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https://www.readbyqxmd.com/read/28107442/comparison-of-various-indices-of-energy-metabolism-in-recumbent-and-healthy-dairy-cows
#1
Hugues Guyot, Johann Detilleux, Pascal Lebreton, Catherine Garnier, Marie Bonvoisin, Frederic Rollin, Charlotte Sandersen
BACKGROUND: Downer cow syndrome (DCS) is often diagnosed in dairy cattle during the early post-partum period. The etiology of this condition is not completely understood, as it can be related to the energetic or electrolyte metabolism, as well as to infectious diseases or to trauma. HYPOTHESIS/OBJECTIVES: The aim of this study is to compare energy metabolism and insulin sensitivity indices and various biochemical parameters between recumbent and healthy dairy cows...
2017: PloS One
https://www.readbyqxmd.com/read/28106384/highly-atroposelective-synthesis-of-arylpyrroles-by-catalytic-asymmetric-paal-knorr-reaction
#2
Lei Zhang, Jian Zhang, Ji Ma, Dao-Juan Cheng, Bin Tan
A general and efficient method for accessing enantiomerically pure arylpyrroles by utilizing the catalytic asymmetric Paal-Knorr reaction has been developed for the first time. A wide range of axially chiral arylpyrroles were obtained in high yields with good to excellent enantioselectivities. The key to success is the use of the combined-acid catalytic system involving a Lewis acid and a chiral phosphoric acid for achieving effective enantiocontrol. Noteworthy is that an unexpected solvent-dependent inversion of the enantioselectivity was observed in the above-mentioned asymmetric reaction...
January 20, 2017: Journal of the American Chemical Society
https://www.readbyqxmd.com/read/28106371/enhancement-of-electrode-stability-using-platinum-cobalt-nanocrystals-on-a-novel-composite-sictic-support
#3
María Millán, Hector Zamora, Manuel Andrés Rodrigo, Justo Lobato
PtCo alloy catalysts for high temperature PEMFCs (Protonic Exchange Membrane Fuel Cells) were synthesized on a novel non-carbonaceous support (SiCTiC) using the impregnation method with NaBH4 as the reducing agent at different synthesis temperatures to evaluate the effect of this variable on their physicochemical and electrochemical properties. The catalysts were characterized by inductively coupled plasma optical emission spectrometry (ICP-OES), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX), X-ray diffraction (XRD), transmission electron microscope-energy dispersive X-ray (TEM) and temperature programmed reduction (TPR)...
January 20, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28106201/efficient-energy-transfer-and-luminescence-properties-of-ca3y-gao-3-bo3-4-tb-3-eu-3-as-a-green-to-red-colour-tunable-phosphor-under-near-uv-excitation
#4
Wasim Ullah Khan, Junhao Li, Xiaohui Li, Qili Wu, Jing Yan, Yiqin Xu, Feiyan Xie, Jianxin Shi, Mingmei Wu
A series of Ca3Y(GaO)3(BO3)4:Tb(3+),Eu(3+) phosphors were prepared by a high-temperature solid-state reaction. Their phase structures were confirmed by powder X-ray diffraction and the element distribution was measured using transmission electron microscopy elemental mapping. The photoluminescence emission and excitation spectra and fluorescence lifetime were studied and discussed in detail. The results revealed that Eu(3+) ions can be efficiently sensitized by Tb(3+) ions under near-UV excitation. In addition, the energy transfer efficiency can be controlled by adjusting the ratio of Eu(3+) and Tb(3+) to realize colour tunable emission from green to red...
January 20, 2017: Dalton Transactions: An International Journal of Inorganic Chemistry
https://www.readbyqxmd.com/read/28099127/prevalence-risk-factors-and-consequences-of-overweight-and-obesity-among-schoolchildren-a-cross-sectional-study-in-kashmir-india
#5
Mohd Ashraf Ganie, Gulzar Ahmad Bhat, Ishfaq Ahmad Wani, Aafia Rashid, Showkat Ali Zargar, Bashir Ahmad Charoo, Zaffar Amin Shah, Syed Mudassar
BACKGROUND: Obesity among children and adolescents is a growing public health problem. The objective of this study was to evaluate the prevalence, risk factors and metabolic consequences of obesity among schoolchildren from Kashmir, India. METHODS: The study subjects (n=2024) included 870 boys and 1154 girls, aged between 6 and 18 years. Data were collected by interviewer-administered questionnaires. Information was obtained about different lifestyles, anthropometric parameters and dietary habits...
