Shefali Vaidya, Saly Hawila, Fan Zeyu, Tuhin Khan, Alexandra Fateeva, François Toche, Rodica Chiriac, Anne Bonhommé, Gilles Ledoux, Sébastien Lebègue, Jeongmin Park, Won June Kim, Juejing Liu, Xiaofeng Guo, Adel Mesbah, Satoshi Horike, Aude Demessence
Gold-sulfur interaction has vital importance in nanotechnologies and material chemistry to design functional nanoparticles, self-assembled monolayers, or molecular complexes. In this paper, a mixture of only two basic precursors, such as the chloroauric acid (HAu(III)Cl4 ) and a thiol molecule ( p -fluorothiophenol ( p -HSPhF)), are used for the synthesis of gold(I)-thiolate coordination polymers. Under different conditions of synthesis and external stimuli, five different functional materials with different states of [Au(I)( p -SPhF)] n can be afforded...
April 23, 2024: ACS Applied Materials & Interfaces