photocatalyst

Herein, we report a visible light-enabled radical trihalomethylation/cyano-migration/carbonylation cascade reaction of 2-hydroxy-2-hex-5-enenitrile with CX3 SO2 Cl as the CX3 -source (X = F, Cl) to obtain 5-oxo-2-(2,2,2-trihaloethyl)pentanenitrile compounds in the absence of a photocatalyst, transition metal and base. This reaction system is also effective to convert (benzo[ d ]thiazol-2-yl)-pent-4-enol to the corresponding 4-(benzo[ d ]thiazol-2-yl)-6,6,6-trihalo-hexanone products. These reactions occur under mild conditions, tolerate a wide range of functional groups, and provide alternative approaches for the 1,2-bifunctionalization reaction of unactivated olefins...

This paper presents a study on two newly constructed two-dimensional van der Waals heterojunctions, Sc2CCl2/MoSe2 and Sc2CCl2/PtSe2, using density-functional theory. The study includes a systematic investigation of their geometrical structure, electronic properties, and optical properties. The results indicate that both heterojunctions are thermodynamically, kinetically, and mechanically stable. Additionally, Bader charge analysis reveals that both heterojunctions exhibit typical type II band properties. However, the band gap of the Sc2CCl2/MoSe2 heterojunction is only 1...

The development of a highly active photocatalyst for visible-light water splitting requires a high-quality semiconductor material and a cocatalyst, which promote the migration of photogenerated charge carriers and surface redox reactions. In this work, cocatalyst loading on an oxyfluoride photocatalyst Pb2Ti2O5.4F1.2 was applied to improve the water oxidation activity. Among the metal oxides examined, RuO2 was found to be the most suitable, and the O2 evolution activity depended on the preparation conditions of Ru/Pb2Ti2O5...

It is a challenging issue for the creation of photogenerated carrier collectors on the photocatalyst to drive charge separation and promote reaction kinetics in the photocatalytic reaction. Herein, based on one-step dual-modulation strategy, IrO2 nanodots are modified at the edge of polymeric carbon nitride (PCN) nanosheets and atomically dispersed Ir atoms are implanted in the skeleton of PCN to obtain a unique Ir-PCN/IrO2 photocatalyst. IrO2 nanodots and atomically dispersed Ir atoms act as hole and electron collectors to synergistically promote the carrier separation and reaction kinetics, respectively, thereby greatly improving the photocatalytic hydrogen evolution (PHE) performance...

Understanding the structure-performance relationships of a frustrated Lewis pair (FLP) at the atomic level is key to yielding high efficiency in activating chemically "inert" molecules into value-added products. A sound strategy was developed herein through incorporating oxygen defects into a Zr-based metal-organic layer (Zr-MOL-D) and employing Lewis basic proximal surface hydroxyls for the in situ formation of solid heterogeneous FLP (Zr4-δ -VO -Zr-OH ). Zr-MOL-D exhibits a superior CO2 to CO conversion rate of 49...

Decatungstate is a potent photocatalyst for hydrogen atom transfer (HAT) but faces degradation issues when using a typical tetra- n -butylammonium salt. Herein, we employed tetraphenylphosphonium as a countercation to yield a highly durable and efficient HAT photocatalyst, enabling α-oxygenation of amides to their corresponding imides using O2 as an oxidant.

ConspectusIn this Account, we discuss our group's research over the past decade on a class of functionalized boron clusters with tunable chemical and physical properties, with an emphasis on accessing and controlling their redox behavior. These clusters can be thought of as three-dimensional aromatic systems that have distinct redox behavior and photophysical properties compared to their two-dimensional organic counterparts. Specifically, our lab has studied the highly tunable, multielectron redox behavior of B12 (OR)12 clusters and applied these molecules in various settings...

Over the past decades, CO2 greenhouse emission has been considerably increased, causing global warming and climate change. Indeed, converting CO2 into valuable chemicals and fuels is a desired option to resolve issues caused by its continuous emission into the atmosphere. Nevertheless, CO2 conversion has been hampered by the ultrahigh dissociation energy of C=O bonds, which makes it thermodynamically and kinetically challenging. From this prospect, photocatalytic approaches appear promising for CO2 reduction in terms of their efficiency compared to other traditional technologies...

As a wide-bandgap rare-earth oxide, Eu2 O3 was often utilized as an auxiliary material of other photocatalysts because its photocatalytic performance was limited by the luminescence characteristics of Eu3+ and low light utilization. In this study, we improved the photocatalytic degradation performance of the Eu2 O3 nanoparticles by doping with Fe cations. The Eu2 O3 nanoparticles with different Fe-doping concentrations (1, 3, and 5%, noted as EF1.0, EF3.0, and EF5.0, respectively) were synthesized via chemical precipitation and calcination methods...

Methylene blue (MB) is a toxic contaminant present in wastewater. Here, we prepared various composites of graphene oxide (GO) with graphitic carbon nitride (g-C3 N4 ) and zinc oxide (ZnO) for the degradation of MB. In comparison to ZnO (22.9%) and g-C3 N4 /ZnO (76.0%), the ternary composites of GO/g-C3 N4 /ZnO showed 90% photocatalytic degradation of MB under a light source after 60 min. The experimental setup and parameters were varied to examine the process and effectiveness of MB degradation. Based on the results of the experiments, a proposed photocatalytic degradation process that explains the roles of GO, ZnO, and g-C3 N4 in improving the photocatalytic efficacy of newly prepared GO/g-C3 N4 /ZnO was explored...