January 18, 2017: Journal of Pediatric Endocrinology & Metabolism: JPEM
https://www.readbyqxmd.com/read/28098997/two-step-design-of-a-single-doped-white-phosphor-with-high-color-rendering
#6
Romain Gautier, Xueyan Li, Zhiguo Xia, Florian Massuyeau
A strategy to design step by step an inorganic single-doped white phosphor is demonstrated. The method consists in tuning different contributions of the emission by successively controlling the chemical compositions of the solid solution or nanosegregated host matrix and the oxidation states of the single dopant. We use this approach to design a white phosphor Na4CaMgSc4Si10O30:Eu with excellent color rendering (CRI > 90) which is similar to common mixed-phosphor light sources but for a single-phase. We show that this methodology can also be extended to other phosphors for use in diverse applications such as biomedicine or telecommunications...
January 18, 2017: Journal of the American Chemical Society
https://www.readbyqxmd.com/read/28098986/investigation-of-the-energy-transfer-mechanism-in-ho-3-and-yb-3-codoped-lu2o3-phosphor-with-efficient-near-infrared-downconversion
#7
Guotao Xiang, Yan Ma, Xianju Zhou, Sha Jiang, Li Li, Xiaobing Luo, Zhendong Hao, Xia Zhang, Guo-Hui Pan, Yongshi Luo, Jiahua Zhang
A high-temperature solid-state method was used to synthesize the Ho(3+)- and Yb(3+)-codoped cubic Lu2O3 powders. The crystal structures of the as-prepared powders were characterized by X-ray diffraction. The energy-transfer (ET) phenomenon between Ho(3+) ions and Yb(3+) ions was verified by the steady-state spectra including visible and near-infrared (NIR) regions. Beyond that, the decay curves were also measured to certify the existence of the ET process. The downconversion phenomena appeared when the samples were excited by 446 nm wavelength corresponding to the transition of Ho(3+): (5)I8→(5)G6/(5)F1...
January 18, 2017: Inorganic Chemistry
https://www.readbyqxmd.com/read/28098969/exciplex-forming-co-host-based-red-phosphorescent-organic-light-emitting-diodes-with-long-operational-stability-and-high-efficiency
#8
Jeong-Hwan Lee, Hyun Shin, Jae-Min Kim, Kwon-Hyeon Kim, Jang-Joo Kim
The use of exciplex forming co-hosts and phosphors incredibly boosts the efficiency of organic light-emitting diodes (OLEDs) by providing a barrier-free charge injection into an emitting layer and a broad recombination zone. However, most of the efficient OLEDs based on the exciplex forming co-hosts has suffered from the short operational lifetime. Here, we demonstrated phosphorescent OLEDs (PhOLEDs) having both high efficiency and long lifetime by using a new exciplex forming co-host composed of N,N'-diphenyl-N,N'-bis(1,1'-biphenyl)-4,4'-diamine (NPB) and (1,3,5-triazine-2,4,6-triyl)tris(benzene-3,1-diyl))tris(diphenylphosphine oxide) (PO-T2T)...
January 18, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28098279/eu-3-doped-y3-xndxal3o12-garnet-synthesis-and-structural-investigation
#9
L Pavasaryte, A Katelnikovas, V Klimavicius, V Balevicius, A Krajnc, G Mali, J Plavec, A Kareiva
Nd(3+)-Doped yttrium aluminium garnet and Eu(3+)-Nd(3+)-co-doped yttrium aluminium garnet were synthesized using an environmentally friendly sol-gel method at low temperatures. The results of X-ray diffraction (XRD) analysis of the powders sintered at 1000 °C showed the purity and formation of monophasic compounds. The phase composition and purity confirmation of the samples were also characterized via FTIR spectroscopy. Desirable microstructural features and particle size of phosphorous materials of the polycrystalline samples were studied via scanning electron microscopy (SEM)...
January 18, 2017: Physical Chemistry Chemical Physics: PCCP
https://www.readbyqxmd.com/read/28098259/wafer-scale-thermodynamically-stable-gan-nanorods-via-two-step-self-limiting-epitaxy-for-optoelectronic-applications
#10
Hyun Kum, Han-Kyu Seong, Wantae Lim, Daemyung Chun, Young-Il Kim, Youngsoo Park, Geonwook Yoo
We present a method of epitaxially growing thermodynamically stable gallium nitride (GaN) nanorods via metal-organic chemical vapor deposition (MOCVD) by invoking a two-step self-limited growth (TSSLG) mechanism. This allows for growth of nanorods with excellent geometrical uniformity with no visible extended defects over a 100 mm sapphire (Al2O3) wafer. An ex-situ study of the growth morphology as a function of growth time for the two self-limiting steps elucidate the growth dynamics, which show that formation of an Ehrlich-Schwoebel barrier and preferential growth in the c-plane direction governs the growth process...
