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https://www.readbyqxmd.com/read/29682817/light-driven-reversible-transformation-between-self-organized-simple-cubic-lattice-and-helical-superstructure-enabled-by-a-molecular-switch-functionalized-nanocage
#1
Kang Zhou, Hari Krishna Bisoyi, Jian-Qiu Jin, Cong-Long Yuan, Zhen Liu, Dong Shen, Yan-Qing Lu, Zhi-Gang Zheng, Weian Zhang, Quan Li
Self-organized stimuli-responsive smart materials with adjustable attributes are highly desirable for a plethora of device applications. Simple cubic lattice is quite uncommon in soft condensed matter due to its lower packing factor. Achieving a stable simple cubic soft lattice and endowing such a lattice with dynamic reconstruction capability solely by a facile light irradiation are of paramount significance for both fundamental studies and engineering explorations. Herein, an elegant stable self-organized simple cubic soft lattice, i...
April 23, 2018: Advanced Materials
https://www.readbyqxmd.com/read/29652381/tuning-selective-reflection-of-light-by-surface-anchoring-in-cholesteric-cells-with-oblique-helicoidal-structures
#2
Olena S Iadlovska, Graham R Maxwell, Greta Babakhanova, Georg H Mehl, Christopher Welch, Sergij V Shiyanovskii, Oleg D Lavrentovich
Selective reflection of light by oblique helicoidal cholesteric (ChOH ) can be tuned in a very broad spectral range by an applied electric field. In this Letter, we demonstrate that the peak wavelength of the selective reflection can be controlled by the surface alignment of the director in sandwich cells. The peak wavelength is blue-shifted when the surface alignment is perpendicular to the bounding plates and red-shifted when it is planar. The effect is explained by the electric field redistribution within the cell caused by a spatially varying heliconical ChOH structure...
April 15, 2018: Optics Letters
https://www.readbyqxmd.com/read/29651630/speeding-up-monte-carlo-simulation-of-patchy-hard-cylinders
#3
Alberto Giacomo Orellana, Emanuele Romani, Cristiano De Michele
The hard cylinder model decorated with attractive patches proved to be very useful recently in studying physical properties of several colloidal systems. Phase diagram, elastic constants and cholesteric properties obtained from computer simulations based on a simple hard cylinder model have been all successfully and quantitatively compared to experimental results. Key to these simulations is an efficient algorithm to check the overlap between hard cylinders. Here, we propose two algorithms to check the hard cylinder overlap and we assess their efficiency through a comparison with an existing method available in the literature and with the well-established algorithm for simulating hard spherocylinders...
April 16, 2018: European Physical Journal. E, Soft Matter
https://www.readbyqxmd.com/read/29651488/a-full-color-photonic-polymer-rewritable-with-a-liquid-crystal-ink
#4
Monali Moirangthem, Anouk F Scheers, Albertus P H J Schenning
A printable and rewritable photonic polymer coating has been fabricated from a cholesteric liquid crystal. Full color images can be patterned in polymer coatings by using a liquid crystal ink. The printed patterns can be erased and rewritten multiple times, making these coatings interesting as rewritable papers.
April 13, 2018: Chemical Communications: Chem Comm
https://www.readbyqxmd.com/read/29626129/light-activated-helical-inversion-in-cholesteric-liquid-crystal-microdroplets
#5
Piotr Sleczkowski, Ye Zhou, Supitchaya Iamsaard, Juan J de Pablo, Nathalie Katsonis, Emmanuelle Lacaze
Cholesteric liquid crystal (CLC) droplets exhibit nontrivial topological features, which are controlled by the ratio between the cholesteric pitch and the droplet radius. The radial spherical structure (RSS) is of particular interest, as it reveals an onion-like concentric organization of the cholesteric helices, leading to the expression of spherical Bragg microcavities. Using an overcrowded alkene-based unidirectional molecular motor as a dopant, we show that the topological defect structure in the droplet can be activated by illumination...
