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titanium corrosion

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https://www.readbyqxmd.com/read/28073074/tribocorrosion-behavior-of-bio-functionalized-highly-porous-titanium
#1
F Toptan, A C Alves, A M P Pinto, P Ponthiaux
Titanium and its alloys are widely used in orthopedic and dental implants, however, some major clinical concerns such as poor wear resistance, lack of bioactivity, and bone resorption due to stress shielding are yet to be overcome. In order to improve these drawbacks, highly porous Ti samples having functionalized surfaces were developed by powder metallurgy with space holder technique followed by anodic treatment. Tribocorrosion tests were performed in 9g/L NaCl solution using a unidirectional pin-on-disc tribometer under 3N normal load, 1Hz frequency and 4mm track diameter...
January 4, 2017: Journal of the Mechanical Behavior of Biomedical Materials
https://www.readbyqxmd.com/read/28064103/why-do-some-titanium-alloy-total-hip-arthroplasty-modular-necks-fail
#2
Samo K Fokter, Andrej Moličnik, Rajko Kavalar, Primož Pelicon, Rebeka Rudolf, Nenad Gubeljak
BACKGROUND: Increased modularity in total hip arthroplasty (THA) through extra junction between the neck and the femoral stem is gaining popularity among orthopaedic community. However, the advantage of the additional junction is shadowed by an increased risk of mechanical failure. The aim of this study was to describe the exact mechanism of fracture of the modular femoral neck in an uncemented stem. METHODS: Clinical, metallurgical, and mechanical analysis including finite-element modelling and elemental-sensitive tissue analysis with the micro-PIXE method was performed on two patients treated with fully modular primary THA made from Titanium alloy of the same oval taper-cone design...
December 27, 2016: Journal of the Mechanical Behavior of Biomedical Materials
https://www.readbyqxmd.com/read/28024627/fretting-corrosion-behavior-of-nitinol-spinal-rods-in-conjunction-with-titanium-pedicle-screws
#3
Elena Lukina, Mikhail Kollerov, Jay Meswania, Alla Khon, Pavel Panin, Gordon W Blunn
Untypical corrosion damage including erosions combined with the build-up of titanium oxide as a corrosion product on the surface of explanted Nitinol spinal rods in the areas where it was in contact with titanium pedicle screw head is reported. It was suggested that Nitinol rods might have inferior fretting corrosion resistance compared with that made of titanium or CoCr. Fretting corrosion of Nitinol spinal rods with titanium (Ti6Al4V) pedicle screws were tested in-vitro by conducting a series of potentiostatic measurements of the peak-to-peak values of fretting corrosion current under bending in a 10% solution of calf serum in PBS...
March 1, 2017: Materials Science & Engineering. C, Materials for Biological Applications
https://www.readbyqxmd.com/read/28024610/alkalescent-nanotube-films-on-a-titanium-based-implant-a-novel-approach-to-enhance-biocompatibility
#4
Yanxian Zhang, Chaofang Dong, Sefei Yang, Junsheng Wu, Kui Xiao, Yunhua Huang, Xiaogang Li
The interfacial pH value has a marked effect on cell viability because the pro-mineralization activity of osteoblasts increases at alkaline extracellular pH, whereas the pro-resorptive activity of osteoclasts increases under more acidic conditions. To obtain the more favorable alkaline interface, we developed a novel nanotube layer that was incorporated with magnesium oxide on a titanium implant substrate (MgO/NT/Ti) via ethylenediamine tetraacetic acid (EDTA) chelation. This facile immersion-annealing process successfully created a homogeneous magnesium oxide layer with sustained release kinetics and superior hydrophilicity according to the surface characterization and microenvironment measurement...
March 1, 2017: Materials Science & Engineering. C, Materials for Biological Applications
https://www.readbyqxmd.com/read/28009708/trunnion-corrosion-in-metal-on-polyethylene-total-hip-arthroplasty-a-case-series
#5
Sivashanmugam Raju, Karthikeyan Chinnakkannu, Mohan K Puttaswamy, Matthew J Phillips
INTRODUCTION: Modular total hip arthroplasty implants can help the operating surgeon reproduce the optimum limb length and offset; however, the modularity can lead to fretting and corrosion with associated metal-related problems. Although metal-on-metal bearings are often reported to have problems, recent case reports suggest that the problems can occur with any articulation, usually as a result of problems at the head/neck junction. METHODS: We retrospectively reviewed three cases of a specific implant combination with nontraumatic trunnion failure, with two cases presenting as acute complete dissociation of the femoral head from the neck...
