supported on MCM-41 can catalyze fragmentation of biorefinery technical lignin, enzymatic mild acidolysis lignin and native lignin derived from corncob, to give lignin oily products containing 15 to 37.8 wt% phenolic monomers, in which the high selectivities towards methyl coumarate 1 and methyl ferulate 2 were obtained (up to 78%)...
April 16, 2018: ChemSusChem
https://www.readbyqxmd.com/read/29657941/investigation-of-frequency-distribution-of-breast-imaging-reporting-and-data-system-birads-classification-and-epidemiological-factors-related-to-breast-cancer-in-iran-a-7-year-study-2010-2016
#9
Mehri Sirous, Parisa Sotoodeh Shahnani, Amirmasoud Sirous
Background: The first cause of women mortality due to cancer is breast cancer. Mammography plays a central part in early detection of breast cancers. The screening methods can play a major role to reduce the morbidity and mortality rate due to this malignancy. We sought the basic data in this study on our population because knowing about the baseline data is apt and vital. Materials and Methods: In this study, data were collected from a questionnaire, contained baseline bio data information, and mammographic imaging of the patients came during 7 years...
2018: Advanced Biomedical Research
https://www.readbyqxmd.com/read/29656164/lignolytic-mushroom-lenzites-elegans-wdp2-laccase-production-characterization-and-bioremediation-of-synthetic-dyes
#10
Raj Kumar Pandey, Salil Tewari, Lakshmi Tewari
A mycoremedial study was undertaken for decolourization of synthetic dyes using wood rot fungal culture Lenzites elegans WDP2. The culture was isolated from decaying wood as fruiting body, and identified on the basis of 5.8S ITS rRNA gene sequence analysis. Qualitative plate screening of culture showed extracellular laccase and lignin peroxidase production, while only laccase enzyme was produced in higher amount (156.793 Uml-1 ) in minimal salt broth medium containing glucose and veratryl alcohol. Laccase activity was increased up to 189...
April 12, 2018: Ecotoxicology and Environmental Safety
https://www.readbyqxmd.com/read/29644848/preparation-of-n-graphdiyne-nanosheets-at-liquid-liquid-interface-for-photocatalytic-nadh-regeneration
#11
Qingyan Pan, Hui Liu, Yingjie Zhao, Siqi Chen, Bo Xue, Xiao-Nan Kan, Xiaowen Huang, Jian Liu, Zhibo Li
Two-dimensional (2D) N-graphdiyne (N-GDY) nanosheets containing different number of N were synthesized by polymerization of triazine, pyrazine and pyridine based monomers at liquid/liquid interface. The configurations and nanostructures of N-GDY were well characterized. The wettability changed to more hydrophilic as the N contents increased. The collected N-GDY was further employed as metal-free photocatalyst for NADH regeneration. The catalytic performance was related with the N content in the graphdiyne. The N3-GDY demonstrated the best activity...
April 12, 2018: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/29629101/cooperative-loading-of-multisite-receptors-with-lanthanide-containers-an-approach-for-organized-luminescent-metallopolymers
#12
Lucille Babel, Laure Guénée, Céline Besnard, Svetlana V Eliseeva, Stéphane Petoud, Claude Piguet
Metal-containing (bio)organic polymers are materials of continuously increasing importance for applications in energy storage and conversion, drug delivery, shape-memory items, supported catalysts, organic conductors and smart photonic devices. The embodiment of luminescent components provides a revolution in lighting and signaling with the ever-increasing development of polymeric light-emitting devices. Despite the unique properties expected from the introduction of optically and magnetically active lanthanides into organic polymers, the deficient control of the metal loading currently limits their design to empirical and poorly reproducible materials...
January 14, 2018: Chemical Science
https://www.readbyqxmd.com/read/29628077/characteristics-of-microbial-community-involved-in-early-biofilms-formation-under-the-influence-of-wastewater-treatment-plant-effluent
#13
Yuke Peng, Jie Li, Junling Lu, Lin Xiao, Liuyan Yang
Effluents from wastewater treatment plants (WWTPs) containing microorganisms and residual nutrients can influence the biofilm formation. Although the process and mechanism of bacterial biofilm formation have been well characterized, little is known about the characteristics and interaction of bacteria, archaea and eukaryotes in the early colonization, especially under the influence of WWTP effluent. The aim of this study was to characterize the important bacterial, archaeal and eukaryotic species in the early stage of biofilm formation downstream of the WWTP outlet...
April 2018: Journal of Environmental Sciences (China)
https://www.readbyqxmd.com/read/29622204/realistic-risk-assessment-of-arsenic-in-rice
#14
Randa A Althobiti, Nausheen W Sadiq, Diane Beauchemin
Over 3 billion people share a diet consisting mainly of rice, which may contain significant amounts of arsenic. Because the toxicity of arsenic is dependent on its chemical form and that it may be in a form that is not bio-accessible (i.e. dissolved in the gastrointestinal tract) and can thus not become bio-available (i.e. end up in the blood stream, where it may exert its toxic effect), the bio-accessibility of arsenic was determined in thirteen different types of rice. The effects of washing and cooking were also studied...
