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https://www.readbyqxmd.com/read/28541270/negative-poisson-s-ratio-in-1t-type-crystalline-two-dimensional-transition-metal-dichalcogenides
#1
Liping Yu, Qimin Yan, Adrienn Ruzsinszky
Materials with a negative Poisson's ratio, also known as auxetic materials, exhibit unusual and counterintuitive mechanical behaviour-becoming fatter in cross-section when stretched. Such behaviour is mostly attributed to some special re-entrant or hinged geometric structures regardless of the chemical composition and electronic structure of a material. Here, using first-principles calculations, we report a class of auxetic single-layer two-dimensional materials, namely, the 1T-type monolayer crystals of groups 6-7 transition-metal dichalcogenides, MX2 (M=Mo, W, Tc, Re; X=S, Se, Te)...
May 25, 2017: Nature Communications
https://www.readbyqxmd.com/read/28537575/physiological-functions-of-programmed-dna-breaks-in-signal-induced-transcription
#2
REVIEW
Janusz Puc, Aneel K Aggarwal, Michael G Rosenfeld
The idea that signal-dependent transcription might involve the generation of transient DNA nicks or even breaks in the regulatory regions of genes, accompanied by activation of DNA damage repair pathways, would seem to be counterintuitive, as DNA damage is usually considered harmful to cellular integrity. However, recent studies have generated a substantial body of evidence that now argues that programmed DNA single- or double-strand breaks can, at least in specific cases, have a role in transcription regulation...
May 24, 2017: Nature Reviews. Molecular Cell Biology
https://www.readbyqxmd.com/read/28530796/what-do-laser-induced-transient-techniques-reveal-for-batteries-na-and-k-intercalation-from-aqueous-electrolytes-as-an-example
#3
Daniel Scieszka, Jeongsik Yun, Aliaksandr S Bandarenka
Technological advancement has been revolutionized by rechargeable batteries, without which the use of various modern devices would not be possible. Aqueous Na-ion batteries have lately garnered much attention, being rec-ognized as a promising alternative to the commonly used Li-ion batteries for the large-scale energy storage systems. However, further improvement and optimization of such systems require a more detailed understanding of intercalation mechanisms. In this work, we for the first time demonstrate implementation of the laser induced current transient (LICT) technique for in-situ characterization of battery systems and investigate the interface between Na2Ni[Fe(CN)6] model battery electrodes in contact with aqueous electrolytes...
May 22, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28529152/coevolution-of-patch-type-dependent-emigration-and-patch-type-dependent-immigration
#4
Helene C Weigang
The three phases of dispersal - emigration, transfer and immigration - are affecting each other and the former and latter decisions may depend on patch types. Despite the inevitable fact of the complexity of the dispersal process, patch-type dependencies of dispersal decisions modelled as emigration and immigration are usually missing in theoretical dispersal models. Here, I investigate the coevolution of patch-type dependent emigration and patch-type dependent immigration in an extended Hamilton-May model...
May 18, 2017: Journal of Theoretical Biology
https://www.readbyqxmd.com/read/28524676/matter-wave-tractor-beams
#5
Alexey A Gorlach, Maxim A Gorlach, Andrei V Lavrinenko, Andrey Novitsky
Optical and acoustic tractor beams are currently the focus of intense research due to their counterintuitive property of exerting a pulling force on small scattering objects. In this Letter we propose a matter-wave tractor beam and utilize the de Broglie waves of nonrelativistic matter particles in analogy to "classical" tractor beams. We reveal the presence of the quantum-mechanical pulling force for the variety of quantum mechanical potentials observing the resonant enhancement of the pulling effect under the conditions of the suppressed scattering known as the Ramsauer-Townsend effect...