January 18, 2017: Scientific Reports
https://www.readbyqxmd.com/read/28098100/impact-of-residual-renal-function-on-clinical-outcome-and-quality-of-life-in-patients-on-peritoneal-dialysis
#11
Manns Manohar John, Amit Gupta, Raj K Sharma, Anupama Kaul
We studied the impact of residual renal function (RRF) on clinical outcome and quality of life in 61 patients on peritoneal dialysis (PD). They were assigned to two groups, at the time of initiation of PD, based on their estimated glomerular filtration rate (eGFR). The high RRF group had eGFR ≥5 mL/min/1.73 m[2] and the low RRF group hade GFR <5 mL/min/1.73 m[2]. All patients were followed up at regular intervals for clinical and biochemical variables. Baselines characteristics including age, sex, body mass index and cause of the kidney disease were similar in both groups...
January 2017: Saudi Journal of Kidney Diseases and Transplantation
https://www.readbyqxmd.com/read/28097508/preparation-and-evaluation-of-biopolymeric-nanoparticles-as-drug-delivery-system-in-effective-treatment-of-rheumatoid-arthritis
#12
Vijay Kumar, Ankita Leekha, Aakriti Tyagi, Ankur Kaul, Anil Kumar Mishra, Anita Kamra Verma
PURPOSE: The study purposes to evaluate nanocrystalline biopolymeric nanoparticles encapsulating methotrexate and dexamethasone with high biocompatibility, enhanced therapeutic efficacy and reduced toxicity. METHODS: Chitosan nanoparticles were prepared by ionic gelation, and Methotrexate (MTX) and Dexamethasone (DEX) were loaded during the preparation and screened for their in vitro efficacy in HEK and RAW264.7 cells, ex vivo and in vivo efficacy. RESULTS: FTIR confirmed the involvement of phosphoric group of sTPP with amine groups of chitosan and also role of hydrogen bonding involved in the preparation of MTXCHNP and DEXCHNP...
January 17, 2017: Pharmaceutical Research
https://www.readbyqxmd.com/read/28096167/chemical-fingerprint-of-dachaihu-granule-and-its-chemical-correlation-between-raw-herbs
#13
Chunqin Mao, Yaping Zhou, De Ji, Xuanzhong Tan, Yi Tao, Wenyi Zang, Tulin Lu
To develop a method to overall evaluate the quality of Dachaihu Granule (DCHG), high-performance liquid chromatography coupled with diode array detector was used to establish chemical fingerprint of DCHG. The correlation between the formula and its raw herbs was also evaluated. According to the retention time of standard components, chemical fingerprint of DCHG was developed and a total of 21 constituents were characterized. The separation was performed on a Kromasil C18 column (250 mm × 4.6 mm i.d. with 5...
January 17, 2017: Journal of Chromatographic Science
https://www.readbyqxmd.com/read/28095050/the-expressions-of-klotho-family-genes-in-human-ocular-tissues-and-in-anterior-lens-capsules-of-age-related-cataract
#14
Yu Zhang, Liya Wang, Zhong Wu, Xiaolin Yu, Xiaofeng Du, Xiaohua Li
PURPOSE: Klotho genes are expressed in limited tissues and have been found to be a pathogenic factor of age-related diseases in mammals, but their expressions and functions in human eyes are yet to be defined. This study was performed to investigate the expression of Klotho family genes in human ocular tissues and anterior lens capsules of age-related cataract. METHODS: Individual tissues were isolated from human eyeballs collected from Henan Eye Bank. Human anterior lens capsules were collected from cortical cataract patients during phacoemulsification with the informed consent...
January 17, 2017: Current Eye Research
https://www.readbyqxmd.com/read/28094363/photoassist-phosphorylated-tio2-as-a-catalyst-for-direct-formation-of-5-hydroxymethyl-furfural-from-glucose
#15
Masashi Hattori, Keigo Kamata, Michikazu Hara
Photo-assisted phosphorylation of an anatase TiO2 catalyst was examined to improve its catalytic performance for the direct production of 5-(hydroxymethyl)furfural (HMF), a versatile chemical platform, from glucose. In phosphorylation based on simple esterification between phosphoric acid and surface OH groups on anatase TiO2 with water-tolerant Lewis acid sites, the density of phosphates immobilized on TiO2 is limited to 2 phosphates nm(-2), which limits selective HMF production. Phosphorylation of the TiO2 surface under fluorescent light irradiation increases the surface phosphate density to 50%, which is higher than the conventional limit, thus preventing the adsorption of hydrophilic glucose molecules on TiO2 and resulting in a more selective HMF production over photoassist-phosphorylated TiO2...