April 6, 2018: Proceedings of the National Academy of Sciences of the United States of America
https://www.readbyqxmd.com/read/29624196/highly-concentrated-collagen-solutions-leading-to-transparent-scaffolds-of-controlled-three-dimensional-organizations-for-corneal-epithelial-cell-colonization
#6
Aurélien Tidu, Djida Ghoubay-Benallaoua, Claire Teulon, Sophie Asnacios, Kate Grieve, François Portier, Marie-Claire Schanne-Klein, Vincent Borderie, Gervaise Mosser
This study aimed at controlling both the organization and the transparency of dense collagen scaffolds making use of the lyotropic mesogen properties of collagen. Cholesteric or plywood-like liquid crystal phases were achieved using mixtures of acetic and hydrochloric acids as solvents. The critical pH at which the switch between the two phases occurred was around pH = 3. The use of the two acids led to fibrillated collagen I scaffolds, whose visual aspect ranged from opaque to transparent. Rheological investigations showed that viscoelastic properties of the plywood-like solutions were optimized for molding due to faster recovery...
April 6, 2018: Biomaterials Science
https://www.readbyqxmd.com/read/29603448/stimuli-driven-control-of-the-helical-axis-of-self-organized-soft-helical-superstructures
#7
REVIEW
Hari Krishna Bisoyi, Timothy J Bunning, Quan Li
Supramolecular and macromolecular functional helical superstructures are ubiquitous in nature and display an impressive catalog of intriguing and elegant properties and performances. In materials science, self-organized soft helical superstructures, i.e., cholesteric liquid crystals (CLCs), serve as model systems toward the understanding of morphology- and orientation-dependent properties of supramolecular dynamic helical architectures and their potential for technological applications. Moreover, most of the fascinating device applications of CLCs are primarily determined by different orientations of the helical axis...
March 30, 2018: Advanced Materials
https://www.readbyqxmd.com/read/29584431/structure-evolution-and-drying-dynamics-in-sliding-cholesteric-cellulose-nanocrystals
#8
Guang Chu, Rita Vilensky, Gleb Vasilyev, Patrick Martin, Ruiyan Zhang, Eyal Zussman
The study of colloidal liquid crystals (LCs) reveals fundamental insights into the nature of ordered materials, giving rise to emergent properties with fascinating applications in soft matter nanotechnology. Here we investigate the shape instabilities, layer undulations, dynamic assembly, and collective behaviors in evaporating a cellulose nanocrystal-based cholesteric LC drop. During the drying process, the drop edges are pinned to the substrate with spontaneous convective flow occurring along the drop, which leads to nonequilibrium sliding of the individual cholesteric fragment with active ordering as well as hydrodynamic fluctuations and flow transitions in the bulk cholesteric phase...
March 29, 2018: Journal of Physical Chemistry Letters
https://www.readbyqxmd.com/read/29569432/manipulation-of-structural-colors-in-liquid-crystal-helical-structures-deformed-by-surface-controls
#9
Chaeri Lim, Sooyeon Bae, Soon Moon Jeong, Na Young Ha
Structural colors from cholesteric liquid crystals (CLCs) are manipulated by changing the only surface anchoring energy of an alignment layer. This behavior comes from the fact that weak surface energy of the perfluoropolymer induces the tilting of the cholesteric helix. Such deformed CLC structures with durability are successfully demonstrated without both any external field applications and additional solidification processes. In addition, electrical tunings of structural colors from the deformed CLCs occur at very low operating voltages, compared with those of conventional CLC structures...
March 23, 2018: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/29556006/confinement-induced-liquid-crystalline-transitions-in-amyloid-fibril-cholesteric-tactoids
#10
Gustav Nyström, Mario Arcari, Raffaele Mezzenga
Chirality is ubiquitous in nature and plays crucial roles in biology, medicine, physics and materials science. Understanding and controlling chirality is therefore an important research challenge with broad implications. Unlike other chiral colloids, such as nanocellulose or filamentous viruses, amyloid fibrils form nematic phases but appear to miss their twisted form, the cholesteric or chiral nematic phases, despite a well-defined chirality at the single fibril level. Here we report the discovery of cholesteric phases in amyloids, using β-lactoglobulin fibrils shortened by shear stresses...