February 2017: Journal of the American Academy of Orthopaedic Surgeons
https://www.readbyqxmd.com/read/27988440/evaluation-of-the-mechanical-properties-of-powder-metallurgy-ti-6al-7nb-alloy
#6
L Bolzoni, E M Ruiz-Navas, E Gordo
Titanium and its alloys are common biomedical materials owing to their combination of mechanical properties, corrosion resistance and biocompatibility. Powder metallurgy (PM) techniques can be used to fabricate biomaterials with tailored properties because changing the processing parameters, such as the sintering temperature, products with different level of porosity and mechanical performances can be obtained. This study addresses the production of the biomedical Ti-6Al-7Nb alloy by means of the master alloy addition variant of the PM blending elemental approach...
December 9, 2016: Journal of the Mechanical Behavior of Biomedical Materials
https://www.readbyqxmd.com/read/27987677/is-there-scientific-evidence-favoring-the-substitution-of-commercially-pure-titanium-with-titanium-alloys-for-the-manufacture-of-dental-implants
#7
REVIEW
Jairo M Cordeiro, Valentim A R Barão
The development of Ti alloys to manufacture dental implants has emerged in recent years due to the increased failure of commercially pure titanium (cpTi) implants. Thus, this study reviews existing information about the mechanical, chemical, electrochemical, and biological properties of the main Ti alloys developed over the past few years to provide scientific evidence in favor of using Ti-based alloys as alternative to cpTi. Ti alloys may be considered viable substitutes in the fabrication of dental implants...
February 1, 2017: Materials Science & Engineering. C, Materials for Biological Applications
https://www.readbyqxmd.com/read/27987668/influence-of-cu-au-and-ag-on-structural-and-surface-properties-of-bioactive-coatings-based-on-titanium
#8
D Wojcieszak, M Mazur, M Kalisz, M Grobelny
In this work influence of copper, silver and gold additives on structural and surface properties of biologically active thin films based on titanium have been described. Coatings were prepared by magnetron sputtering method. During each process metallic discs (targets) - Ti and the additive (Cu, Ag or Au) were co-sputtered in argon atmosphere. Structural investigation of as-deposited coatings was performed with the aid of XRD and SEM/EDS method. It was found that all prepared thin films were homogenous. Addition of Cu, Ag and Au resulted in nanocrystalline structure...
February 1, 2017: Materials Science & Engineering. C, Materials for Biological Applications
https://www.readbyqxmd.com/read/27987658/a-novel-approach-to-fabrication-of-three-dimensional-porous-titanium-with-controllable-structure
#9
Dong Wang, Qiuyan Li, Mingqin Xu, Guofeng Jiang, Yunxia Zhang, Guo He
A new approach to fabrication of porous titanium by using the molybdenum wire as space holder was developed, in which titanium liquid was cast into the entangled molybdenum wires in a vacuum environment, and followed by etching off the space holder material in an aqua regia solution. This infiltration casting and acid corrosion method fabricated the porous titanium with different porosities with a pore diameter of 0.4mm. The porous titanium with the porosity of 32-47% exhibited the Young's modulus in the range of 23-62GPa and the yielding strength in the range of 76-192MPa...
February 1, 2017: Materials Science & Engineering. C, Materials for Biological Applications
https://www.readbyqxmd.com/read/27897215/novel-ti-ta-hf-zr-alloys-with-promising-mechanical-properties-for-prospective-stent-applications
#10
Jixing Lin, Sertan Ozan, Yuncang Li, Dehai Ping, Xian Tong, Guangyu Li, Cuie Wen
Titanium alloys are receiving increasing research interest for the development of metallic stent materials due to their excellent biocompatibility, corrosion resistance, non-magnetism and radiopacity. In this study, a new series of Ti-Ta-Hf-Zr (TTHZ) alloys including Ti-37Ta-26Hf-13Zr, Ti-40Ta-22Hf-11.7Zr and Ti-45Ta-18.4Hf-10Zr (wt.%) were designed using the d-electron theory combined with electron to atom ratio (e/a) and molybdenum equivalence (Moeq) approaches. The microstructure of the TTHZ alloys were investigated using optical microscopy, XRD, SEM and TEM and the mechanical properties were tested using a Vickers micro-indenter, compression and tensile testing machines...
