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https://www.readbyqxmd.com/read/25202942/unconventional-molecule-resolved-current-rectification-in-diamondoid-fullerene-hybrids
#1
Jason C Randel, Francis C Niestemski, Andrés R Botello-Mendez, Warren Mar, Georges Ndabashimiye, Sorin Melinte, Jeremy E P Dahl, Robert M K Carlson, Ekaterina D Butova, Andrey A Fokin, Peter R Schreiner, Jean-Christophe Charlier, Hari C Manoharan
The unimolecular rectifier is a fundamental building block of molecular electronics. Rectification in single molecules can arise from electron transfer between molecular orbitals displaying asymmetric spatial charge distributions, akin to p-n junction diodes in semiconductors. Here we report a novel all-hydrocarbon molecular rectifier consisting of a diamantane-C60 conjugate. By linking both sp(3) (diamondoid) and sp(2) (fullerene) carbon allotropes, this hybrid molecule opposingly pairs negative and positive electron affinities...
2014: Nature Communications
https://www.readbyqxmd.com/read/20657836/a-comparative-approach-linking-molecular-dynamics-of-altered-peptide-ligands-and-mhc-with-in-vivo-immune-responses
#2
Bernhard Knapp, Ulrich Omasits, Wolfgang Schreiner, Michelle M Epstein
BACKGROUND: The recognition of peptide in the context of MHC by T lymphocytes is a critical step in the initiation of an adaptive immune response. However, the molecular nature of the interaction between peptide and MHC and how it influences T cell responsiveness is not fully understood. RESULTS: We analyzed the immunological consequences of the interaction of MHC class II (I-Au) restricted 11-mer peptides of myelin basic protein with amino acid substitutions at position 4...
July 19, 2010: PloS One
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