March 19, 2018: Nature Nanotechnology
https://www.readbyqxmd.com/read/29521982/continuously-tunable-optical-notch-filter-and-band-pass-filter-systems-that-cover-the-visible-to-near-infrared-spectral-ranges
#11
Mi-Yun Jeong, Jin Yeob Mang
Spatially continuous tunable optical notch and band-pass filter systems that cover the visible (VIS) and near-infrared (NIR) spectral ranges from ∼460  nm to ∼1,000  nm are realized by combining left- and right-handed circular cholesteric liquid crystal (CLC) wedge cells with continuous pitch gradient. The notch filter system is polarization independent in all of the spectral ranges. The band-pass filter system, when the left- and right-handed CLCs are arranged in a row, is polarization independent, while when they are arranged at right angles, they are polarization dependent; furthermore, the full-width at half-maximum of the band-pass filter can be changed reversibly from the original bandwidth of 36 nm to 16 nm...
March 10, 2018: Applied Optics
https://www.readbyqxmd.com/read/29515951/temperature-tunable-lasing-from-dye-doped-chiral-microdroplets-encapsulated-in-a-thin-polymeric-film
#12
Gia Petriashvili, Mauro Daniel Luigi Bruno, Maria Penelope De Santo, Riccardo Barberi
In the last decade, much interest has grown around the possibility to use liquid-crystal droplets as optical microcavities and lasers. In particular, 3D laser emission from dye-doped cholesteric liquid crystals confined inside microdroplets paves the way for many applications in the field of sensors or tunable photonics. Several techniques can be used to obtain small microresonators as, for example, dispersing a liquid crystal inside an immiscible isotropic fluid to create an emulsion. Recently, the possibility to obtain a thin free-standing film starting from an emulsion having a mixture of water and polyvinyl alcohol as isotropic matrix has been reported...
2018: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/29448380/theoretical-model-of-chirality-induced-helical-self-propulsion
#13
Takaki Yamamoto, Masaki Sano
We recently reported the experimental realization of a chiral artificial microswimmer exhibiting helical self-propulsion [T. Yamamoto and M. Sano, Soft Matter 13, 3328 (2017)1744-683X10.1039/C7SM00337D]. In the experiment, cholesteric liquid crystal (CLC) droplets dispersed in surfactant solutions swam spontaneously, driven by the Marangoni flow, in helical paths whose handedness is determined by the chirality of the component molecules of CLC. To study the mechanism of the emergence of the helical self-propelled motion, we propose a phenomenological model of the self-propelled helical motion of the CLC droplets...
January 2018: Physical Review. E
https://www.readbyqxmd.com/read/29442119/chiral-lyotropic-chromonic-liquid-crystals-composed-of-disodium-cromoglycate-doped-with-water-soluble-chiral-additives
#14
Tatsuya Shirai, Min Shuai, Keita Nakamura, Akihiro Yamaguchi, Yumiko Naka, Takeo Sasaki, Noel A Clark, Khoa V Le
We investigated the pitches of cholesteric liquid crystals prepared by mixing disodium cromoglycate (DSCG) in water with 5 different water-soluble chiral additives. The measurements are based on the Grandjean-Cano wedge cell method. Overall, the twisting effect is weak, and the shortest pitch of 2.9 ± 0.2 μm is obtained using trans-4-hydroxy-l-proline, by which the cholesteric sample is iridescent at certain viewing angles. Freeze-fracture transmission electron microscopy (FFTEM) was also performed for the first time on both the nematic and cholesteric phases, revealing that stacked chromonic aggregates are very long, up to a few hundred nm, which explains why cholesteric chromonic liquid crystals hardly have pitches in the visible wavelength region...
February 14, 2018: Soft Matter
https://www.readbyqxmd.com/read/29402016/photoalignment-of-dye-doped-cholesteric-liquid-crystals-for-electrically-tunable-patterns-with-fingerprint-textures
#15
Yuan Shen, Yan-Chao Xu, Ya-Hao Ge, Rong-Guo Jiang, Xiao-Zhong Wang, Sen-Sen Li, Lu-Jian Chen
We present a convenient photoalignment approach to fabricate rewritable fingerprint textures with designed geometrical patterns based on methyl red doped cholesteric liquid crystals (MDCLCs). MDCLC systems with/without nanoparticles of polyhedral oligomeric silsesquioxanes (POSS) were employed to realize two types of sophisticated binary patterns, respectively. Based on the understanding of involved mechanisms related to boundary conditions and middle-layer theory, we demonstrated the precise manipulation of fingerprint patterns by varying the fingerprint grating vectors in different domains...