ZnO nanorods (ZnO-nr) have been widely studied as a promising nanomaterial for photoelectrochemical water splitting. However, almost all prior studies employed planar electrodes. Here, we investigated the performance of ZnO nanorods on a fibrous carbon cloth (CC) electrode, which offers a larger surface area for functionalization of photocatalysts. ZnO nanorods and Ni nanofilm were deposited on carbon cloth substrates for investigation as the photoanode and cathode of a photoelectrochemical water splitting setup, respectively...

Chitosan (CS) polysaccharide is expected to exhibit greater ionic conductivity, which can be attributed to its increased amino group content when it is blended with different semiconducting materials. Herein, the work used this conducting ability of chitosan and prepared a heterogeneous MoS2 -induced magnetic chitosan (MF@CS) composite via the co-precipitation method, which was used to scrutinize the catalytic performance with Methylene Blue (MB) and Malachite Green (MG) dyes by visible light irradiation. The saturation magnetization value of the MF@CS composite is found to be 7...

The design and preparation of dual-functional photocatalysts for simultaneously realizing photocatalytic wastewater purification and hydrogen energy generation pose significant challenges. This article presents the engineering of a binary heterostructured photocatalyst by combining TiO2 (nanorods) and MoS2 nanosphere using a straightforward solvothermal method and the assessment of the phase structures, morphologies, and optical properties of the resulting nanocomposites using diverse analytical techniques...

In this study, the BiOBr/rGO nanocomposite photocatalysts are fabricated by a facile solvothermal method. The BiOBr growth on reduced graphene oxide (rGO) sheet could improve BiOBr's photocatalytic activity by increasing its adsorption ability, surface area, and charge carriers' separation efficiency. The prepared nanocomposites were characterized by XRD, Raman, FESEM, EDS, XPS, and UV-visible DRS. The BiOBr/rGO (BRG) nanocomposites showed improved photocatalytic activity for the photodegradation of Rhodamine B (RhB) dye and Tetracycline (TC) under visible light irradiation...

Recently, there has been a significant increase in interest in using photocatalysis for the energy conversion of polluting gases. In this research, sodium and ruthenium bimetallic functional sites co-modified bismuth tungstate (Ru/Na-Bi2 WO6 ) nanoflower photocatalyst was synthesized via the hydrothermal method. The CO2 reduction products on the Bi2 WO6 substrate were CO (1.66 μmol/g/h, 68 %) and CH4 (0.78 μmol/g/h, 32 %). After optimization, a significant change in the CO2 products of the Bi2 WO6 -based composite material was observed, with CO (0...

Groundwater contaminated with hexavalent chromium Cr(VI) causes serious health concerns for the ecosystem. In this study, a hybrid amino functionalized MOF@rGO nanocatalyst was produced by utilization of a biowaste mediated carbon material (reduced graphene oxide; rGO) and its surface was modified by in situ synthesis of a nanocrystalline, mixed ligand octahedral MOF containing iron metal and NH2 functional groups and the prepared composite was investigated for Cr (VI) removal. The photocatalytic degradation of Cr(VI) in aqueous solutions was carried out under UV irradiation...

Photocatalysis was an attractive strategy that had potential to tackle the Microcystin-LR (MC-LR) contamination of aquatic ecosystems. Herein, magnetic photocatalyst Fe3 O4 /Bi2 WO6 /Reduced graphene oxide composites (Bi2 WO6 /Fe3 O4 /RGO) were employed to degrade MC-LR. The removal efficiency and kinetic constant of the optimized Bi2 WO6 /Fe3 O4 /RGO (Bi2 WO6 /Fe3 O4 -40%/RGO) was 1.8 and 2.3 times stronger than the pure Bi2 WO6 . The improved activity of Bi2 WO6 /Fe3 O4 -40%/RGO was corresponded to the expanded visible light adsorption ability and reduction of photogenerated carrier recombination efficiency through the integration of Bi2 WO6 and Fe3 O4 -40%/RGO...

MoS2 -based materials have emerged as photoelectric semiconductors characterized by a narrow band gap, high capacity for absorbing visible light, and reduced H2 adsorption energy comparable to Pt. These attributes render them appealing for application in photocatalytic hydrogen production. Despite these advantages, the widespread adoption of MoS2 -based materials remains hindered by challenges associated with limited exposure to active sites and suboptimal catalytic hydrogen production efficiency. To address these issues, we have designed and synthesized a new class of highly dispersed bimetallic/trimetallic sulfide materials...

The enhancement of charge separation and utilization efficiency in both the bulk phase and interface of semiconductor photocatalysts, as well as the expansion of light absorption range, are crucial research topics in the field of photocatalysis. To address this issue, twinned Cd0.5 Zn0. 5S (T-CZS) homojunctions consisting of wurtzite Cd0.5 Zn0.5 S (WZ-CZS) and zinc blende Cd0.5 Zn0.5 S (ZB-CZS) were synthesized via a hydrothermal method to facilitate the bulk-phase charge separation. Meanwhile, Cu2-x Se with localized surface plasmon resonance effect (LSPR) generated by Cu vacancies was also obtained through a hydrothermal process...

Release of formaldehyde gas indoors is a serious threat to human health. The traditional adsorption method is not stable enough for formaldehyde removal. Photocatalytic degradation of formaldehyde is effective and rapid, but photocatalysts are generally expensive and not easy to recycle. In this paper, geopolymer microspheres were applied as matrix materials for photocatalysts loading to degrade formaldehyde. Geopolymer microspheres were prepared from red mud and granulated blast furnace slag as raw materials by alkali activation...