January 17, 2017: Physical Chemistry Chemical Physics: PCCP
https://www.readbyqxmd.com/read/28094246/development-of-sr-incorporated-biphasic-calcium-phosphate-bone-cement
#16
Hui Zhu, Dagang Guo, Wenli Qi, Kewei Xu
To follow the design strategy of traditional biphasic calcium phosphate (BCP) ceramic, in the present study, strontium-doped biphasic calcium phosphate bone cement (Sr-BCPC) composites comprising Sr-β-tricalcium phosphate (TCP)/Sr-hydroxyapatite (HAP) had been prepared for the first time using Sr x -β-TCP/tetracalcium phosphate (TTCP) as a cement powder and diluted phosphoric acid as a cement liquid. The phase composition, setting time, compressive strength, washout resistance, in vitro degradation rate, microstructure evolutions, hydration dynamics and cytotoxicity of Sr-BCPC at various Sr contents were intensively investigated...
January 17, 2017: Biomedical Materials
https://www.readbyqxmd.com/read/28092769/spatiotemporal-change-of-phosphorous-speciation-and-concentration-in-stormwater-in-the-st-lucie-estuary-watershed-south-florida
#17
Liguang Li, Zhenli He, Zhigang Li, Suli Li, Yongshan Wan, Peter J Stoffella
Phosphorous (P) concentration in stormwater runoff varies at different spatial and temporal scales. Excessive P loading from agriculture system into the St. Lucie Estuary (SLE) contributed to water quality deterioration in southern Indian River Lagoon. This study examines the spatial and temporal shifts of different P forms in runoff and storm water under different land use, water management, and rainfall conditions. Storm water samplings were conducted monthly between April 2013 and December 2014 in typical farmland and along the waterway (Canal C-24) that connects lands to the SLE...
January 6, 2017: Chemosphere
https://www.readbyqxmd.com/read/28092703/enantioselective-three-component-amination-of-enecarbamates-enables-the-synthesis-of-structurally-complex-small-molecules
#18
Audrey Dumoulin, Guillaume Bernadat, Géraldine Masson
The control of asymmetric synthesis tools represents a major challenge, especially when it comes to the synthesis of bioactive molecules. In this context, the asymmetric synthesis of 1,2-diamines through amination of enecarbamates has appeared to us as a highly efficient and tunable approach. Indeed, reactivity of the latter species could be exploited to realize a double functionalization via an electrophilic amination followed by nucleophilic trapping. Herein, we describe a chiral phosphoric acid-catalyzed electrophilic amination of enecarbamates with dibenzylazodicarboxylate and oxygenated or thiol-containing nucleophiles affording stable precursors of α-hydrazinoimines in high yields and with almost complete enantioselectivities (up to >99%)...
January 16, 2017: Journal of Organic Chemistry
https://www.readbyqxmd.com/read/28092632/the-tilt-dependent-potential-of-mean-force-of-a-pair-of-dna-oligomers-from-all-atom-molecular-dynamics-simulations
#19
Ruggero Cortini, Xiaolin Cheng, Jeremy C Smith
Electrostatic interactions between DNA molecules have been extensively studied experimentally and theoretically, but several aspects (e.g. its role in determining the pitch of the cholesteric DNA phase) still remain unclear. Here, we performed large-scale all-atom molecular dynamics simulations in explicit water and 150 mM sodium chloride, to reconstruct the potential of mean force (PMF) of two DNA oligomers 24 base pairs long as a function of their interaxial angle and intermolecular distance. We find that the potential of mean force is dominated by total DNA charge, and not by the helical geometry of its charged groups...
January 16, 2017: Journal of Physics. Condensed Matter: An Institute of Physics Journal
https://www.readbyqxmd.com/read/28088539/the-dna-damage-response-of-c-elegans-affected-by-gravity-sensing-and-radiosensitivity-during-the-shenzhou-8-spaceflight
#20
Ying Gao, Dan Xu, Lei Zhao, Yeqing Sun
Space radiation and microgravity are recognized as primary and inevitable risk factors for humans traveling in space, but the reports regarding their synergistic effects remain inconclusive and vary across studies due to differences in the environmental conditions and intrinsic biological sensitivity. Thus, we studied the synergistic effects on transcriptional changes in the global genome and DNA damage response (DDR) by using dys-1 mutant and ced-1 mutant of C. elegans, which respectively presented microgravity-insensitivity and radiosensitivity when exposure to spaceflight condition (SF) and space radiation (SR)...
January 7, 2017: Mutation Research
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