quantum yield review

Food safety concerns have become a significant threat to human health and well-being, catching global attention in recent years. As a result, it is imperative to research conceptually novel biosensing and effective techniques for food matrices detection. Currently, DNA-templated metal nanoclusters (DNA-MNCs) are considered as one of the most promising nanomaterials due to their excellent properties in biosensing. While DNA-MNCs have garnered increasing interest, the reviews of design strategies, applications, and futuristic prospects for biosensing have been hardly found especially in food safety...

Source location in quantum networks is a critical area of research with profound implications for cutting-edge fields such as quantum state tomography, quantum computing, and quantum communication. In this study, we present groundbreaking research on the technique and theory of source location in Szegedy's quantum networks. We develop a linear system evolution model for a Szegedy's quantum network system using matrix vectorization techniques. Subsequently, we propose a highly precise and robust source-location algorithm based on compressed sensing specifically tailored for Szegedy's quantum network...

In recent years, carbon dots (CDs) have garnered increasing attention due to their simple preparation methods, versatile performances, and wide-ranging applications. CDs can manifest various optical, physical, and chemical properties including quantum yield (QY), emission wavelength (Em), solid-state fluorescence (SSF), room-temperature phosphorescence (RTP), material-specific responsivity, pH sensitivity, anti-oxidation and oxidation, and biocompatibility. These properties can be effectively regulated through precise control of the CD preparation process, rendering them suitable for diverse applications...

Third-generation organic light-emitting diodes (OLEDs) based on metal-free thermally activated delayed fluorescent (TADF) materials have sparked tremendous interest in the last decade due to their nearly 100% exciton utilization efficiency, which can address the low-efficiency issue of the first-generation fluorescent emitters and the high-cost issue of the second-generation organometallic phosphorescent emitters. Construction of efficient and stable TADF-OLEDs requires utilizing TADF materials with a narrow singlet-triplet energy gap (ΔEST ), high photoluminescence quantum yield (PLQY) and short TADF lifetime...

Phosphorene, or two-dimensional (2D) black phosphorus, has recently emerged as a competitor of graphene as it offers several advantages, including a tunable band gap, higher on/off current ratio, piezoelectric nature, and biocompatibility. Researchers have succeeded in obtaining several forms of phosphorene, such as nanosheets, nanorods, nanoribbons, and quantum dots, with satisfactory yields. Nanostructures with various controlled properties have been fabricated in multiple devices for energy production. These phosphorene-based devices are lightweight, flexible, and efficient, demonstrating great potential for energy-harvesting applications in sensors and nanogenerators...

The search for empirical schemes to evidence the nonclassicality of large masses is a central quest of current research. However, practical schemes to witness the irreducible quantumness of an arbitrarily large mass are still lacking. To this end, we incorporate crucial modifications to the standard tools for probing the quantum violation of the pivotal classical notion of macrorealism (MR): while usual tests use the same measurement arrangement at successive times, here we use two different measurement arrangements...

Quasi-two-dimensional (quasi-2D) perovskites have attracted much attention due to their outstanding properties, such as inherent quantum-well structure, strong dielectric and quantum confinement, large exciton binding energy, and high photoluminescence quantum yield. By virtue of these superior merits, quasi-2D perovskites have shown great potential for next-generation light-emitting diodes (LEDs). Herein, this review presents an overview of the basic properties of quasi-2D perovskites and their photoluminescence modulations by large organic cation engineering, monovalent cation engineering, halogen engineering, defect passivation engineering, and dimensionality engineering...

Research on lead halide perovskites has demonstrated that they are one of the potential materials for optoelectronic and bio-related applications owing to their promising optical and electronic properties. However, their poor chemical stability in ambient environments is a critical factor that affects their practical applications. Silica is known for its excellent environmental/chemical stability and good optical properties. Therefore, SiO2 -coated lead halide perovskites have been studied by introducing the protective layer containing SiO2 to prevent the rapid destruction of their surface chemistry and environmental degradation...

Halide perovskites have emerged as promising materials for various optoelectronic devices because of their excellent optical and electrical properties. In particular, halide perovskite quantum dots (PQDs) have garnered considerable attention as emissive materials for light-emitting diodes (LEDs) because of their higher color purities and photoluminescence quantum yields compared to conventional inorganic quantum dots (CdSe, ZnSe, ZnS, etc.). However, PQDs exhibit poor structural stabilities in response to external stimuli (moisture, heat, etc...

Tip-enhanced nano-spectroscopy and -imaging have significantly advanced our understanding of low-dimensional quantum materials and their interactions with light, providing a rich insight into the underlying physics at their natural length scale. Recently, various functionalities of the plasmonic tip expand the capabilities of the nanoscopy, enabling dynamic manipulation of light-matter interactions at the nanoscale. In this review, we focus on a new paradigm of the nanoscopy, shifting from the conventional role of imaging and spectroscopy to the dynamical control approach of the tip-induced light-matter interactions...