May 5, 2017: Physical Review Letters
https://www.readbyqxmd.com/read/28508079/a-twofold-quantum-delayed-choice-experiment-in-a-superconducting-circuit
#6
Ke Liu, Yuan Xu, Weiting Wang, Shi-Biao Zheng, Tanay Roy, Suman Kundu, Madhavi Chand, Arpit Ranadive, Rajamani Vijay, Yipu Song, Luming Duan, Luyan Sun
Wave-particle complementarity lies at the heart of quantum mechanics. To illustrate this mysterious feature, Wheeler proposed the delayed-choice experiment, where a quantum system manifests the wave- or particle-like attribute, depending on the experimental arrangement, which is made after the system has entered the interferometer. In recent quantum delayed-choice experiments, these two complementary behaviors were simultaneously observed with a quantum interferometer in a superposition of being closed and open...
May 2017: Science Advances
https://www.readbyqxmd.com/read/28507227/when-two-wrongs-make-a-right-synchronized-neuronal-bursting-from-combined-electrical-and-inhibitory-coupling
#7
Reimbay Reimbayev, Kevin Daley, Igor Belykh
Synchronized cortical activities in the central nervous systems of mammals are crucial for sensory perception, coordination and locomotory function. The neuronal mechanisms that generate synchronous synaptic inputs in the neocortex are far from being fully understood. In this paper, we study the emergence of synchronization in networks of bursting neurons as a highly non-trivial, combined effect of electrical and inhibitory connections. We report a counterintuitive find that combined electrical and inhibitory coupling can synergistically induce robust synchronization in a range of parameters where electrical coupling alone promotes anti-phase spiking and inhibition induces anti-phase bursting...
June 28, 2017: Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences
https://www.readbyqxmd.com/read/28504530/framing-affects-scale-usage-for-judgments-of-learning-not-confidence-in-memory
#8
Benjamin D England, Francesca R Ortegren, Michael J Serra
Framing metacognitive judgments of learning (JOLs) in terms of the likelihood of forgetting rather than remembering consistently yields a counterintuitive outcome: The mean of participants' forget-framed JOLs is often higher (after reverse-scoring) than the mean of their remember-framed JOLs, suggesting greater confidence in memory. In the present experiments, we tested 2 competing explanations for this pattern of results. The optimistic-anchoring hypothesis suggests that forget-framed JOLs are associated with greater optimism about memory than are remember-framed JOLs, which leads to their greater magnitude...
May 15, 2017: Journal of Experimental Psychology. Learning, Memory, and Cognition
https://www.readbyqxmd.com/read/28503401/bio-inspired-micro-to-nanoporous-polymers-with-tunable-stiffness
#9
Julia Syurik, Ruth Schwaiger, Prerna Sudera, Stephan Weyand, Siegbert Johnsen, Gabriele Wiegand, Hendrik Hölscher
Background: Inspired by structural hierarchies and the related excellent mechanical properties of biological materials, we created a smoothly graded micro- to nanoporous structure from a thermoplastic polymer. Results: The viscoelastic properties for the different pore sizes were investigated in the glassy regime by dynamic flat-punch indentation. Interestingly, the storage modulus was observed to increase with increasing pore-area fraction. Conclusion: This outcome appears counterintuitive at first sight, but can be rationalized by an increase of the pore wall thickness as determined by our quantitative analysis of the pore structure...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28498712/fast-diffusion-of-long-guest-rods-in-a-lamellar-phase-of-short-host-particles
#10
Laura Alvarez, M Paul Lettinga, Eric Grelet
We investigate the dynamic behavior of long guest rodlike particles immersed in liquid crystalline phases formed by shorter host rods, tracking both guest and host particles by fluorescence microscopy. Counterintuitively, we evidence that long rods diffuse faster than short rods forming the one-dimensional ordered smectic-A phase. This results from the larger and noncommensurate size of the guest particles as compared to the wavelength of the energy landscape set by the lamellar stack of liquid slabs. The long guest particles are also shown to be still mobile in the crystalline smectic-B phase, as they generate their own voids in the adjacent layers...
April 28, 2017: Physical Review Letters
https://www.readbyqxmd.com/read/28493757/argumentation-and-the-diffusion-of-counter-intuitive-beliefs
#11
Nicolas Claidière, Emmanuel Trouche, Hugo Mercier
Research in cultural evolution has focused on the spread of intuitive or minimally counterintuitive beliefs. However, some very counterintuitive beliefs can also spread successfully, at least in some communities-scientific theories being the most prominent example. We suggest that argumentation could be an important factor in the spread of some very counterintuitive beliefs. A first experiment demonstrates that argumentation enables the spread of the counterintuitive answer to a reasoning problem in large discussion groups, whereas this spread is limited or absent when participants can show their answers to each other but cannot discuss...