November 29, 2016: Scientific Reports
https://www.readbyqxmd.com/read/27886000/evaluation-of-corrosion-resistance-and-surface-characteristics-of-orthodontic-wires-immersed-in-different-mouthwashes
#11
Didem Nalbantgil, Feyza Ulkur, Gulfeza Kardas, Mustafa Culha
BACKGROUND: Patients use mouthwashes in addition to mechanical cleaning during orthodontic treatment. The effects of mouthwashes on the archwires have not been examined yet. OBJECTIVE: To compare the corrosion resistance of four different arch wires and corrosion effects of different mouthwashes to formulate a biocompatible and mechanically useful arch wire and mouthwash combination. METHODS: Each group comprised of 4 wire samples of 2 cm 0...
November 25, 2016: Bio-medical Materials and Engineering
https://www.readbyqxmd.com/read/27881805/corrosion-resistance-and-biological-activity-of-tio2-implant-coatings-produced-in-oxygen-rich-environments
#12
Rui Zhang, Yi Wan, Xing Ai, Zhanqiang Liu, Dong Zhang
The physical and chemical properties of bio-titanium alloy implant surfaces play an important role in their corrosion resistance and biological activity. New turning and turning-rolling processes are presented, employing an oxygen-rich environment in order to obtain titanium dioxide layers that can both protect implants from corrosion and also promote cell adhesion. The surface topographies, surface roughnesses and chemical compositions of the sample surfaces were obtained using scanning electron microscopy, a white light interferometer, and the Auger electron spectroscopy, respectively...
January 2017: Proceedings of the Institution of Mechanical Engineers. Part H, Journal of Engineering in Medicine
https://www.readbyqxmd.com/read/27869194/a-highly-efficient-stable-durable-and-recyclable-filter-fabricated-by-femtosecond-laser-drilling-of-a-titanium-foil-for-oil-water-separation
#13
Sen Ye, Qiang Cao, Qingsong Wang, Tianyuan Wang, Qing Peng
It has been a long standing challenge to efficiently separate oil and water since prehistoric times, and now it has become even more desirable in oily wastewater purification and oil spill cleanup. Here we introduce a super oil-water separation filter with superhydrophilicity and underwater superoleophobicity, fabricated using femtosecond laser micro-hole drilling of a titanium foil. Such a simply-made filter, without any modification, can achieve a separation efficiency exceeding 99% in eight typical oil-water mixtures...
November 21, 2016: Scientific Reports
https://www.readbyqxmd.com/read/27860159/evaluation-of-corrosion-resistance-of-implant-use-ti-zr-binary-alloys-with-a-range-of-compositions
#14
Teisuke Akimoto, Takeshi Ueno, Yusuke Tsutsumi, Hisashi Doi, Takao Hanawa, Noriyuki Wakabayashi
Although titanium-zirconium (Ti-Zr) alloy has been adopted for clinical applications, the ideal proportion of Zr in the alloy has not been identified. In this study, we investigated the biocompatibility of Ti-Zr alloy by evaluating its corrosion resistance to better understand whether there is an optimal range or value of Zr proportion in the alloy. We prepared pure Ti, Ti-30Zr, Ti-50Zr, Ti-70Zr, and pure Zr (mol% of Zr) samples and subjected them to anodic polarization and immersion tests in a lactic acid + sodium chloride (NaCl) solution and artificial saliva...
November 18, 2016: Journal of Biomedical Materials Research. Part B, Applied Biomaterials
https://www.readbyqxmd.com/read/27858551/increased-levels-of-dissolved-titanium-are-associated-with-peri-implantitis-a-case-control-study
#15
Luciana M Safioti, Georgios A Kotsakis, Alex E Pozhitkov, Whasun O Chung, Diane M Daubert
BACKGROUND: Peri-implantitis represents a disruption of the biocompatible interface between the titanium (Ti) dioxide layer of the implant surface and the peri-implant tissues. Increasing preclinical data suggest that the peri-implantitis microbiota not only triggers an inflammatory immune response but also causes electrochemical alterations of the Ti surfaces, i.e. corrosion, that aggravate this inflammatory response. Thus, we hypothesized that there is an association between the dissolution of titanium from dental implants, which suggests corrosion, and peri-implantitis in humans...