This article provides a discussion on the construction of conformal Gaussian gauge systems to study the evolution of solutions to the Einstein field equations with positive Cosmological constant. This is done by means of a gauge based on the properties of conformal geodesics. The use of this gauge, combined with the extended conformal Einstein field equations, yields evolution equations in the form of a symmetric hyperbolic system for which standard Cauchy stability results can be employed. This strategy is used to study the global properties of de Sitter-like spacetimes with constant negative scalar curvature...

Iridium(III) complexes are emerging as a promising tool in the area of detection and therapy due to their prominent photophysical properties, including higher photostability, tunable phosphorescence emission, long-lasting phosphorescence, and high quantum yields. In recent years, much effort has been devoted to develop novel near-infrared (NIR) iridium(III) complexes to improve signal-to-noise ratio and enhance tissue penetration. In this review, we summarize different classes of organometallic NIR iridium(III) complexes for detection and therapy, including cyclometalated ligand-enabled NIR iridium(III) complexes and NIR-dye-conjugated iridium(III) complexes...

Colloidal quantum dots (QDs) are widely regarded as advanced emissive materials with significant potential for display applications owing to their excellent optical properties such as high color purity, near-unity photoluminescence quantum yield, and size-tunable emission color. Building upon these attractive attributes, QDs have successfully garnered attention in the display market as down-conversion luminophores and now venturing into the realm of self-emissive displays, exemplified by QD light-emitting diodes (QD-LEDs)...

A set of empirical rovibrational energy levels, obtained through the MARVEL (measured active rotational-vibrational energy levels) procedure, is presented for the <mml:math xmlns:mml="https://www.w3.org/1998/Math/MathML"> <mml:semantics> <mml:mrow><mml:msup><mml:mrow/> <mml:mrow><mml:mn>13</mml:mn></mml:mrow> </mml:msup> </mml:mrow> <mml:annotation>$$ {}^{13} $$</mml:annotation></mml:semantics> </mml:math> C <mml:math xmlns:mml="https://www...

It is predicted that strongly interacting spins on a frustrated lattice may lead to a quantum disordered ground state or even form a quantum spin liquid with exotic low-energy excitations. However, a controlled tuning of the frustration strength, separating its effects from those of disorder and other factors, is pending. Here, we perform comprehensive ^{1}H NMR measurements on Y_{3}Cu_{9}(OH)_{19}Cl_{8} single crystals revealing an unusual Q[over →]=(1/3×1/3) antiferromagnetic state below T_{N}=2...

A major challenge for density functional theory (DFT) is its failure to treat static correlation, yielding errors in predicted charges, band gaps, van der Waals forces, and reaction barriers. Here we combine one- and two-electron reduced density matrix (1- and 2-RDM) theories with DFT to obtain a universal O(N^{3}) generalization of DFT for static correlation. Using the lowest unitary invariant of the cumulant 2-RDM, we generate a 1-RDM functional theory that corrects the convexity of any DFT functional to capture static correlation in its fractional orbital occupations...

Boron-based multiple-resonance (MR) emitters exhibit the advantages of narrowband emission, high absolute photoluminescence quantum yield, thermally activated delayed fluorescence (TADF), and sufficient stability during the operation of organic light-emitting diodes (OLEDs). Thus, such MR emitters have been widely applied as blue emitters in triplet-triplet-annihilation-driven fluorescent devices used in smartphones and televisions. Moreover, they hold great promise as TADF or terminal emitters in TADF-assisted fluorescence or phosphor-sensitised fluorescent OLEDs...

Vibrational spectroscopy is an omnipresent spectroscopic technique to characterize functional nanostructured materials such as zeolites, metal-organic frameworks (MOFs), and metal-halide perovskites (MHPs). The resulting experimental spectra are usually complex, with both low-frequency framework modes and high-frequency functional group vibrations. Therefore, theoretically calculated spectra are often an essential element to elucidate the vibrational fingerprint. In principle, there are two possible approaches to calculate vibrational spectra: (i) a static approach that approximates the potential energy surface (PES) as a set of independent harmonic oscillators and (ii) a dynamic approach that explicitly samples the PES around equilibrium by integrating Newton's equations of motions...

The fission of a string connecting two charges is an astounding phenomenon in confining gauge theories. The dynamics of this process have been studied intensively in recent years, with plenty of numerical results yielding a dichotomy: the confining string can decay relatively fast or persist up to extremely long times. Here, we put forward a dynamical localization transition as the mechanism underlying this dichotomy. To this end, we derive an effective string breaking description in the light-meson sector of a confined spin chain and show that the problem can be regarded as a dynamical localization transition in Fock space...

Long-range hoppings in quantum disordered systems are known to yield quantum multifractality, the features of which can go beyond the characteristic properties associated with an Anderson transition. Indeed, critical dynamics of long-range quantum systems can exhibit anomalous dynamical behaviors distinct from those at the Anderson transition in finite dimensions. In this paper, we propose a phenomenological model of wave packet expansion in long-range hopping systems. We consider both their multifractal properties and the algebraic fat tails induced by the long-range hoppings...