May 11, 2017: Journal of Experimental Psychology. General
https://www.readbyqxmd.com/read/28493310/evolution-of-heterogeneous-mixed-siliciclastic-carbonate-aquifers-containing-metastable-sediments
#12
Daniel Franco, Kapo Coulibaly, Tanya Kunberger, Kristoph-Dietrich Kinzli, Sebastian Arbelaez, Thomas M Missimer
Mixed carbonate and siliciclastic marine sediments commonly become freshwater aquifers in eastern coastal regions of the United States and many other global locations. As these deposits age, the carbonate fraction of the sediment is commonly removed by dissolution and the aquifer can become a solely siliciclastic system or contain zones or beds of pure quartz sand. During aquifer evolution, the sediment grain size characteristics, hydraulic conductivity, and porosity change. An investigation of these changes using mixed carbonate/siliciclastic sediment samples collected from a modern barrier island beach in southern Florida showed that the average mean grain diameter decreased with removal of the carbonate fraction, but the average hydraulic conductivity and porosity increased slightly, but not to statistical significance...
May 10, 2017: Ground Water
https://www.readbyqxmd.com/read/28489262/mechanochemical-friedel-crafts-alkylation-a-sustainable-pathway-towards-porous-organic-polymers
#13
Erik Troschke, Sven Grätz, Tilo Lübken, Lars Borchardt
This study elucidates an innovative mechanochemical approach applying Friedel-Crafts alkylation to synthesize porous covalent triazine frameworks (CTFs). Herein, we pursue a counterintuitive approach by utilizing a rather destructive method to synthesize well-defined materials with intrinsic porosity. Investigating a model system including carbazole as monomer and cyanuric chloride as triazine node, ball milling is shown to successfully yield porous polymers almost quantitatively. We verified the successful structure formation by an in-depth investigation applying XPS, solid-state NMR and FT-IR spectroscopy...
May 10, 2017: Angewandte Chemie
https://www.readbyqxmd.com/read/28485894/an-orbital-overlap-complement-to-atomic-partial-charge
#14
Arshad Mehmood, Benjamin G Janesko
Atomic partial charges are widely used to predict reactivity. Partial charge alone is often insufficient: the carbons of benzene and cyclobutadiene, or those of diamond, graphene, and C60 , possess nearly identical partial charges and very different reactivities. Our atomic overlap distance complements computed partial charges by measuring the size of orbital lobes that best overlap with the wavefunction around an atom. Compact, chemically stable atoms tend to have overlap distances smaller than chemically soft, unstable atoms...
May 9, 2017: Angewandte Chemie
https://www.readbyqxmd.com/read/28485886/false-confessions
#15
REVIEW
Saul M Kassin
As illustrated by numerous cases in recent years, DNA exonerations of innocent individuals have cast a spotlight on the counterintuitive problem of false confessions. Studying the underlying psychology scientists have found that (1) innocent people are often targeted for interrogation because police make erroneous but confident judgments of deception; (2) certain interrogation techniques-namely, lengthy sessions, presentations of false evidence, and minimization themes that imply leniency-increase the risk that innocent people will confess; (3) certain individuals are particularly vulnerable to influence-notably, those with mental health problems or intellectual impairments, which render them overly compliant or suggestible, and children and adolescents, who exhibit 'immaturity of judgment'; (4) confession evidence is highly persuasive in court as a matter of common sense, increasing perceptions of guilt, even among judges and juries who see the confession as coerced, and even at times when the confession is contradicted by exculpatory information; (5) Miranda rights to silence and to counsel are not sufficiently protective, so proposals for reform have centered on the mandatory recording of interrogations, from start to finish, and a shift toward using investigative interviewing-a less confrontational, less deceptive means of questioning suspects...