August 15, 2018: Food Chemistry
https://www.readbyqxmd.com/read/29620109/using-porphyrin-amino-acid-pairs-to-model-the-electrochemistry-of-heme-proteins-experimental-and-theoretical-investigations
#15
Rudra N Samajdar, Dhivya Manogaran, S Yashonath, Aninda J Bhattacharyya
Quasi reversibility in electrochemical cycling between different oxidation states of iron is an often seen characteristic of iron containing heme proteins that bind dioxygen. Surprisingly, the system becomes fully reversible in the bare iron-porphyrin complex: hemin. This leads to the speculation that the polypeptide bulk (globin) around the iron-porphyrin active site in these heme proteins is probably responsible for the electrochemical quasi reversibility. To understand the effect of such polypeptide bulk on iron-porphyrin, we study the interaction of specific amino acids with the hemin center in solution...
April 5, 2018: Physical Chemistry Chemical Physics: PCCP
https://www.readbyqxmd.com/read/29617117/sustainable-hydrogels-based-on-lignin-methacrylate-copolymers-with-enhanced-water-retention-and-tunable-material-properties
#16
Kalavathy Rajan, Jeffrey K Mann, Eldon English, David P Harper, Danielle Julie Carrier, Timothy G Rials, Nicole Labbé, Stephen C Chmely
Synthesizing lignin-based copolymers would valorize a major co-product stream from pulp and paper mills and bio-refineries, as well as reduce the dependence on petrochemical-based consumer goods. In this study, we used organosolv lignin isolated from hybrid poplar (Populus trichocarpa ✕ P. deltoides) to generate lignin-containing methacrylate hydrogels. The copolymer hydrogels were synthesized by first grafting 2-hydroxyethyl methacrylate (HEMA) onto lignin (OSLH) via esterification, and then by free radical polymerization of OSLH with excess HEMA...
April 4, 2018: Biomacromolecules
https://www.readbyqxmd.com/read/29616363/a-comparative-in-vivo-scrutiny-of-biosynthesized-copper-and-zinc-oxide-nanoparticles-by-intraperitoneal-and-intravenous-administration-routes-in-rats
#17
Ashajyothi C, Harish K Handral, Chandrakanth Kelmani R
During the present time, anti-microbial features of copper (Cu) and zinc oxide (ZnO) nanoparticles (NPs) are extensively used to combat the growth of pathogenic microbes. CuNPs and ZnONPs are recurrently used in cosmetics, medicine and food additives, and their potential for toxic impacts on human and ecosystem is of high concern. In this study, the fate and toxicity of 16- to 96-nm-ranged biosynthesized copper (Bio-CuNPs) and zinc oxide (Bio-ZnONPs) was assessed in male Wistar rats. In vivo exposures of the two nanoparticles are achieved through two different administration routes namely, intraperitoneal (i/p) and intravenous (i/v) injections...
April 3, 2018: Nanoscale Research Letters
https://www.readbyqxmd.com/read/29616216/microstructure-evolution-in-mg-zn-zr-gd-biodegradable-alloy-the-decisive-bridge-between-extrusion-temperature-and-performance
#18
Huai Yao, Jiu-Ba Wen, Yi Xiong, Yan Lu, Marko Huttula
Being a biocompatible metal with similar mechanical properties as bones, magnesium bears both biodegradability suitable for bone substitution and chemical reactivity detrimental in bio-ambiences. To benefit its biomaterial applications, we developed Mg-2.0Zn-0.5Zr-3.0Gd (wt%) alloy through hot extrusion and tailored its biodegradability by just varying the extrusion temperatures during alloy preparations. The as-cast alloy is composed of the α-Mg matrix, a network of the fish-bone shaped and ellipsoidal (Mg, Zn)3 Gd phase, and a lamellar long period stacking ordered phase...
2018: Frontiers in Chemistry
https://www.readbyqxmd.com/read/29616183/sustainability-assessment-of-biogas-production-from-buffalo-grass-and-dung-biogas-purification-and-bio-fertilizer
#19
Ajcharapa Chuanchai, Rameshprabu Ramaraj
Biomass from wetland aquatic grass and buffalo grass can be exploited for biogas production, because this substrate is plenteous and does not compete with food production. In this study, the grass substrate was physically pretreated by boiling with different retention time to increase its biodegradability and was examined in batch mode. Boiling pretreatment suggested that 100 °C with 2 h retention time was the best condition. The results showed that the optimum grass concentration in the 1:1 ratio of co-digestion mixture with manure produced the highest methane yield...
March 2018: 3 Biotech
https://www.readbyqxmd.com/read/29611541/nanocurcumin-pyrroloquinoline-formulation-prevents-hypertrophy-induced-pathological-damage-by-relieving-mitochondrial-stress-in-cardiomyocytes-under-hypoxic-conditions
#20
Sarita Nehra, Varun Bhardwaj, Anju Bansal, Pronobesh Chattopadhyay, Deepika Saraswat
This study investigates the therapeutic effect of a nanocurcumin formulation (NCF) containing nanocurcumin (NC) and pyrroloquinoline quinone (PQQ) on ameliorating hypoxia-induced stress in hypertrophied primary human ventricular cardiomyocytes (HVCM) under hypoxic conditions, as validated in a Sprague-Dawley rat model of chronic hypobaric hypoxia (cHH)-induced right ventricular hypertrophy (RVH). Based on our previous findings, here, we analyzed the improvement in the protective efficacy of NCF against mitochondrial damage...
December 1, 2017: Experimental & Molecular Medicine
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