November 18, 2016: Journal of Periodontology
https://www.readbyqxmd.com/read/27836578/will-new-metal-heads-restore-mechanical-integrity-of-corroded-trunnions
#16
Aditya Derasari, Jonathan E Gold, Sabir Ismaily, Philip C Noble, Stephen J Incavo
BACKGROUND: Metal wear and corrosion from modular junctions in total hip arthroplasty can lead to further unwanted surgery. Trunnion tribocorrosion is recognized as an important contributor to failure. This study was performed to determine if new metal heads restore mechanical integrity of the original modular junction after impaction on corroded trunnions, and assess which variables affect stability of the new interface created at revision total hip arthroplasty. METHODS: Twenty-two trunnions, cobalt-chromium (CoCr) and titanium alloy (TiAIV), (CoCr, n = 12; TiAIV, n = 10) and new metal heads were used, 10 trunnions in pristine condition and 12 with corrosion damage...
October 11, 2016: Journal of Arthroplasty
https://www.readbyqxmd.com/read/27829756/corrosion-resistance-of-stainless-steel-nickel-titanium-titanium-molybdenum-alloy-and-ion-implanted-titanium-molybdenum-alloy-archwires-in-acidic-fluoride-containing-artificial-saliva-an-in-vitro-study
#17
Venith Jojee Pulikkottil, S Chidambaram, P U Bejoy, P K Femin, Parson Paul, Mohamed Rishad
OBJECTIVE: (1) To evaluate the corrosion resistance of four different orthodontic archwires and to determine the effect of 0.5% NaF (simulating high fluoride-containing toothpaste of about 2250 ppm) on corrosion resistance of these archwires. (2) To assess whether surface roughness (Ra) is the primary factor influencing the corrosion resistance of these archwires. MATERIALS AND METHODS: Four different archwires (stainless steel [SS], nickel-titanium [NiTi], titanium molybdenum alloy [TMA], and ion-implanted TMA) were considered for this study...
October 2016: Journal of Pharmacy & Bioallied Sciences
https://www.readbyqxmd.com/read/27818733/skin-corrosion-and-irritation-test-of-nanoparticles-using-reconstructed-three-dimensional-human-skin-model-epiderm-tm
#18
Hyejin Kim, Jonghye Choi, Handule Lee, Juyoung Park, Byung-Il Yoon, Seon Mi Jin, Kwangsik Park
Effects of nanoparticles (NPs) on skin corrosion and irritation using three-dimensional human skin models were investigated based on the test guidelines of Organization for Economic Co-operation and Development (OECD TG431 and TG439). EpiDerm(TM) skin was incubated with NPs including those harboring iron (FeNPs), aluminum oxide (AlNPs), titanium oxide (TNPs), and silver (AgNPs) for a defined time according to the test guidelines. Cell viabilities of EpiDerm(TM) skins were measured by the 3-(4, 5-dimethylthi-azol-2-yl)-2...
October 2016: Toxicological Research
https://www.readbyqxmd.com/read/27818563/corrosion-behavior-of-plasma-electrolytically-oxidized-gamma-titanium-aluminide-alloy-in-simulated-body-fluid
#19
L Lara Rodriguez, P A Sundaram
Plasma electrolytic oxidized (PEO) γTiAl alloy samples were electrochemically characterized by open circuit potential (OCP), cyclic polarization and electrochemical impedance spectroscopy (EIS) to evaluate their corrosion resistance in simulated body fluid (SBF) in order to gauge their potential for biomedical applications. Experimental results through OCP and cyclic polarization studies demonstrated the protective nature and the beneficial effect of the PEO coatings on γTiAl. The PEO surface increased corrosion resistance of these surface modified alloys...
September 15, 2016: Materials Chemistry and Physics
https://www.readbyqxmd.com/read/27782560/a-new-flexible-titanium-foil-cell-for-hydrothermal-experiments-and-fluid-sampling
#20
Shi-Jun Wu, Min-Jian Cai, Can-Jun Yang, Ke-Wei Li
This paper describes the design of a flexible titanium foil cell, as well as its applications in hydrothermal experiments and in non-contaminating storage of seafloor hydrothermal fluids. A flexible cell constructed totally from pure titanium (Grade 1) can be used in corrosive environment because of the excellent chemical stability and temperature tolerance of the material. Theoretical calculation and finite element analysis of the titanium foil cell have been conducted to identify its flexibility and deformation mode...
September 2016: Review of Scientific Instruments
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