January 22, 2018: Optics Express
https://www.readbyqxmd.com/read/29401903/tuning-the-correlated-color-temperature-of-white-light-emitting-diodes-resembling-planckian-locus
#16
Ziqian He, Haiwei Chen, Yun-Han Lee, Shin-Tson Wu
We report a new electrically tunable color filter to actively adjust the correlated color temperature of white light-emitting diodes. With four passive cholesteric films and an active polarization rotator, both circular polarizations of the incident light are utilized to generate complementary blue and yellow colors. The blue/yellow ratio can be tuned by the applied voltage of the polarization rotator. In experiment, the tunable color filter offers a reasonably wide tuning range (1900 K and 2400 K), which resembles the Planckian locus...
January 22, 2018: Optics Express
https://www.readbyqxmd.com/read/29401858/tunable-liquid-crystal-microshell-laser-based-on-whispering-gallery-modes-and-photonic-band-gap-mode-lasing
#17
Yuelan Lu, Yue Yang, Yan Wang, Lei Wang, Ji Ma, Lingli Zhang, Weimin Sun, Yongjun Liu
The lasing behaviors of dye-doped cholesteric liquid crystal (DDCLC) microshells fabricated with silica-glass-microsphere coated DDCLCs were examined. Lasing characteristics were studied in a carrier medium with different refractive indices. The lasing in spherical cholesteric liquid crystals (CLCs) was attributed to two mechanisms, photonic band-gap (PBG) lasing and whispering-gallery modes (WGMs), which can independently exist by varying the chiral agent concentration and pumping energy. It was also found that DDCLC microshells can function as highly sensitive thermal sensors, with a temperature sensitivity of 0...
February 5, 2018: Optics Express
https://www.readbyqxmd.com/read/29382841/topology-dependent-self-structure-mediation-and-efficient-energy-conversion-in-heat-flux-driven-rotors-of-cholesteric-droplets
#18
Jun Yoshioka, Fumito Araoka
When heat flux is applied to a chiral liquid crystal, unidirectional rotation is induced around the flux axis, as first discovered by Otto Lehmann in 1900. In recent years, this heat-flux-induced phenomenon has been studied mostly in droplets of cholesteric liquid crystals undergoing phase transition from the isotropic to cholesteric phase, i.e., in the coexistence region, which occurs over a very narrow temperature range. Here, we report that the heat-flux-induced rotation can be stabilised by the use of a dispersion system, in which the cholesteric droplets are dispersed in a viscous and poorly miscible isotropic solvent...
January 30, 2018: Nature Communications
https://www.readbyqxmd.com/read/29347367/elastic-and-viscous-properties-of-the-nematic-dimer-cb7cb
#19
Greta Babakhanova, Zeinab Parsouzi, Sathyanarayana Paladugu, Hao Wang, Yu A Nastishin, Sergij V Shiyanovskii, Samuel Sprunt, Oleg D Lavrentovich
We present a comprehensive set of measurements of optical, dielectric, diamagnetic, elastic, and viscous properties in the nematic (N) phase formed by a liquid crystalline dimer. The studied dimer, 1,7-bis-4-(4'-cyanobiphenyl) heptane (CB7CB), is composed of two rigid rodlike cyanobiphenyl segments connected by a flexible aliphatic link with seven methyl groups. CB7CB and other nematic dimers are of interest due to their tendency to adopt bent configurations and to form two states possessing a modulated nematic director structure, namely, the twist-bend nematic, N_{TB}, and the oblique helicoidal cholesteric, Ch_{OH}, which occurs when the achiral dimer is doped with a chiral additive and exposed to an external electric or magnetic field...
December 2017: Physical Review. E
https://www.readbyqxmd.com/read/29347288/optical-band-gap-in-a-cholesteric-elastomer-doped-by-metallic-nanospheres
#20
Julio C Hernández, J Adrián Reyes
We analyzed the optical band gaps for axially propagating electromagnetic waves throughout a metallic doped cholesteric elastomer. The composed medium is made of metallic nanospheres (silver) randomly dispersed in a cholesteric elastomer liquid crystal whose dielectric properties can be represented by a resonant effective uniaxial tensor. We found that the band gap properties of the periodic system greatly depend on the volume fraction of nanoparticles in the cholesteric elastomer. In particular, we observed a displacement of the reflection band for quite small fraction volumes whereas for larger values of this fraction there appears a secondary band in the higher frequency region...
December 2017: Physical Review. E
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