May 9, 2017: Wiley Interdisciplinary Reviews. Cognitive Science
https://www.readbyqxmd.com/read/28480973/brain-activities-associated-with-learning-of-the-monty-hall-dilemma-task
#16
Takahiro Hirao, Timothy I Murphy, Hiroaki Masaki
The Monty Hall Dilemma (MHD) poses a counterintuitive probabilistic problem to the players of this game. In the MHD task, a participant chooses one of three options where only one contains a reward. After one of the unchosen options (always no reward) is disclosed, the participant is asked to make a final decision: either change to the remaining option or stick with their first choice. Although the probability of winning if they change is higher (2/3) compared to sticking with their first choice (1/3), most people stick with their original selection and often lose...
May 8, 2017: Psychophysiology
https://www.readbyqxmd.com/read/28470591/high-intensity-interval-training-in-facioscapulohumeral-muscular-dystrophy-type-1-a-randomized-clinical-trial
#17
Grete Andersen, Karen Heje, Astrid Emile Buch, John Vissing
Increasing evidence suggests that high-intensity training (HIT) is a time-efficient exercise strategy to improve fitness. HIT has never been explored in neuromuscular diseases, likely because it may seem counterintuitive. A single session of high-intensity exercise has been studied without signs of muscle damage in facioscapulohumeral muscular dystrophy type 1 (FSHD1). We aimed to determine whether HIT is safe and effective in FSHD1 in a randomized, controlled parallel study. Untrained adults with genetically verified FSHD1 (n = 13) able to perform cycle-ergometer exercise were randomized to 8 weeks of supervised HIT (n = 6) (3 × 10-min cycle-ergometer-HIT/week) or 8 weeks of usual care (n = 7)...
May 3, 2017: Journal of Neurology
https://www.readbyqxmd.com/read/28470433/effects-of-interplay-of-nanoparticles-surfactants-and-base-fluid-on-the-surface-tension-of-nanocolloids
#18
A R Harikrishnan, Purbarun Dhar, Prabhat K Agnihotri, Sateesh Gedupudi, Sarit K Das
A systematically designed study has been conducted to understand and demarcate the degree of contribution by the constituting elements to the surface tension of nanocolloids. The effects of elements such as surfactants, particles and the combined effects of these on the surface tension of these complex fluids are studied employing the pendant drop shape analysis method by fitting the Young-Laplace equation. Only the particle has shown an increase in the surface tension with particle concentration in a polar medium like DI water, whereas only a marginal effect of particles on surface tension in weakly polar mediums like glycerol and ethylene glycol has been demonstrated...
May 2017: European Physical Journal. E, Soft Matter
https://www.readbyqxmd.com/read/28468877/preservation-of-peripheral-t-follicular-helper-cell-function-in-hiv-controllers
#19
Supranee Buranapraditkun, Franco Pissani, Jeffrey E Teigler, Bruce T Schultz, Galit Alter, Mary Marovich, Merlin L Robb, Michael A Eller, Jeff Martin, Steven Deeks, Nelson L Michael, Hendrik Streeck
The maturation process of high-affinity antibodies is a result of intricate interactions between B cells and follicular helper T (Tfh) cells occurring in lymphoid germinal centers. HIV infection induces significant chronic immune activation, phenotypic skewing, and inflammation driven by years of continuous viral replication. High levels of viremia as well as immune activation and dysfunction have been demonstrated to have a perturbing impact on the B cell memory compartment and contribute to B cell exhaustion...
May 3, 2017: Journal of Virology
https://www.readbyqxmd.com/read/28466098/lone-pair-%C3%AF-interactions-in-biological-systems-occurrence-function-and-physical-origin
#20
REVIEW
Jiří Kozelka
Lone pair-π interactions are now recognized as a supramolecular bond whose existence in biological systems is documented by a growing number of examples. They are commonly attributed to electrostatic forces. This review attempts to highlight some recent discoveries evidencing the important role which lone pair-π interactions, and anion-π interactions in particular, play in stabilizing the structure and affecting the function of biomolecules. Special attention is paid to studies exploring the physical origin of these at first glance counterintuitive interactions between a lone pair of electrons of one residue and the π-cloud of another...
May 2, 2017: European Biophysics Journal: EBJ
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